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Tetraphenoxysilane

HCID 70896
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Substructure searchFind similar structures

Basic information

CAS
1174-72-7
Standard SMILES
c1ccc(O[Si](Oc2ccccc2)(Oc2ccccc2)Oc2ccccc2)cc1
InChIKey
ADLSSRLDGACTEX-UHFFFAOYSA-N
Molecular formula
C24H20O4Si
Average molar mass
400.5 g/mol
Monoisotopic mass
400.11308565

Overview

Tetraphenoxysilane appears as white powder or light pink chunky solid. (NTP, 1992)

Names & identifiers

Preferred name
Tetraphenoxysilane
IUPAC
tetraphenyl silicate
English name
Tetraphenoxysilane
Molecular formula
C24H20O4Si
Molecular weight
400.5

Names & synonyms

Tetraphenoxysilane1174-72-7Tetraphenyl orthosilicatetetraphenyl silicateSilane, tetraphenoxy-Phenyl silicate ((PhO)4Si)UNII-0D1L8O3QUIEINECS 214-638-40D1L8O3QUINSC 252166NSC-252166DTXSID0026129
Show more names
DK046Orthosilicetraphenylsilicatetetrakis(phenoxy)silaneTetraphenoxysilanemin98%tetraphenoxysilane min 98%TETRAPHENOXYSILANE, tech-95
phenyl silicateRefChem:188833DTXCID006129Silicic acid, tetraphenyl esterSilicic acid (H4SiO4), tetraphenyl esterMFCD00020651TetraphenylorthosilicateSCHEMBL301726

Database identifiers

CAS
1174-72-7
PubChem CID
70896
DTXSID
DTXSID0026129
UNII
0D1L8O3QUI
EC Number
214-638-4
Nikkaji
J70.245E

Properties

Computed structural properties

Topological polar surface area
36.9 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
4
Rotatable bonds
8
Heavy atoms
29
Formal charge
0
Complexity
364

Experimental & physicochemical properties

SpringerMaterials PropertiesChemical shift
Density1.141 at 68 °F (NTP, 1992) - Denser than water; will sink
Solubilityless than 1 mg/mL at 68.9 °F (NTP, 1992)
Flash Pointgreater than 230 °F (NTP, 1992)
Boiling Point784 °F at 760 mmHg (NTP, 1992)
Melting Point118 to 120 °F (NTP, 1992)
Vapor Densitygreater than 1 (NTP, 1992) (Relative to Air)
Vapor Pressure0.975 mmHg (NTP, 1992)
Physical DescriptionTetraphenoxysilane appears as white powder or light pink chunky solid. (NTP, 1992)

Physicochemical properties

Melting point

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory InformationChemical: Silicic acid (H4SiO4), tetraphenyl ester
DOT LabelCorrosive
Fire HazardsThis chemical is probably combustible. (NTP, 1992)
Health HazardsSYMPTOMS: Symptoms of exposure to this compound may include irritation of the skin and eyes.
Reactive GroupSiloxanes
Reactivity ProfileTETRAPHENOXYSILANE is incompatible with strong oxidizers and mineral acids. (NTP, 1992).
Air and Water ReactionsInsoluble in water.
Hazard Classes and CategoriesSkin Corr. 1C (100%)

Safety & protection

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationSilicic acid (H4SiO4), tetraphenyl ester: ACTIVE

Applications

General DescriptionWhite powder or light pink chunky solid.

Suppliers47 total

湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
温州共赢化学有限公司+86-0086-577-64498589 +86-15355981851 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
北京华威锐科化工有限公司0757-86329057 18934348241 · [email protected]
上海泰坦科技股份有限公司4006009262 13023226327 · [email protected]
上海祈铭新材料有限公司021-36010885 13661599081;13701898138 · [email protected]
TOKYO CHEMICAL INDUSTRY CO., LTD.03-36680489 · [email protected]
广东顺奥化学试剂有限公司19928586137 · [email protected]
上海探圭新材料科技有限公司18516111942 · [email protected]
上海石洋化工有限公司021-56795766 · [email protected]

