HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,2-Hydrazinedicarboxamide
Hydrazodicarbonamide · 1,2-hydrazinedicarboxamide · DIUREA · Biurea · p-urazine · Biurea,99% · Ureidourea · dicarbamide
Identifiers & Physical Properties
| CAS No. | 110-21-4 |
|---|---|
| Molecular formula | C2H6N4O2 |
| Average molar mass | 118.1 g/mol |
| Monoisotopic mass | 118.04907543 g/mol |
| SMILES | NC(=O)NNC(N)=O |
| InChIKey | ULUZGMIUTMRARO-UHFFFAOYSA-N |
| PubChem CID | 8039 |
| ChEMBL | CHEMBL3188383 |
| EC No. | 203-747-2 |
| DTXSID | DTXSID6024628 |
Chemical & Physical Properties
| XLogP | -2.1 |
|---|---|
| Topological polar surface area | 110 |
| Hydrogen bond donors | 4 |
| Hydrogen bond acceptors | 2 |
| Rotatable bonds | 0 |
| Heavy atoms | 8 |
| Formal charge | 0 |
| Complexity | 96.6 |
| Chemical classes | Nitrogen Compounds -> Other Nitrogen Compounds |
| SpringerMaterials Properties | Crystal structure |
| LogP (partition coefficient) | log Kow = -2.37 /Estimated/ |
| Color/Form | Plates from water |
| Solubility | less than 1 mg/mL at 66 °F (NTP, 1992)In water, 238 mg/L at 16 °CSulfuric Acid (Sparingly, Heated) |
| Melting point | 471 to 473 °F (NTP, 1992)258 °C247-250 °C |
| Vapor pressure | 0.0000595 [mmHg]5.9X10-5 mm Hg at 25 °C /Estimated/ |
| Henry's law constant | Henry's Law constant = 1X10-19 atm-cu m/mol at 25 °C /Estimated/ |
| Physical Description | Biurea is a white powder. (NTP, 1992)White solid[CAMEO] |
| Other Experimental Properties | Hydroxyl radical reaction rate constant = 4.0X10-12 cu cm/molec-sec at 25 °C /Estimated/ |
| Boiling point | 220.6°C (rough estimate) |
| Density | 1.6040 |
| Refractive index | 1.4462 (estimate) |
| Storage conditions | Sealed in dry,Room Temperature |
| pKa (acidity coefficient) | 10.06±0.43(Predicted) |
| Physical state | Solid |
| Color | White to Off-White |
| CAS DataBase Reference | 110-21-4(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | POJ4UOY01H |
| EPA Substance Registry System | Biurea (110-21-4) |
| GHS pictogram | GHS07 |
| Signal word | Warning |
| GHS hazard statements | H303-H315-H319-H335 |
| GHS precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 24/25 |
| TSCA inventory status | TSCA listed |
| Hazard class | IRRITANT |
| Customs code | 29280000 |
| Hazardous substances data | 110-21-4(Hazardous Substances Data) |
| Toxicity | LD50 oral in rat: > 2gm/kg |
Safety & Regulations
| GHS classification | This chemical does not meet GHS hazard criteria for 88.1% (37 of 42) of all reports.WarningH315 (11.9%): Causes skin irritation [Warning Skin corrosion/irritation]P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 42 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatory information | Chemical: 1,2-Hydrazinedicarboxamide |
| Fire hazards | The flash point of this compound is not available, however it is probably non-flammable. (NTP, 1992) |
| Hazards summary | May cause irritation[MSDSonline] |
| Reactive group | Amides and Imides |
| Reactivity Profile | BIUREA is chemically classified as an amide. Amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx). |
| Air and Water Reactions | Insoluble in water. |
| Hazard Classes and Categories | Skin Irrit. 2 (11.9%) |
| Fire fighting | Fires associated with this compound should be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992) |
| First aid | EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. |
Applications & Uses
Uses
Hydrazine-1,2-dicarboxamide is a useful compound in the process of producing protected anode active material particles for rechargeable lithium batteries.
General Description
White powder.