Isopropyllithium
Basic information
- CAS
1888-75-1- Standard SMILES
C[CH-]C.[Li+]- InChIKey
SZAVVKVUMPLRRS-UHFFFAOYSA-N- Molecular formula
- C3H7Li
- Average molar mass
- 50.1 g/mol
- Monoisotopic mass
- 50.07077866
Names & identifiers
- Preferred name
- Isopropyllithium
- IUPAC
- lithium propane
- English name
- Isopropyllithium
- Molecular formula
- C3H7Li
- Molecular weight
- 50.03
Names & synonyms
Isopropyllithium1888-75-1EINECS 217-561-4RefChem:792253217-561-4Lithium, (1-methylethyl)- (9CI)lithium,propanelithium propan-2-ide(propan-2-yl)lithiumisopropyl lithiumi-PrLiSCHEMBL107926
Show more names
2-Propyllithium2-Lithiopropane(1-Methylethyl)lithiumisopropyllithiumsolutionIsopropyllithium 8% in PentaneISOPROPYLLITHIUM 1.7M IN PENTANEIsopropyllithiumsolutioninPentane
Lithium,(1-methylethyl)-(9ci)DTXSID40940390HDSLTIHESBGENB-UHFFFAOYSA-NSZAVVKVUMPLRRS-UHFFFAOYSA-NAKOS025294796NS00081164Isopropyllithium, Isopropyllithium solution, lithium, (1-methylethyl)-, 529745_ALDRICH, MolPort-003-935-966, CID74678, EINECS 217-561-4, CID6093461, InChI=1/C3H7.Li/c1-3-2;/h3H,1-2H3, 1888-75-1
Database identifiers
- CAS
1888-75-1- PubChem CID
- 74678
- DTXSID
DTXSID40940390- EC Number
- 217-561-4
- Nikkaji
- J199.711D
Properties
Computed structural properties
- Topological polar surface area
- 0 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 1
- Rotatable bonds
- 0
- Heavy atoms
- 4
- Formal charge
- 0
- Complexity
- 3.2
Physicochemical properties
- Melting point
- 99 · 99-100℃
- Boiling point
- 35 · 35-36 °C
- Density
- 0.632 g/mL · 0.632 g/mL at 25 °C
- Flash point
- 31 °F · −31 °F
- storage temp.
- 2 · 2-8°C
- InChI
- 1S/C3H7.Li/c1-3-2;/h3H,1-2H3;
- InChIKey
- HDSLTIHESBGENB-UHFFFAOYSA-N
- SMILES
- [Li]C(C)C
- UNSPSC Code
- 12352103 · 12352103
- NACRES
- 22 · NA.22
- Symbol(GHS)
- 2 · GHS02,GHS05,GHS07,GHS08,GHS09
- Signal word
- Danger
- Hazard statements
- 224 · H224-H304-H315-H318-H336-H411
- Precautionary statements
- 210 · P210-P261-P273-P280-P301+P310-P305+P351+P338
- target organs
- Central nervous system
- Hazard Codes
- F+,C,N,Xn,F
- Risk Statements
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H250 (39.1%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]
P210, P222, P223, P231, P231+P232, P233, P260, P264, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 64 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Hazard Classes and CategoriesPyr. Liq. 1 (39.1%)
Safety data
- wgk
- 1
- ridadr
- UN 2924 3/PG 1
- risk_code
- 12-14-20/22-34-67-66-65-51/53-11
- Signal word
- Danger
- Symbol(GHS)
- GHS02,GHS05,GHS07,GHS08,GHS09
- hazard_code
- F+,C,N,Xn,F
- safety_code
- 16-33-36/37/39-45-62-61
- Storage Class
- 4.3 - Hazardous materials which set free flammable gases upon contact with water
- target organs
- Central nervous system
- Hazard statements
- H224-H304-H315-H318-H336-H411
- Hazard Classifications
- Aquatic Chronic 2Asp. Tox. 1Eye Dam. 1Flam. Liq. 1Skin Irrit. 2STOT SE 3
- Precautionary statements
- P210-P261-P273-P280-P301+P310-P305+P351+P338
Chemistry & industry
Applications
UsesUsed in a study of the alkylative ring opening of N-sulfonyl protected aziridines providing amino alcohols and ethers.
UsesIsopropyllithium is used in a study of the alkylative ring opening of N-sulfonyl protected aziridines providing amino alcohols and ethers.
Upstream & downstream products
Downstream products
Related reactions
0 records
No reaction records under the current filter.
Compound notes
Loading…