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
47 · 47-50 °C
Boiling point
417 °C · 417°C
Density
1.1412 · 1.1412
refractive index
1.5539 · 1.5539
Flash point
160 °C · 160°C (320°F)
form
solid
Specific Gravity
1.1412 · 1.1412
Hydrolytic Sensitivity
7 · 7: reacts slowly with moisture/water
FDA UNII
0 D1L8O3QUI · 0D1L8O3QUI
EPA Substance Registry System
Silicic acid (H4SiO4), tetraphenyl ester (1174-72-7)
Symbol(GHS)
5 · GHS05
Signal word
Danger
Hazard statements
314 · H314
Precautionary statements
260 · P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501
Hazard Codes
C
Risk Statements
34 · 34
Safety Statements
26 · 26-36/37/39-45
RIDADR
3261 · UN 3261 8/PG 3
TSCA
TSCA listed
Fire Fighting
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 item

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 item

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Personal Protective Equipment (PPE) · 1 item

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Safety data

tsca
TSCA listed
ridadr
UN 3261 8/PG 3
risk_code
34
Signal word
Danger
Symbol(GHS)
GHS05
hazard_code
C
safety_code
26-36/37/39-45
Hazard statements
H314
Precautionary statements
P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501
江苏艾康生物医药研发有限公司
025-66028182 17714375163 · [email protected]
Shanghai Enchem Industry Co., Ltd.15021317485
壮铭新材料科技江苏有限公司17312398916 051386936896 15216715905 · [email protected]
Alfa Chemistry1-516-6625404 · [email protected]
Henan Alfa Chemical Co., Ltd+8618339805032 · [email protected]
杭州鼎燕化工有限公司0571-87157530-8003 18049756717 · [email protected]
Alfa Chemistry+1-5166625404 · [email protected]
上海阿拉丁生化科技股份有限公司6206333 13167063860 · [email protected]
陕西缔都医药化工有限公司029-029-81120477 17792793610 · [email protected]
上海源叶生物科技有限公司18916372613 · [email protected]
深圳市创鑫生物科技有限公司13417589054 · [email protected]
上海鑫矽新材料有限公司13585834793 13660927110 · [email protected]
上海圭景新材料科技有限公司18616507986 · [email protected]
新亚强硅化学股份有限公司19921372399 · [email protected]
杭州洁汉化工有限公司+86-571-86217390; +8618058761490 · [email protected]
Shanghai Daken Advanced Materials Co.,Ltd+86-2158073036 · [email protected]
苏州矽索新材料有限公司(生产型企业)0512-65402974 18550909935 · [email protected]
常州北山化工有限公司+86-021-61559630 +86-13761092941 · [email protected]
career henan chemical co+86-0371-86658258 · [email protected]
ATK CHEMICAL COMPANY LIMITED+undefined-21-51877795 · [email protected]
Win-Win Chemical CO., Limited0086-577-64498589 · [email protected]
安徽硅创新材料科技有限公司17201714774 · [email protected]
湖南秉航新材料有限公司85521272 18932438858 · [email protected]
海蔚化学86-21-51086038 · [email protected]
深圳市创鑫生物科技有限公司13417589054 · [email protected]
Aladdin Scientific[email protected]
湖北拓邦化工有限公司027-59106185 13986192185 · [email protected]
湖北科孚乐材料科技有限公司+86-27-84459282 · [email protected]
湖北魏氏化学试剂股份有限公司027-59102966 18717199209 · [email protected]
陕西缔都医药化工有限公司+86-29-81139210 17389186172 · [email protected]
上海积流新材料科技有限公司18817937917 18751119219 · [email protected]
广东翁江化学试剂有限公司0751-2815983 13927872582 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]
榆林润天畅化工有限责任公司15890142075 15890142075 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-15350571055 · [email protected]
Hefei TNJ Chemical Industry Co.,Ltd.+86-0551-65418671 +86-189 4982 3763 · [email protected]
CD Chemical Group Limited+86-13651442114 · [email protected]