Propylmagnesium chloride
Basic information
- CAS
2234-82-4- Standard SMILES
[CH2-]CC.[Cl-].[Mg+2]- InChIKey
AMXVKMXLDJXAPM-UHFFFAOYSA-M- Molecular formula
- C3H7ClMg
- Average molar mass
- 102.84 g/mol
- Monoisotopic mass
- 102.0086696
Names & identifiers
- Preferred name
- Propylmagnesium chloride
- IUPAC
- magnesium;propane;chloride
- English name
- Propylmagnesium chloride
- Molecular formula
- C3H7ClMg
- Molecular weight
- 102.85
Names & synonyms
2234-82-4propylmagnesium chlorideMagnesium, chloropropyl-Chloropropylmagnesiumn-Propylmagnesium chlorideEINECS 218-785-55MGU4Y7G7XEC 218-785-5DTXSID00883815Magnesium, chloropropylnPropylmagnsium chlorideRefChem:869864
Show more names
Chlorpropylmagnesiumn-PropylMagnesiuM chchloropropyl-magnesiuPropylchloromagnesiumsol.,2.0mindiethyletherMagnesium,chloropropyl-Propylmangesium chloride
CHLORO(PROPYL)MAGNESIUMDTXCID101023301218-785-5PrMgClUNII-5MGU4Y7G7Xpropylmagnesiumchloriden-PrMgClnPr-MgCl
Database identifiers
- CAS
2234-82-4- PubChem CID
- 75225
- DTXSID
DTXSID00883815- EC Number
- 218-785-5
Properties
Computed structural properties
- Topological polar surface area
- 0 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 2
- Rotatable bonds
- 0
- Heavy atoms
- 5
- Formal charge
- 0
- Complexity
- 6.9
Experimental & physicochemical properties
Chemical ClassesMetals -> Metals, Organic Compounds
Physicochemical properties
- Boiling point
- 148 · 148-150 °C(Press: 15 Torr)
- Density
- 0.83 g/mL · 0.83 g/mL at 20 °C
- Flash point
- 40 °F · −40 °F
- form
- solution
- Water Solubility
- Reacts with water.
- Sensitive
- Air & Moisture Sensitive
- BRN
- 3600246 · 3600246
- InChI
- InChI=1S/C3H7.ClH.Mg/c1-3-2;;/h1,3H2,2H3;1H;/q;;+1/p-1
- InChIKey
- AMXVKMXLDJXAPM-UHFFFAOYSA-M
- SMILES
- C([Mg]Cl)CC
- FDA UNII
- 5 MGU4Y7G7X · 5MGU4Y7G7X
- EPA Substance Registry System
- Magnesium, chloropropyl- (2234-82-4)
- UNSPSC Code
- 12352103 · 12352103
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
This chemical does not meet GHS hazard criteria for 2.2% (1 of 45) of reports.
Danger
H225 (11.1%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P231+P232, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 45 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Regulatory InformationREACH registered substance: Chloropropylmagnesium (EC: 218-785-5)
Hazards SummaryReacts with water evolving flammable gases that may spontaneously ignite; Causes burns; [ECHA REACH Registrations] See Methylmagnesium chloride and Bromopropylmagnesium.
Hazard Classes and CategoriesWater-react. 2 (95.6%)
Toxicology
Adverse EffectsDermatotoxin - Skin burns.
Safety data
- wgk
- 1
- tsca
- TSCA listed
- ridadr
- UN 3399 4.3/PG 1
- hs_code
- 29319090
- risk_code
- 12-14/15-22-34-66-67-19-11
Chemistry & industry
Uses & manufacturing
UsesUsed as a reagent in chemical manufacturing (introduce the n-propyl group); [ECHA REACH Registrations]
General Manufacturing InformationMagnesium, chloropropyl-: ACTIVE
Applications
UsesPropylmagnesium Chloride is a useful reagent for the preparation of 4-(2,4-bis(2-Hydroxyphenyl)-1H-imidazol-1-yl)benzoic Acid derivatives as novel iron chelators.
UsesGrignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
General DescriptionThis product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.
Upstream & downstream products
Downstream products
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Compound notes
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