HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Bromoethyl methyl ether
2-BROMOETHYL METHYL ETHER · 2-METHOXYETHYL BROMIDE · Methoxyethyl bromide · BROMOETHYL METHYL ETHER · 2-Bromoethyl methyl ethe · TIMTEC-BB SBB007906 · 1-BROMO-2-METHOXYETHANE · 1-METHOXY-2-BROMOETHANE
Identifiers & Physical Properties
| CAS No. | 6482-24-2 |
|---|---|
| Molecular formula | C3H7BrO |
| Average molar mass | 138.99 g/mol |
| Monoisotopic mass | 137.96803 g/mol |
| SMILES | COCCBr |
| InChIKey | YZUPZGFPHUVJKC-UHFFFAOYSA-N |
| PubChem CID | 80972 |
| EC No. | 229-339-4 |
| DTXSID | DTXSID0064385 |
Chemical & Physical Properties
| XLogP | 0.8 |
|---|---|
| Topological polar surface area | 9.2 |
| Hydrogen bond donors | 0 |
| Hydrogen bond acceptors | 1 |
| Rotatable bonds | 2 |
| Heavy atoms | 5 |
| Formal charge | 0 |
| Complexity | 16 |
| Physical Description | Colorless or pale yellow liquid[Alfa Aesar MSDS] |
| Kovats Retention Index | 696716.2 |
| Boiling point | 40-41 °C/66 mmHg (lit.) |
| Density | 1.479 g/mL at 25 °C (lit.) |
| Refractive index | n20/D 1.447(lit.) |
| Flash point | 83 °F |
| Storage conditions | 2-8°C |
| Solubility | water: soluble14.4g/L at 25°CSoluble in water.14,4 g/L at 25°C |
| Physical state | Liquid |
| Specific gravity | 1.479 |
| Color | Clear colorless to yellow |
| InChI | InChI=1S/C3H7BrO/c1-5-3-2-4/h2-3H2,1H3 |
| InChIKey | YZUPZGFPHUVJKC-UHFFFAOYSA-N |
| SMILES | C(Br)COC |
| CAS DataBase Reference | 6482-24-2(CAS DataBase Reference) |
| FDA UNII | QMC9NTS6GR |
| NIST Chemistry Reference | Ethane, 1-bromo-2-methoxy(6482-24-2) |
| EPA Substance Registry System | Ethane, 1-bromo-2-methoxy- (6482-24-2) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
| GHS pictogram | GHS02,GHS06 |
| Signal word | Danger |
| GHS hazard statements | H226-H301-H315-H319-H335 |
| GHS precautionary statements | P210-P301+P310+P330-P302+P352-P305+P351+P338 |
| Target organs | Respiratory system |
| Personal protective equipment (PPE) | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
| Hazard symbols | Xi,F,Xn |
| Risk statements (R) | 10-36/37/38-22 |
| Safety statements (S) | 16-26-37/39 |
| UN transport number | UN 3271 3/PG 3 |
| Water hazard class (WGK) | 3 |
| Hazard Note | Irritant/Flammable |
| TSCA inventory status | TSCA listed |
| Hazard class | 3Acute Tox. 3 OralEye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3 |
| Packing group | III |
| Customs code | 29091990 |
| Storage class | 3 - Flammable liquids |
| Limited quantities | 1.0 L (0.3 gallon) (liquid) |
| Excepted quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
Safety & Regulations
| GHS classification | DangerH226 (100%): Flammable liquid and vapor [Warning Flammable liquids]H301 (83.7%): Toxic if swallowed [Danger Acute toxicity, oral]H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]H335 (98%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposureRespiratory tract irritation]P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P280, P301+P316, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 49 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| Hazards summary | A skin and strong eye irritantA lachrymator[Alfa Aesar MSDS] See beta-Chloroethyl methyl ether. |
| Peroxide Forming Chemical | 2-Bromoethyl methyl etherD: Other compounds that may form peroxidesKelly |
| Hazard Classes and Categories | Flam. Liq. 3 (100%)Acute Tox. 3 (83.7%)Skin Irrit. 2 (100%)Eye Irrit. 2 (100%)STOT SE 3 (98%) |
| Adverse effects | Lacrimator (Lachrymator) - A substance that irritates the eyes and induces the flow of tears. |
| Personal protective equipment (PPE) | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
| Water hazard class (WGK) | 3 |
| TSCA inventory status | TSCA listed |
| UN transport number | UN 3271 3/PG 3 |
| Customs code | 29091990 |
| Risk statements (R) | 10-36/37/38-22 |
| Signal word | Danger |
| GHS pictogram | GHS02,GHS06 |
| Hazard symbols | Xi,F,Xn |
| hazard_note | Irritant/Flammable |
| Safety statements (S) | 16-26-37/39 |
| Hazard class | 3Acute Tox. 3 OralEye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3 |
| Storage class | 3 - Flammable liquids |
| Packing group | III |
| Target organs | Respiratory system |
| GHS hazard statements | H226-H301-H315-H319-H335 |
| Limited quantities | 1.0 L (0.3 gallon) (liquid) |
| Excepted quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
| GHS precautionary statements | P210-P301+P310+P330-P302+P352-P305+P351+P338 |
Applications & Uses
Uses
2-Bromoethyl methyl ether has been used as starting reagent in the synthesis of 1-bromo-4-(2-methoxyethoxy)benzene and 1-bromo-4-[(2-methoxyethoxy)methyl]benzene.
Uses
1-Bromo-2-methoxyethane has been used as starting reagent in the synthesis of 1-bromo-4-(2-methoxyethoxy)benzene and 1-bromo-4-[(2-methoxyethoxy)methyl]benzene.
General Description
Kinetics of potassium iodide exchange reaction with 2-bromoethyl methyl ether in acetone at 15 and 25°C has been investigated.