Silver(I) trifluoromethanesulfonate
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Basic information
- CAS
2923-28-6- Standard SMILES
O=S(=O)([O-])C(F)(F)F.[Ag+]- InChIKey
QRUBYZBWAOOHSV-UHFFFAOYSA-M- Molecular formula
- CAgF3O3S
- Average molar mass
- 256.94 g/mol
- Monoisotopic mass
- 255.85712
Names & identifiers
- Preferred name
- Silver(I) trifluoromethanesulfonate
- IUPAC
- silver trifluoromethanesulfonate
- English name
- Silver trifluoromethanesulfonate
- Molecular formula
- CAgF3O3S
- Molecular weight
- 256.94
Names & synonyms
Silver trifluoromethanesulfonateSilver(I) trifluoromethanesulfonateSilver trifluoromethylsulfonateUK2MGY9YSFMethanesulfonic acid, trifluoro-, silver(1+) saltDTXSID5062716NSC-225087RefChem:1098551DTXCID4037958ARGENTIO TRIFLUOROMETHANESULFONATE220-882-22923-28-6
Show more names
TRIFLUOROMETHYLSULFONYLOXYSILVERSilver (trifluoromethyl)sulfonateTRIFLUOROMETHANESULFONIC ACID SILVER SALTfonatever trifLuoromethanesuLSilver(I)triflate
Silver triflateagotfSilver (I) Trifluoromethane SulfonateCAgF3O3SSilver trifluoromethanesulphonateMethanesulfonic acid, 1,1,1-trifluoro-, silver(1+) salt (1:1)silver(1+) trifluoromethanesulfonateMFCD00013226
Database identifiers
- CAS
2923-28-6- PubChem CID
- 76223
- DTXSID
DTXSID5062716- UNII
- UK2MGY9YSF
- EC Number
- 220-882-2
- Nikkaji
- J163E
Properties
Computed structural propertiesFilling in
- Topological polar surface area
- 65.6 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 6
- Rotatable bonds
- 0
- Heavy atoms
- 9
- Formal charge
- 0
- Complexity
- 145
Physicochemical properties
- Melting point
- 286 °C · 286 °C (lit.)
- storage temp.
- 30 °C · Store below +30°C.
- solubility
- Methanol (Slightly), Water (Slightly)
- form
- Powder
- color
- White to light beige
- Water Solubility
- Soluble in water and also in most organic solvents.
- Sensitive
- Light Sensitive
- Hydrolytic Sensitivity
- 6 · 6: forms irreversible hydrate
- BRN
- 3598402 · 3598402
- Stability
- Stable, but may be light sensitive. Incompatible with strong acids, strong oxidizing agents.
- InChI
- InChI=1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
- InChIKey
- QRUBYZBWAOOHSV-UHFFFAOYSA-M
- SMILES
- C(F)(F)(F)S([O-])(=O)=O.[Ag+]
- CAS DataBase Reference
- 2923 · 2923-28-6(CAS DataBase Reference)
- FDA UNII
- 2 MGY9YSF · UK2MGY9YSF
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
Safety data
- F
- 8
- PPE
- dust mask type N95 (US), Eyeshields, Gloves
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- 3260
- hs_code
- 28432900
- risk_code
- 36/37/38-50-34
- Signal word
- Danger
- Symbol(GHS)
- GHS05
- hazard_code
- Xi,C
- hazard_note
- Corrosive
- safety_code
- 26-36-61-45-36/37/39
- hazard_class
- 8
- Storage Class
- 11 - Combustible Solids
- Hazard statements
- H315-H318
- Hazard Classifications
- Eye Dam. 1Skin Irrit. 2
- Precautionary statements
- P264-P280-P302+P352-P305+P351+P338-P332+P313-P362+P364
Chemistry & industry
Applications
UsesSilver Trifluoromethanesulfonate is used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. It is also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes.
General DescriptionSilver trifluoromethanesulfonate p-complexes of monoenes, dienes, trienes, monoynes and diynes have been prepared. It reacts with 2-fluoro- and 3-fluoro-4-alkoxystilbazoles to afford the mesomorphic complexes. Iodine monochloride/AgOTf constitutes an efficient promoter system for the O-glycoside synthesis.
Upstream & downstream products
Upstream raw materials
Downstream products
Related reactions
149 records
Compound notes
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