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2-Ethoxy-3,4-dihydro-2H-pyran

HCID 7676
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Substructure searchFind similar structures

Basic information

CAS
103-75-3
Standard SMILES
CCOC1CCC=CO1
InChIKey
VZJFPIXCMVSTID-UHFFFAOYSA-N
Molecular formula
C7H12O2
Average molar mass
128.17 g/mol
Monoisotopic mass
128.08372962

Overview

Ethoxydihydropyran is a colorless liquid. Floats on water. (USCG, 1999)

Names & identifiers

Preferred name
2-Ethoxy-3,4-dihydro-2H-pyran
IUPAC
2-ethoxy-3,4-dihydro-2H-pyran
English name
2-Ethoxy-3,4-dihydro-2H-pyran
Molecular formula
C7H12O2
Molecular weight
128.17

Names & synonyms

2-Ethoxy-3,4-dihydro-2H-pyran103-75-32-Ethoxypyran2-Ethoxydihydropyran2H-Pyran, 2-ethoxy-3,4-dihydro-2-Ethoxy-2,3-dihydro-4H-pyranETHOXYDIHYDROPYRAN3,4-Dihydro-2-ethoxy-2H-pyran2-Ethoxy-3,4-dihydropyran2-Ethoxy-3,4-dihydro-2-pyran3,4-dihydro-2-ethoxy-2H-pyrane2-Ethoxy-2,3-dihydro(4H)pyran
Show more names
2-ethoxy-3,4-dihydro-2h-pyra3,4-Ehydro-2-methoxy-2H-pyran
2-Ethoxy-3,4-dihydro-1,2-pyran3,4-Dihydro-2H-pyran-2-yl ethyl ether2-Ethoxy-2,3-dihydro-gamma-pyranNSC 6271MFCD000065612-Ethoxy-2,3-dihydro-.gamma.-pyranNSC-6271K6DS120547

Database identifiers

CAS
103-75-3
PubChem CID
7676
DTXSID
DTXSID40883293
UNII
K6DS120547
EC Number
203-141-8
Nikkaji
J51.178A

Properties

Computed structural properties

XLogP
1.5
Topological polar surface area
18.5 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
2
Heavy atoms
9
Formal charge
0
Complexity
99.1

Experimental & physicochemical properties

Chemical ClassesOther Classes -> Ethers, Other
Density · 2 items

0.875 at 68 °F (USCG, 1999) - Less dense than water; will float

0.970 @ 20 °C/20 °C

Color/FormLIQUID
SolubilityVERY SLIGHTLY SOL IN WATER
Flash Point · 2 items

98 °F (USCG, 1999)

111 °F OC.

Boiling Point · 2 items

289 °F at 760 mmHg (USCG, 1999)

143 °C

Melting Point · 2 items

-148 °F (USCG, 1999)

FP: -100 °C

Physical Description · 2 items

Ethoxydihydropyran is a colorless liquid. Floats on water. (USCG, 1999)

Colorless liquid; [CAMEO]

Physicochemical properties

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P264, P264+P265, P280, P302+P352, P303+P361+P353, P305+P351+P338, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P235, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 41 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information2-Ethoxy-3,4-dihydro-2H-pyran: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelFlammable Liquid
Fire HazardsExcerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Fire PotentialCOMBUSTIBLE. MODERATE FIRE RISK.
Health HazardsContact with liquid irritates eyes. Also irritates skin on prolonged contact. (USCG, 1999)
Hazards SummaryAn eye irritant; [CAMEO] An irritant; [MSDSonline]
Reactive GroupEthers
Reactivity Profile · 1 item

Ethers, such as ETHOXYDIHYDROPYRAN can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

Chemistry & industry

Uses & manufacturing

Uses · 2 items

Used as stabilizer and intermediate; [HSDB]

STABILIZER; INTERMEDIATE

General Manufacturing Information2H-Pyran, 2-ethoxy-3,4-dihydro-: ACTIVE

Applications

UsesStabilizer, intermediate.

General DescriptionColorless liquid. Floats on water.

Upstream & downstream products

Upstream raw materials

AcroleinEthyl vinyl ether

Downstream products

Glutaraldehyde

Suppliers67 total

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
阿诺西(上海)生物技术有限公司400-1107768 15058188853 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
湖北鑫杰成化工科技有限公司13554075426 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.

Related reactions

0 records
New reaction record

No reaction records under the current filter.

Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Melting point
153 · 153-155 °C
Boiling point
42 °C16 · 42 °C16 mm Hg(lit.)
Density
0.957 g/mL · 0.957 g/mL at 25 °C(lit.)
refractive index
20 · n20/D 1.439(lit.)
Flash point
76 °F · 76 °F
storage temp.
2 · 2-8°C
form
liquid
color
Yellow
InChI
1S/C7H12O2/c1-2-8-7-5-3-4-6-9-7/h4,6-7H,2-3,5H2,1H3
InChIKey
VZJFPIXCMVSTID-UHFFFAOYSA-N
SMILES
CCOC1CCC=CO1
CAS DataBase Reference
103 · 103-75-3(CAS DataBase Reference)
EWG's Food Scores
1 · 1
FDA UNII
6 DS120547 · K6DS120547
EPA Substance Registry System
2 H-Pyran, · 2H-Pyran, 2-ethoxy-3,4-dihydro- (103-75-3)
UNSPSC Code
12352100 · 12352100
Symbol(GHS)
7 · GHS07,GHS02
Signal word
Warning
Hazard statements
319 · H319-H226
Precautionary statements
210 · P210-P370+P378-P233-P240-P241+P242+P243-P264-P280-P303+P361+P353-P305+P351+P338+P337+P313-P403+P235-P501
PPE
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes
Xi,F
Risk Statements
10 · 10-36/38-11
Safety Statements
26 · 26-16
RIDADR
3271 · UN 3271 3/PG 3
WGK Germany
2 · 2
RTECS
8925000 · UP8925000
TSCA
TSCA listed
HazardClass
3.2 · 3.2
PackingGroup
III
HS Code
29329990 · 29329990
Storage Class
3 · 3 - Flammable liquids
Hazard Classifications
3 · Flam. Liq. 3
Hazardous Substances Data
103 · 103-75-3(Hazardous Substances Data)
Air and Water ReactionsFlammable.
Hazard Classes and CategoriesFlam. Liq. 3 (100%)

Safety & protection

Fire FightingFire Extinguishing Agents Not to Be Used: Water may be ineffective.
First AidEYES: flush with water for at least 15 min.
Nonfire Spill ResponseExcerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Isolation and EvacuationExcerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Personal Protective Equipment (PPE)Goggles or face shield; rubber gloves. (USCG, 1999)

Toxicology

Adverse EffectsNeurotoxin - Acute solvent syndrome
Human Toxicity ExcerptsMODERATELY TOXIC.
Toxicity DataLCLo (rat) = 8,000 ppm/4h

Safety data

PPE
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk
2
tsca
TSCA listed
rtecs
UP8925000
ridadr
UN 3271 3/PG 3
hs_code
29329990
risk_code
10-36/38-11
Signal word
Warning
Symbol(GHS)
GHS07,GHS02
hazard_code
Xi,F
safety_code
26-16
hazard_class
3.2
Storage Class
3 - Flammable liquids
packing_group
III
Hazard statements
H319-H226
Hazard Classifications
Flam. Liq. 3
Precautionary statements
P210-P370+P378-P233-P240-P241+P242+P243-P264-P280-P303+P361+P353-P305+P351+P338+P337+P313-P403+P235-P501
Hazardous Substances Data
103-75-3(Hazardous Substances Data)
+86-0571-88938639 17705817739 · [email protected]
河南英田生物科技有限公司0370-4053511; 18339993703 · [email protected]
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天津希恩思生化科技有限公司400 638 7771 · [email protected]
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深圳康特腾科技有限公司86-0755-86635001 · [email protected]
越林试剂021-62960152 · [email protected]
北京京土恒盛化工科技有限公司00-13911456598 13911456598 · [email protected]
上海丽康新材料有限公司+86-16631818819 +86-17736933208 · [email protected]
PT CHEM GROUP LIMITED+86-85511178; +86-85511178 · [email protected]
上海孚一生物科技有限公司+86 (21) 61124340
青岛海智微元生物科技有限公司18317699790 18317699790 · [email protected]
天津荣燊化工有限公司18317763565; 18317763565 · [email protected]
湖北赛恩斯化工有限公司15994282563 15994282563 · [email protected]
九鼎化学(上海)科技有限公司4009209199 · [email protected]
Henan Alfa Chemical Co., Ltd+8618339805032 · [email protected]
广东翁江化学试剂有限公司0751-2815987 13927875076 · [email protected]
陕西缔都医药化工有限公司029-029-81120477 17792793610 · [email protected]
武汉福鑫化工有限公司+86-2759207851; +86-18007136271 · [email protected]
河南沃咖斯生物科技有限公司18537671377 · [email protected]
湖北美钡新材料有限公司18271819653 · [email protected]
南通市苏北化工原料有限公司0513-85290972 18762756250 · [email protected]
武汉克米克生物医药技术有限公司027-13163388153 13163388153 · [email protected]
湖北世腾化工科技有限公司19086915685 18971850150 · [email protected]
泰安市嘉叶生物科技有限公司15318151873;13127280945 · [email protected]
武汉弘德悦欣医药科技有限公司027-83850116 18164090116 · [email protected]
Shaanxi Didu New Materials Co. Ltd+86-86-17392712779 +86-13289823923 · [email protected]
杭州洁汉化工有限公司+86-571-86217390; +8618058761490 · [email protected]
Shanghai Daken Advanced Materials Co.,Ltd+86-2158073036 · [email protected]
江苏艾康生物医药研发有限公司025-58859352 19370895928 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
天津希恩思生化科技有限公司400-6387771-6039 18920764717 · [email protected]
河南阿尔法化工有限公司0371-55051623 18137891487 · [email protected]
合肥天健化工有限公司+86-0551-65418679 +86-18949832763 · [email protected]
career henan chemical co+86-0371-86658258 · [email protected]
武汉欣扬瑞和化学科技有限公司15926260361 · [email protected]
TCI Chemicals (India) Pvt. Ltd.[email protected]