2-Bromomethylnaphthalene
Basic information
- CAS
939-26-4- Standard SMILES
BrCc1ccc2ccccc2c1- InChIKey
RUHJZSZTSCSTCC-UHFFFAOYSA-N- Molecular formula
- C11H9Br
- Average molar mass
- 221.09 g/mol
- Monoisotopic mass
- 219.98876239
Names & identifiers
- Preferred name
- 2-Bromomethylnaphthalene
- IUPAC
- 2-(bromomethyl)naphthalene
- English name
- 2-(Bromomethyl)naphthalene
- Molecular formula
- C11H9Br
- Molecular weight
- 221.09
Names & synonyms
2-(Bromomethyl)naphthalene939-26-42-BromomethylnaphthaleneNaphthalene, 2-(bromomethyl)-EINECS 213-359-5DTXSID10239864RefChem:467281DTXCID60162355213-359-5InChI=1/C11H9Br/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-7H,8H2-Naphthylmethyl bromideMFCD00004123
Show more names
2-Naphtylmethyl bromide2-BMN2-Bromomethyl naphthnaphthylmethyl bromideBROMOMETHYLNAPTHALENE-22-(Bromomethyl)phthalene2-(Xiu Jiaji)naphthalene2-(brommethyl)naphthalen
2-bromomethyl-naphthalene.beta.-(Bromomethyl)naphthalene2-Bromomethyl naphthalene2-Menaphthyl bromide2-(bromomethyl)napthalene(Naphthalen-2-yl)methyl bromide; 2-Menaphthyl bromide; 2-Naphthylmethyl bromide; beta-(Bromomethyl)naphthalene; beta-Naphthylmethyl bromide2-bromomethynaphthalene2-Bromomethylnapthalene
Database identifiers
- CAS
939-26-4- PubChem CID
- 70320
- DTXSID
DTXSID10239864- EC Number
- 213-359-5
- Nikkaji
- J149.364G
Properties
Computed structural properties
- XLogP
- 3.7
- Topological polar surface area
- 0 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 0
- Rotatable bonds
- 1
- Heavy atoms
- 12
- Formal charge
- 0
- Complexity
- 144
Experimental & physicochemical properties
SpringerMaterials Properties13C nuclear magnetic resonance spectrum
Physicochemical properties
- Melting point
- 51 · 51-54 °C(lit.)
- Boiling point
- 213 °C100 · 213 °C100 mm Hg(lit.)
- Density
- 1.3971 · 1.3971 (rough estimate)
- refractive index
- 1.6411 · 1.6411 (estimate)
- Flash point
- 230 °F · >230 °F
- storage temp.
- 2 · 2-8°C
- solubility
- Chloroform (Sparingly), Ethyl Acetate (Very Slightly)
- form
- Fine Crystalline Powder
- color
- Slightly yellow to light beige
- Water Solubility
- Soluble in water (reacts), and chloroform.
- BRN
- 636546 · 636546
- InChI
- InChI=1S/C11H9Br/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-7H,8H2
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P260, P261, P264, P272, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P333+P317, P362+P364, P363, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 50 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Regulatory InformationNaphthalene, 2-(bromomethyl)-: Does not have an individual approval but may be used under an appropriate group standard
Hazard Classes and CategoriesSkin Corr. 1B (100%)
Safety data
- F
- 10-21
- PPE
- Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
- wgk
- 3
- ridadr
- UN 3261 8/PG 2
- hs_code
- 29033036
- risk_code
- 34-43-36/37/38-36
- Signal word
- Danger
- Symbol(GHS)
- GHS05,GHS07
- hazard_code
- C,Xi
- hazard_note
- Corrosive/Keep Cold
- safety_code
- 26-28-36/37/39-45-37-27
- hazard_class
- 8
Chemistry & industry
Applications
UsesIt is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.
Uses2-(Bromomethyl)naphthalene (2-BMN) can be employed as a starting material in the synthesis of 2-(fluoromethyl)naphthalene , 2-naphthylmethyl azide , 2-naphthalenecarboxaldehyde , diselenide, bis(2-naphthalenylmethyl) , 1H-1,2,3-triazole, 4,4′-(1,4-phenylene)bis[1-(2-naphthalenylmethyl).
Upstream & downstream products
Upstream raw materials
Downstream products
Related reactions
391 records
Compound notes
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