CAS 873-38-1 2-Bromo-4-chloroaniline (HCID 70110)

Names & identifiers

Preferred name: 2-Bromo-4-chloroaniline
IUPAC: 2-bromo-4-chloroaniline
English name: 2-Bromo-4-chloroaniline
Molecular formula: C6H5BrClN
Molecular weight: 206.47

Names & synonyms

2-Bromo-4-chloroaniline873-38-1Benzenamine, 2-bromo-4-chloro-EINECS 212-837-0DTXSID90236270NSC 139478RefChem:85710DTXCID90158761212-837-0SYTBIFURTZACKR-UHFFFAOYSA-N2-Bromo-4-chloro-phenylamineMFCD00041313

Show more names

2-Bromo-4-chL2-Bromo-4-chlroaniline4-Chloro-2-Bromoanilin4-methoxy-2-bromo aniline2-Bromo-4-chloroaniline 99%2-Bromo-4-chloroaniline >2-Bromo-4-chloroaniline,98%

2-BROMO-4-CHLORO ANILINEAA3RNN5H9JNSC-1394782-bromo-4-chlorophenylamine2-bromo-4-chloro-aniline2-Bromo-4-chlorobenzenamine4-CHLORO-2-BROMOANILINENSC139478

Database identifiers

CAS: 873-38-1
PubChem CID: 70110
DTXSID: DTXSID90236270
UNII: AA3RNN5H9J
EC Number: 212-837-0
Nikkaji: J195.153J

Properties

Computed structural properties

XLogP: 3
Topological polar surface area: 26 Å²
Hydrogen bond donors: 1
Hydrogen bond acceptors: 1
Rotatable bonds: 0
Heavy atoms: 9
Formal charge: 0
Complexity: 99.1

Physicochemical properties

Melting point: 64 · 64-68 °C (lit.)
Boiling point: 127 °C · 127°C 14mm
Density: 1.722 · 1.722±0.06 g/cm3(Predicted)
Flash point: 127 °C/20mm · 127°C/20mm
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: soluble in Methanol
pka: 1.9 · 1.90±0.10(Predicted)
form: Crystalline Powder
color: Pale brown
BRN: 2802563 · 2802563
InChI: InChI=1S/C6H5BrClN/c7-5-3-4(8)1-2-6(5)9/h1-3H,9H2
InChIKey: SYTBIFURTZACKR-UHFFFAOYSA-N
SMILES: C1(N)=CC=C(Cl)C=C1Br
CAS DataBase Reference: 873 · 873-38-1(CAS DataBase Reference)
FDA UNII: 3 RNN5H9J · AA3RNN5H9J
NIST Chemistry Reference: 2 · 2-Bromo-4-chloroaniline(873-38-1)
UNSPSC Code: 12352100 · 12352100
NACRES: 22 · NA.22
Symbol(GHS): 7 · GHS07,GHS06,GHS08
Signal word: Warning
Hazard statements: 301 · H301-H302+H312+H332-H302-H311-H332-H373-H315-H319-H335
Precautionary statements: 280 h-P302+P352-P309-P310-P261-P305+P351+P338-P280a-P301+P310a-P405-P501a-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501 · P280h-P302+P352-P309-P310-P261-P305+P351+P338-P280a-P301+P310a-P405-P501a-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501
target organs: Respiratory system
PPE: 95 · dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes: Xi
Risk Statements: 36 · 36/37/38
Safety Statements: 26 · 26-36
RIDADR: 2811 · UN2811
WGK Germany: 3 · 3
Hazard Note: Harmful
HazardClass: 6.1 · 6.1
PackingGroup: III
HS Code: 29214200 · 29214200
Storage Class: 11 · 11 - Combustible Solids
Hazard Classifications: 2 Skin · Eye Irrit. 2Skin Irrit. 2STOT SE 3
REACH Registrations: Active

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H302 (12.5%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P262, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P316, P317, P319, P321, P330, P332+P317, P337+P317, P361+P364, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 48 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesAcute Tox. 4 (12.5%)

Safety data

PPE: dust mask type N95 (US), Eyeshields, Gloves
wgk: 3
ridadr: UN2811
hs_code: 29214200
risk_code: 36/37/38
Signal word: Warning
Symbol(GHS): GHS07,GHS06,GHS08
hazard_code: Xi
hazard_note: Harmful
safety_code: 26-36
hazard_class: 6.1
Storage Class: 11 - Combustible Solids
packing_group: III
target organs: Respiratory system
Hazard statements: H301-H302+H312+H332-H302-H311-H332-H373-H315-H319-H335
REACH Registrations: Active
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
Precautionary statements: P280h-P302+P352-P309-P310-P261-P305+P351+P338-P280a-P301+P310a-P405-P501a-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501

Chemistry & industry

Applications

Uses2-Bromo-4-chloroaniline may be used in the preparation of:2-bromo-4-chloro-N-tosylaniline2-bromo-4-chlorothiophenol7-chloro-4a-methyl-4,4a,9,9a-tetrahydro-1H-carbazol-2(3H)-one

General Description2-Bromo-4-chloroaniline is a 2-bromo-4-substituted aniline that can be prepared from 4-chloroaniline via electrophilic bromination.