Basic information
- CAS
1592-20-7- Standard SMILES
C=Cc1ccc(CCl)cc1- InChIKey
ZRZHXNCATOYMJH-UHFFFAOYSA-N- Molecular formula
- C9H9Cl
- Average molar mass
- 152.62 g/mol
- Monoisotopic mass
- 152.03927797
Names & identifiers
- Preferred name
- p-Vinylbenzyl chloride
- IUPAC
- 1-(chloromethyl)-4-ethenylbenzene
- English name
- 4-Vinylbenzyl chloride
- Molecular formula
- C9H9Cl
- Molecular weight
- 152.62
Names & synonyms
4-Vinylbenzyl chloride1592-20-71-(Chloromethyl)-4-vinylbenzene4-(Chloromethyl)styrene1-(chloromethyl)-4-ethenylbenzenep-vinylbenzyl chlorideBenzene, 1-(chloromethyl)-4-ethenyl-CJL4OJ6BS0Benzene, (chloromethyl)ethenyl-EINECS 216-471-2DTXSID2061808RefChem:858262
Show more names
4-VINYLBENZYL CHLORIDE, STAB.4-(Chloromethyl)styrene, 90%, stabilizedCMS 144-Vinylbenylchloride4-Vinylbenzyl chlorip-(Chloromethyl)styrene
1(Chloromethyl)4vinylbenzeneDTXCID4035124Benzene, 1(chloromethyl)4ethenylEINECS 250-005-9216-471-24-Chloromethylstyrene1-(chloromethyl)-4-vinyl-benzenepoly(4-vinylbenzyl chloride)
Database identifiers
- CAS
1592-20-7、30030-25-2- PubChem CID
- 74126
- DTXSID
DTXSID2061808- UNII
- CJL4OJ6BS0
- EC Number
- 216-471-2
- Nikkaji
- J91.309J
Properties
Computed structural properties
- XLogP
- 3.1
- Topological polar surface area
- 0 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 0
- Rotatable bonds
- 2
- Heavy atoms
- 10
- Formal charge
- 0
- Complexity
- 101
Experimental & physicochemical properties
Chemical ClassesOther Classes -> Halogenated Monoaromatics
Physical Description
Liquid
Liquid; [Sigma-Aldrich MSDS]
Physicochemical properties
- Boiling point
- 229 °C · 229 °C(lit.)
- Density
- 1.083 g/mL · 1.083 g/mL at 25 °C(lit.)
- vapor density
- 5.3 · 5.3 (vs air)
- vapor pressure
- 1 mm · 1 mm Hg ( 56.1 °C)
- refractive index
- 20 · n20/D 1.572(lit.)
- Flash point
- 221 °F · 221 °F
- storage temp.
- 2 · 2-8°C
- Water Solubility
- Insoluble in water
- solubility
- Chloroform (Sparingly)
- form
- Liquid
- color
- Clear yellow
- Viscosity
- 1 · 1,830cP(25°C)(lit.)
- FreezingPoint
- -15.5 · -15.5
- BRN
- 2204384 · 2204384
- Stability
- Light Sensitive
- InChI
- 1S/C9H9Cl/c1-2-8-3-5-9(7-10)6-4-8/h2-6H,1,7H2
- InChIKey
- ZRZHXNCATOYMJH-UHFFFAOYSA-N
- SMILES
- ClCc1ccc(C=C)cc1
- CAS DataBase Reference
- 1592 · 1592-20-7(CAS DataBase Reference)
- FDA UNII
- 4 OJ6BS0 · CJL4OJ6BS0
- EPA Substance Registry System
- 1 · Benzene, 1-(chloromethyl)-4-ethenyl- (1592-20-7)
- UNSPSC Code
- 12162002 · 12162002
- NACRES
- 23 · NA.23
- Symbol(GHS)
- 5 · GHS05,GHS06
- Signal word
- Danger
- Hazard statements
- 302 · H302-H311-H314-H317
- Precautionary statements
- 261 · P261-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338
- PPE
- Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
- Hazard Codes
- C
- Risk Statements
- 34 · 34-43-21/22
- Safety Statements
- 26 · 26-36/37/39-45
- RIDADR
- 3265 · UN 3265 8/PG 3
- WGK Germany
- 3 · 3
- F
- 8 · 8-19
- TSCA
- TSCA listed
- HazardClass
- 8 · 8
- PackingGroup
- III
- HS Code
- 29039990 · 29039990
- Storage Class
- 6.1 A · 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
- Hazard Classifications
- 3 DermalAcute · Acute Tox. 3 DermalAcute Tox. 4 OralEye Dam. 1Skin Corr. 1BSkin Sens. 1
Safety & regulation
GHS classification
GHS Classification
Danger
H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]
P260, P261, P262, P264, P270, P272, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P333+P317, P361+P364, P362+P364, P363, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 54 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Regulatory Information
Chemical: Benzene, 1-(chloromethyl)-4-ethenyl-
Benzene, (chloromethyl)ethenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzene, (chloromethyl)ethenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Hazards Summary
Causes burns and lachrymation; Inhalation may cause corrosive injuries to upper respiratory tract; May cause skin sensitization; Harmful by ingestion; Toxic by skin absorption; Oral LD50 (rat) = 630-1,260 mg/kg; Dermal LD50 (rabbit) = 500-1,000 mg/kg; [Sigma-Aldrich MSDS] Search for (1592-20-7[EC/RN Number]) AND (dermatitis OR allergic OR sensitizer OR sensitization): no results; [PubMed]
Hazard Classes and CategoriesAcute Tox. 4 (100%)
Toxicology
Adverse EffectsDermatotoxin - Skin burns.
Safety data
- F
- 8-19
- PPE
- Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- UN 3265 8/PG 3
- hs_code
- 29039990
- risk_code
- 34-43-21/22
- Signal word
- Danger
- Symbol(GHS)
- GHS05,GHS06
- hazard_code
- C
- safety_code
- 26-36/37/39-45
- hazard_class
- 8
- Storage Class
- 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
- packing_group
- III
- Hazard statements
- H302-H311-H314-H317
- Hazard Classifications
- Acute Tox. 3 DermalAcute Tox. 4 OralEye Dam. 1Skin Corr. 1BSkin Sens. 1
- Precautionary statements
- P261-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338
Chemistry & industry
Uses & manufacturing
U.S. Production2023: 1,000,000 - <5,000,000 lb
Industry UsesIntermediate
General Manufacturing Information
All Other Chemical Product and Preparation Manufacturing
Benzene, 1-(chloromethyl)-4-ethenyl-: ACTIVE
Benzene, (chloromethyl)ethenyl-: ACTIVE
Applications
UsesComponent of ion exchange resins, photo-resist polymers, cross-linkable fibers, coupling agents and electroconducting polymers.Starter for various copolymer preparations.Dual functional monomer. Readily derivatized by chloride displacement.
Upstream & downstream products
Upstream raw materials
Downstream products
Suppliers100 total
国药集团化学试剂有限公司86-21-63210123 · [email protected]
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Related reactions
103 records
Compound notes
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