HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Bromomethylnaphthalene
2-(broMoMethyl)napthalene · 2-Naphtylmethyl bromide · 2-naphthylmethyl bromide · 2-BMN · 2-Bromomethyl naphth · naphthylmethyl bromide · BROMOMETHYLNAPTHALENE-2 · 2-(Bromomethyl)phthalene
Identifiers & Physical Properties
| CAS No. | 939-26-4 |
|---|---|
| Molecular formula | C11H9Br |
| Average molar mass | 221.09 g/mol |
| Monoisotopic mass | 219.98876239 g/mol |
| SMILES | BrCc1ccc2ccccc2c1 |
| InChIKey | RUHJZSZTSCSTCC-UHFFFAOYSA-N |
| PubChem CID | 70320 |
| EC No. | 213-359-5 |
| DTXSID | DTXSID10239864 |
Chemical & Physical Properties
| XLogP | 3.7 |
|---|---|
| Topological polar surface area | 0 |
| Hydrogen bond donors | 0 |
| Hydrogen bond acceptors | 0 |
| Rotatable bonds | 1 |
| Heavy atoms | 12 |
| Formal charge | 0 |
| Complexity | 144 |
| SpringerMaterials Properties | 13C nuclear magnetic resonance spectrum |
| Melting point | 51-54 °C(lit.) |
| Boiling point | 213 °C100 mm Hg(lit.) |
| Density | 1.3971 (rough estimate) |
| Refractive index | 1.6411 (estimate) |
| Flash point | >230 °F |
| Storage conditions | 2-8°C |
| Solubility | Chloroform (Sparingly), Ethyl Acetate (Very Slightly)Soluble in water (reacts), and chloroform. |
| Physical state | Fine Crystalline Powder |
| Color | Slightly yellow to light beige |
| BRN | 636546 |
| InChI | InChI=1S/C11H9Br/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-7H,8H2 |
| InChIKey | RUHJZSZTSCSTCC-UHFFFAOYSA-N |
| SMILES | C1=C2C(C=CC=C2)=CC=C1CBr |
| CAS DataBase Reference | 939-26-4(CAS DataBase Reference) |
| NIST Chemistry Reference | Naphthalene, 2-(bromomethyl)-(939-26-4) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
| GHS pictogram | GHS05,GHS07 |
| Signal word | Danger |
| GHS hazard statements | H314-H317 |
| GHS precautionary statements | P260-P272-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
| Personal protective equipment (PPE) | Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges |
| Hazard symbols | C,Xi |
| Risk statements (R) | 34-43-36/37/38-36 |
| Safety statements (S) | 26-28-36/37/39-45-37-27 |
| UN transport number | UN 3261 8/PG 2 |
| Water hazard class (WGK) | 3 |
| F | 10-21 |
| Hazard Note | Corrosive/Keep Cold |
| Hazard class | 8Skin Corr. 1BSkin Sens. 1 |
| Packing group | II |
| Customs code | 29033036 |
| Storage class | 8A - Combustible corrosive hazardous materials |
| Limited quantities | 1 Kg (2.2 lbs) (solid) |
| Excepted quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
Safety & Regulations
| GHS classification | DangerH314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]P260, P261, P264, P272, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P333+P317, P362+P364, P363, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 50 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatory information | Naphthalene, 2-(bromomethyl)-: Does not have an individual approval but may be used under an appropriate group standard |
| Hazard Classes and Categories | Skin Corr. 1B (100%) |
| F | 10-21 |
| Personal protective equipment (PPE) | Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges |
| Water hazard class (WGK) | 3 |
| UN transport number | UN 3261 8/PG 2 |
| Customs code | 29033036 |
| Risk statements (R) | 34-43-36/37/38-36 |
| Signal word | Danger |
| GHS pictogram | GHS05,GHS07 |
| Hazard symbols | C,Xi |
| hazard_note | Corrosive/Keep Cold |
| Safety statements (S) | 26-28-36/37/39-45-37-27 |
| Hazard class | 8Skin Corr. 1BSkin Sens. 1 |
| Storage class | 8A - Combustible corrosive hazardous materials |
| Packing group | II |
| GHS hazard statements | H314-H317 |
| Limited quantities | 1 Kg (2.2 lbs) (solid) |
| Excepted quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
| GHS precautionary statements | P260-P272-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
Applications & Uses
Uses
It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.
Uses
2-(Bromomethyl)naphthalene (2-BMN) can be employed as a starting material in the synthesis of 2-(fluoromethyl)naphthalene , 2-naphthylmethyl azide , 2-naphthalenecarboxaldehyde , diselenide, bis(2-naphthalenylmethyl) , 1H-1,2,3-triazole, 4,4′-(1,4-phenylene)bis[1-(2-naphthalenylmethyl).