Allylmagnesium chloride

HCID 75804CAS 2622-05-1
Substructure searchFind similar structures

Basic information

Standard SMILES
C=C[CH2-].[Cl-].[Mg+2]
InChIKey
PLYLAFITHJUEGX-UHFFFAOYSA-M
Molecular formula
C3H5ClMg
Average molar mass
100.83 g/mol

Names & identifiers

Preferred name
Allylmagnesium chloride
IUPAC
magnesium;prop-1-ene;chloride
English name
Allylmagnesium chloride
Molecular formula
C3H5ClMg
Molecular weight
100.83

Names & synonyms

Allylmagnesium chloride2622-05-1Magnesium, chloro-2-propen-1-yl-Magnesium, chloro-2-propenyl-EINECS 220-067-1DTXSID4062561EC 220-067-1RefChem:554919Magnesium, chloro2propenylMagnesium, chloro2propen1ylDTXCID3037468220-067-1
Show more names
0/1/22ChloroallylmagnesiumAllylmagnesiumchloridAllyl chlorideMagnesiuMchloro-2-propenyl-magnesiuPropenylmagnesium chloride2-Propenylmagnesium chloride
Allylchloromagnesiummagnesium;prop-1-ene;chloride2-propenyl magnesium chlorideAllylmagnesium chloride 1M in THFAllylmagnesium chloride 2M in THFChlorido(prop-2-en-1-yl)magnesiumAllylmagnesium chloride, 1M in MeTHFallyl-magnesium chloride

Database identifiers

CAS
2622-05-1
PubChem CID
75804
DTXSID
DTXSID4062561
EC Number
220-067-1

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
0
Heavy atoms
5

Experimental & physicochemical properties

Chemical ClassesMetals -> Metals, Organic Compounds
Physical Description2 Molar solution in tetrahydrofuran: Liquid; [Sigma-Aldrich MSDS]

Physicochemical properties

Melting point
-21 °C · -21°C
Boiling point
66 °C · 66°C
Density
0.995 g/mL · 0.995 g/mL at 25 °C
Flash point
1 °F · 1 °F
storage temp.
water-free area
form
Liquid

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H225 (40.5%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P222, P223, P231, P231+P232, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 84 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 3 items

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

REACH registered substance: Allylmagnesium chloride (EC: 220-067-1)

Magnesium, chloro-2-propenyl-: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1 item

2 Molar solution in tetrahydrofuran (CAS# 109-99-9): Reacts violently with water; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS] See Vinylmagnesium chloride and Methylmagnesium chloride.

Hazard Classes and CategoriesFlam. Liq. 2 (40.5%)

Toxicology

Adverse EffectsDermatotoxin - Skin burns.

Safety data

F
1-3-10
PPE
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
wgk
1
tsca
TSCA listed
ridadr
UN 3399 4.3/PG 1
hs_code
29319090

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationMagnesium, chloro-2-propen-1-yl-: ACTIVE
Applications · 1 item

UsesAllylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.

Upstream & downstream products

Suppliers50 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]

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