Basic information
- CAS
2325-27-1- Standard SMILES
c1ccc(N=P(c2ccccc2)(c2ccccc2)c2ccccc2)cc1- InChIKey
PTLOPIHJOPWUNN-UHFFFAOYSA-N- Molecular formula
- C24H20NP
- Average molar mass
- 353.4 g/mol
- Monoisotopic mass
- 353.13333664
Names & identifiers
- Preferred name
- N-(triphenylphosphoranylidene)aniline
- IUPAC
- triphenyl(phenylimino)-λ5-phosphane
- English name
- Tetraphenylphosphine imide
- Molecular formula
- C24H20NP
- Molecular weight
- 353.4
Names & synonyms
N-(Triphenylphosphoranylidene)anilineEINECS 219-039-1N-(Triphenylphosphoranylidene)benzenamineDTXSID80177820NSC 110604RefChem:828742DTXCID40100311219-039-12325-27-1Tetraphenylphosphine imideBenzenamine, N-(triphenylphosphoranylidene)-(Phenylimino)triphenylphosphorane
Show more names
triphenyl(phenylimino)-N-Tetraphenylphosphine imideANILIDENETRIPHENYLPHOSPHORANEN-Phenyltriphenylphosphine imideN-Phenyltriphenylphosphine imine
Phosphine imide, tetraphenyl-Tetraphenylphosphiniminetriphenyl(phenylimino)-lambda5-phosphane6L9PT46NGVTriphenylphosphine phenylimideMFCD00003044NSC-110604N,1,1,1-tetraphenyl-lambda5-phosphanimine
Database identifiers
- CAS
2325-27-1- PubChem CID
- 75352
- DTXSID
DTXSID80177820- UNII
- 6L9PT46NGV
- EC Number
- 219-039-1
- Nikkaji
- J1.797.718K、J116.886J
Properties
Computed structural properties
- XLogP
- 6.5
- Topological polar surface area
- 12.4 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 1
- Rotatable bonds
- 4
- Heavy atoms
- 26
- Formal charge
- 0
- Complexity
- 408
Physicochemical properties
- Melting point
- 130 °C · 130°C
- solubility
- 25 mg/mL, · chloroform: soluble25mg/mL, clear to slightly hazy (colorless to brown)
- Water Solubility
- 25 mg/mL · Insoluble in water. Soluble in chloroform 25 mg/mL.
- Sensitive
- Moisture Sensitive
- BRN
- 753032 · 753032
- InChI
- 1S/C24H20NP/c1-5-13-21(14-6-1)25-26(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H
- InChIKey
- PTLOPIHJOPWUNN-UHFFFAOYSA-N
- SMILES
- c1ccc(cc1)N=P(c2ccccc2)(c3ccccc3)c4ccccc4
- FDA UNII
- 6 L9PT46NGV · 6L9PT46NGV
- UNSPSC Code
- 12352100 · 12352100
- NACRES
- 22 · NA.22
- Symbol(GHS)
- 7 · GHS07
- Signal word
- Warning
- Hazard statements
- 315 · H315-H319-H335
- Precautionary statements
- 261 · P261-P264-P271-P280-P302+P352-P305+P351+P338
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 43 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Hazard Classes and CategoriesSkin Irrit. 2 (100%)
Safety data
- PPE
- dust mask type N95 (US), Eyeshields, Gloves
- wgk
- 3
- risk_code
- 36/37/38
- Signal word
- Warning
- Symbol(GHS)
- GHS07
- hazard_code
- Xi
- safety_code
- 26-37/39
- Storage Class
- 11 - Combustible Solids
- target organs
- Respiratory system
- Hazard statements
- H315-H319-H335
- Hazard Classifications
- Eye Irrit. 2Skin Irrit. 2STOT SE 3
- Precautionary statements
- P261-P264-P271-P280-P302+P352-P305+P351+P338
Chemistry & industry
Applications
UsesN-(Triphenylphosphoranylidene)aniline is used in the preparation of new novel iminophosphoranes.
UsesThe Staudinger Ligation: A High-Yield, Chemoselective, and Mild Synthetic MethodIntermediate for the preparation of isocyanates and isothiocyanates.
General DescriptionN-(Triphenylphosphoranylidene)aniline was reported as a new electrolyte additive for high performance lithium cobalt oxide (LiCoO2) electrodes during high voltage operations in lithium ion batteries.
Upstream & downstream products
Downstream products
Suppliers11 total
阿法埃莎（中国）化学有限公司400-6106006 · [email protected]
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
烟台正信新材料科技有限公司13854547682 13854547682 · [email protected]
无锡丽恒昇生物医药科技有限公司15250805028 15250805028 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
江苏艾康生物医药研发有限公司025-58859352 19370895928 · [email protected]
上海安屹诺生物医药科技有限公司021-34625901 · [email protected]
Related reactions
0 records
No reaction records under the current filter.
Compound notes
Loading…