Basic information
- CAS
3317-67-7- Standard SMILES
[Co+2].c1ccc2c(c1)-c1nc-2nc2[n-]c(nc3nc(nc4[n-]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21- InChIKey
MPMSMUBQXQALQI-UHFFFAOYSA-N- Molecular formula
- C32H16CoN8
- Average molar mass
- 571.5 g/mol
- Monoisotopic mass
- 571.082986
Names & identifiers
- Preferred name
- Cobalt phthalocyanine
- IUPAC
- cobalt(2+);2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene
- English name
- COBALT(II) PHTHALOCYANINE
- Molecular formula
- C32H16CoN8
- Molecular weight
- 571.46
Names & synonyms
3317-67-7Cobalt phthalocyanineCobalt(II) phthalocyanineCobaltous phthalocyaninePhthalocyaninatocobalt(II)Cobalt(2+) phthalocyanineDTXSID5062972Cobalt, (29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32)-, (SP-4-1)-RefChem:127216DTXCID8038643222-012-7Cobalt phthalocyanin
Show more names
COPCPCCOPigmentBlue75Cobalt PhtalocyaninePHTHALOCYANINE COBALTCobalt(II) phtalocyanineCOBALT(+2)PHTHALOCYANINE
Phthalocyanine Cobalt(II)MFCD00010718Cobalt(II) Phthalocyanine (purified by sublimation)(Phthalocyaninato(2-))cobaltNSC 187643Cobalt, [29H,31H-phthalocyaninato(2-)-.kappa.N29,.kappa.N30,.kappa.N31,.kappa.N32]-, (SP-4-1)-cobalt(2+);2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaeneC32H16CoN8
Database identifiers
Properties
Computed structural properties
- Topological polar surface area
- 79.3 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 8
- Rotatable bonds
- 0
- Heavy atoms
- 41
- Formal charge
- 0
- Complexity
- 709
Experimental & physicochemical properties
Chemical ClassesDyes -> Phthalocyanine Dyes
Physical DescriptionDark odorless powder; [Alfa Aesar MSDS]
Physicochemical properties
- Melting point
- 300 °C · >300 °C
- Density
- 0.677 g/cm3 · 0.677g/cm3
- storage temp.
- -20 °C · Store at -20°C
- solubility
- 1 mg/mL · DMSO: < 1 mg/mL (insoluble or slightly soluble)
- form
- crystal
- color
- purple
- Water Solubility
- Insoluble in water.
- Hydrolytic Sensitivity
- 4 · 4: no reaction with water under neutral conditions
- BRN
- 4121847 · 4121847
- Stability
- Stable. Incompatible with strong oxidizing agents.
- InChIKey
- MPMSMUBQXQALQI-UHFFFAOYSA-N
- SMILES
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
This chemical does not meet GHS hazard criteria for 72.6% (127 of 175) of all reports.
Warning
H351 (25.1%): Suspected of causing cancer [Warning Carcinogenicity]
P203, P280, P318, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 175 reports by companies from 4 notifications to the ECHA C&L Inventory.
Hazard information
Regulatory InformationREACH registered substance: [29H,31H-phthalocyaninato-N29,N30,N31,N32]cobalt (EC: 222-012-7)
Hazards SummaryAn irritant; May cause skin sensitization; Suspected of causing genetic defects; [Alfa Aesar MSDS] See Cobaltocene.
Hazard Classes and CategoriesCarc. 2 (25.1%)
Safety data
- wgk
- 3
- tsca
- TSCA listed
- hs_code
- 29339900
- risk_code
- 40
- Signal word
- Warning
- Symbol(GHS)
- GHS08
- hazard_code
- Xn
- safety_code
- 36/37
- Hazard statements
- H351
- REACH Registrations
- Active
- Precautionary statements
- P201-P308+P313
Chemistry & industry
Uses & manufacturing
General Manufacturing InformationCobalt, [29H,31H-phthalocyaninato(2-)-.kappa.N29,.kappa.N30,.kappa.N31,.kappa.N32]-, (SP-4-1)-: ACTIVE
Applications
DescriptionCobalt phthalocynine (CoPc) is a member of metal phthalocyanines (MPcs) are frequently used in manyorganic electronic devices such as light-emitting diodes (LEDs), organic photovoltaics (OPVs), organic field-effect transistors (OFETs) and chemical sensors as a p-type semiconducting material. Compared to otherhole-injection layer (HIL) materials, most metal phthalocyanines are water and air stable, thermally stable, and nontoxic.They can be sublimed or sputtered with highly uniform, thin films on a variety of substrates. The synthesis of such materials are also relatively inexpensive and easy to prepare. The chemical structure of MPc allows tuning of its ionisation potential orHOMO levels by altering the central atom in Pc macrocycles.
UsesCobalt(II) phthalocyanine may be used to develop carbon black based electrocatalysts. CoPC may be used as an end capping agent of a hyperbranched poly(aryl ether ketone) to be used for oxidative decomposition of 2,4,6,-trichlorophenol. CoPC modified carbon paste may be used as indicators for electrocatalytic amperometric measurements. ZnO impregnated with CoPC may be used as a sensitizer to determine the photodegradation of cyanide in aqueous suspension. CoPC catalyzed aerobic regenerations of aldehydes and ketones have been investigated.
General DescriptionCobalt(II) phthalocyanine (CoPC )is a metallopthalocyanine.
Suppliers100 total
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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