Silver trifluoroacetate
Basic information
- CAS
2966-50-9- Standard SMILES
O=C([O-])C(F)(F)F.[Ag+]- InChIKey
KZJPVUDYAMEDRM-UHFFFAOYSA-M- Molecular formula
- C2AgF3O2
- Average molar mass
- 220.88 g/mol
- Monoisotopic mass
- 219.8901359
Names & identifiers
- Preferred name
- Silver trifluoroacetate
- IUPAC
- silver 2,2,2-trifluoroacetate
- English name
- Silver trifluoroacetate
- Molecular formula
- C2AgF3O2
- Molecular weight
- 220.88
Names & synonyms
Silver trifluoroacetate2966-50-9Acetic acid, 2,2,2-trifluoro-, silver(1+) salt (1:1)NSC 9447EINECS 221-004-0DTXSID7062748RefChem:183052DTXCID5038042Acetic acid, trifluoro, silver(1+) saltAcetic acid, 2,2,2trifluoro, silver(1+) salt (1:1)221-004-0Silver(1+) trifluoroacetate
Show more names
AgTFASilver 2,2,2-trifluoroacetateSilvertrifluoroacetate98%Trifluoroacetoxysilver(I)Silver trifluoroacetate 98%SILVER TRIFLUOROACETIC ACIDSilvertrifluoroacetate,min.98%
SILVER(I) 2,2,2-TRIFLUOROACETATETrifluoroacetic acid silver saltSILVER(I) TRIFLUOROACETATETrifluoroacetic acid, silver saltsilver;2,2,2-trifluoroacetateSilver perfluoroacetateSilver mono(trifluoroacetate)Acetic acid, trifluoro-, silver(1+) salt
Database identifiers
- CAS
2966-50-9- PubChem CID
- 76299
- DTXSID
DTXSID7062748- EC Number
- 221-004-0
- Nikkaji
- J306.888I
Properties
Computed structural properties
- Topological polar surface area
- 40.1 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 5
- Rotatable bonds
- 0
- Heavy atoms
- 8
- Formal charge
- 0
- Complexity
- 77.9
Experimental & physicochemical properties
Chemical ClassesMetals -> Organic Acids, Metal Salts
Physical DescriptionWhite odorless powder; Hygroscopic and soluble in water; [Alfa Aesar MSDS]
Physicochemical properties
- Melting point
- 257 · 257-260 °C (dec.) (lit.)
- storage temp.
- 30 °C · Store below +30°C.
- form
- Crystalline Powder
- color
- Light beige to gray
- Water Solubility
- SOLUBLE
- Sensitive
- Hygroscopic
- BRN
- 3634022 · 3634022
- InChI
- InChI=1S/C2HF3O2.Ag/c3-2(4,5)1(6)7;/h(H,6,7);/q;+1/p-1
- InChIKey
- KZJPVUDYAMEDRM-UHFFFAOYSA-M
- SMILES
- C(F)(F)(F)C(=O)O[Ag]
- CAS DataBase Reference
- 2966 · 2966-50-9(CAS DataBase Reference)
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H300 (84.8%): Fatal if swallowed [Danger Acute toxicity, oral]
P261, P264, P264+P265, P270, P271, P273, P280, P301+P316, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Regulatory InformationSilver trifluoroacetate: Does not have an individual approval but may be used under an appropriate group standard
Hazards SummaryA skin and strong eye irritant; [Alfa Aesar MSDS] See Sodium fluoroacetate.
Hazard Classes and CategoriesAcute Tox. 2 (84.8%)
Safety & protection
Exposure Control and Personal Protection0.01 [mg/m3], inhalable fraction (salts), as Ag[German Research Foundation (DFG)]
Threshold Limit Values (TLV)0.01 [mg/m3], as Ag (compounds)
Permissible Exposure Limit (PEL)0.01 [mg/m3], as Ag
Immediately Dangerous to Life or Health (IDLH)10.0 [mg/m3], as Ag
Chemistry & industry
Uses & manufacturing
General Manufacturing InformationAcetic acid, 2,2,2-trifluoro-, silver(1+) salt (1:1): ACTIVE
Applications
UsesSilver Trifluoroacetate functions as a catalyst in the synthesis of cyclobutene-fused azepines/dihydropyridines.
Upstream & downstream products
Upstream raw materials
Downstream products
Related reactions
113 records
Compound notes
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