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Tetramethylgermanium

HCID 70079
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
865-52-1
Standard SMILES
[CH3][Ge]([CH3])([CH3])[CH3]
InChIKey
ZRLCXMPFXYVHGS-UHFFFAOYSA-N
Molecular formula
C4H12Ge
Average molar mass
132.77 g/mol
Monoisotopic mass
134.0150781

Overview

Tetramethylgermane is an organogermanium compound that is germanium which carries four methyl groups. It has a role as a NMR chemical shift reference compound.

Names & identifiers

Preferred name
Tetramethylgermanium
IUPAC
tetramethylgermane
English name
Tetramethylgermane
Molecular formula
C4H12Ge
Molecular weight
132.78

Names & synonyms

TetramethylgermaniumGermane, tetramethyl-Germanium, tetramethylRefChem:897356212-745-0Tetramethylgermane865-52-1Germanium, tetramethyl-TL 81EINECS 212-745-0Me4GeBRN 3660066
Show more names
tl81tetramethyl-germaniuTetralmethylgermaniumTetramethylgermane,99%Tetramethylgermanium,97%Tetramethylgermanium,98%
MFCD00014843(CH3)4Ge4-04-00-04282 (Beilstein Handbook Reference)Tetramethyl germaniumC4H12Getetra-methyl-germaniumTetramethylgermanium, 98%GERMANIUM TETRAMETHYL

Database identifiers

CAS
865-52-1
PubChem CID
70079
DTXSID
DTXSID70235600
ChEBI
CHEBI:231506
EC Number
212-745-0
Nikkaji
J95.354G

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
0
Rotatable bonds
0
Heavy atoms
5
Formal charge
0
Complexity
19.1

Experimental & physicochemical properties

Chemical ClassesMetals -> Metals, Organic Compounds
Vapor Pressure30.0 [mmHg]
Physical DescriptionClear light yellow liquid; [Sigma-Aldrich MSDS]

Physicochemical properties

Melting point
-88 °C · -88 °C (dec.) (lit.)
Boiling point
43 · 43-44 °C/740 mmHg (lit.)
Density
0.978 g/mL · 0.978 g/mL at 25 °C (lit.)
vapor pressure
6.74 psi · 6.74 psi ( 20 °C)
refractive index
20 · n20/D 1.389(lit.)
Flash point
35 °F · −35 °F
storage temp.
Flammables area
form
liquid
Specific Gravity
0.978 · 0.978
color
colorless
Water Solubility

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P317, P321, P330, P337+P317, P362+P364, P370+P378, P403+P235, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 44 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazards SummaryInhalation lethal concentration (mouse) > 2,500 mg/m3/10min; [RTECS] A strong eye irritant; Harmful by ingestion, inhalation, and skin absorption; [Sigma-Aldrich MSDS] See Germanium. See Tetramethyl lead.
Hazard Classes and CategoriesFlam. Liq. 2 (100%)

Toxicology

Adverse EffectsNeurotoxin - Other CNS neurotoxin

Safety data

PPE
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk
3
tsca
No
rtecs
LY5345000
ridadr
UN 1993 3/PG 2
hs_code
2931900090
risk_code
11-20/21/22-36-36/37
Signal word

Chemistry & industry

Applications

UsesEmployed as a Chemical Vapor Deposition (CVD) precursor to germanium oxide thin films.

UsesCVD precursor to germanium oxide thin films.

Upstream & downstream products

Downstream products

TRIMETHYLGERMANIUM BROMIDEGermanium

Suppliers40 total

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海源象化学有限公司17312431727 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
武汉易泰科技有限公司上海分公司18930552037 · [email protected]
阿法埃莎(中国)化学有限公司400-6106006 · [email protected]

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Not miscible or difficult to mix in water.
Hydrolytic Sensitivity
4 · 4: no reaction with water under neutral conditions
Dielectric constant
1.82 · 1.8200000000000001
InChI
InChI=1S/C4H12Ge/c1-5(2,3)4/h1-4H3
InChIKey
ZRLCXMPFXYVHGS-UHFFFAOYSA-N
SMILES
[Ge](C)(C)(C)C
CAS DataBase Reference
865 · 865-52-1(CAS DataBase Reference)
UNSPSC Code
12352103 · 12352103
NACRES
23 · NA.23
Symbol(GHS)
2 · GHS02,GHS07
Signal word
Danger
Hazard statements
225 · H225-H302+H312+H332-H319
Precautionary statements
210 · P210-P280-P301+P312-P303+P361+P353-P304+P340+P312-P305+P351+P338
PPE
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes
F,Xn
Risk Statements
11 · 11-20/21/22-36-36/37
Safety Statements
16 · 16-26-36
RIDADR
1993 · UN 1993 3/PG 2
WGK Germany
3 · 3
RTECS
5345000 · LY5345000
TSCA
No
HazardClass
3 · 3
PackingGroup
II
HS Code
2931900090 · 2931900090
Storage Class
3 · 3 - Flammable liquids
Hazard Classifications
4 OralEye · Acute Tox. 4 OralEye Irrit. 2Flam. Liq. 2
Danger
Symbol(GHS)
GHS02,GHS07
hazard_code
F,Xn
safety_code
16-26-36
hazard_class
3
Storage Class
3 - Flammable liquids
packing_group
II
Hazard statements
H225-H302+H312+H332-H319
Hazard Classifications
Acute Tox. 4 OralEye Irrit. 2Flam. Liq. 2
Precautionary statements
P210-P280-P301+P312-P303+P361+P353-P304+P340+P312-P305+P351+P338
安耐吉化学&3A(安徽泽升科技股份有限公司)
400-0056266 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
山东西亚化学有限公司13355009207 13355009207 · [email protected]
四川库利南科技有限公司400-1166-196 18981987031 · [email protected]
艾科试剂4008-755-333 18080918076 · [email protected]
TOKYO CHEMICAL INDUSTRY CO., LTD.03-36680489 · [email protected]
苏州亚科科技股份有限公司0512-87182055 13451648594 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
九鼎化学(上海)科技有限公司4009209199 · [email protected]
西安美川生物科技有限公司029-89275612 +8618991951683 · [email protected]
广东翁江化学试剂有限公司0751-2886766 13927870850 · [email protected]
上海阿拉丁生化科技股份有限公司6206333 13167063860 · [email protected]
陕西缔都医药化工有限公司+86-29-81139210 +86-17392587031 · [email protected]
上海源叶生物科技有限公司18916372613 · [email protected]
SHANGHAI AOTA NEW MATERIAL CO., LTD+8615821847224 · [email protected]
上海颖心实验室设备有限公司021-021-59178156 15300768757 · [email protected]
山东西亚化学有限公司4009903999 13395398332 · [email protected]
上海思域化工科技有限公司021-34053660 · [email protected]
郑州汇聚化工有限公司0371-55900031 18137872243 · [email protected]
广州市金华大化学试剂有限公司020-84383047 · [email protected]
上海贤鼎生物科技有限公司021-021-52271985 17721149837 · [email protected]
拓元(潍坊)新材料科技有限公司13940155665 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
陕西缔都医药化工有限公司029-88380327 17691182729 · [email protected]
TCI Chemicals (India) Pvt. Ltd.[email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
北京百灵威科技有限公司18210857532 18210857532 · [email protected]
上海鼓臣生物技术有限公司021-34675735 19147740836 · [email protected]
杭州南原有机硅科技有限公司15868422438 · [email protected]
亚索试剂400-873-6778 18660992876 · [email protected]
湖北实顺生物科技有限公司027-59223025 15107168801 · [email protected]