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Ferrous bromide

HCID 82240
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Substructure searchFind similar structures

Basic information

CAS
7789-46-0
Standard SMILES
[Br-].[Br-].[Fe+2]
InChIKey
GYCHYNMREWYSKH-UHFFFAOYSA-L
Molecular formula
Br2Fe
Average molar mass
215.65 g/mol
Monoisotopic mass
213.77161

Overview

Iron(II) bromide is a chemical compound of iron and bromine. It is useful synthetic intermediate. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625, L653)

Names & identifiers

Preferred name
Ferrous bromide
IUPAC
iron(2+) dibromide
English name
IRON (II) BROMIDE
Molecular formula
Br2Fe
Molecular weight
215.65

Names & synonyms

Iron(II) bromide7789-46-0UNII-EA3X054RBZEA3X054RBZEINECS 232-168-8RefChem:57875232-168-8Ferrous bromideIron dibromideIRON (II) BROMIDEiron(2+);dibromideMFCD00016081
Show more names
FeBr2IRON BROMIDEIron(II)bromide,ultradry,99.995%(metalsbasis)Dibromoironironbromide(febr2)Iron Bromide PowderIron bromide (FeBr2)
Br2FeDibromoiron; Ferrous Bromide,;Iron Dibromide;FERRUM BROMATUMFERROUS BROMIDE, ANHYDROUS, 99.999%SCHEMBL96654FERROUS BROMIDE [MI]FERRUM BROMATUM [HPUS]AKOS015832994

Database identifiers

CAS
7789-46-0
PubChem CID
82240
UNII
EA3X054RBZ
EC Number
232-168-8
Nikkaji
J43.817K

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
0
Heavy atoms
3
Formal charge
0
Complexity
0

Experimental & physicochemical properties

Chemical ClassesMetals -> Metals, Inorganic Compounds
SpringerMaterials Propertiesdielectric constant
Physical DescriptionLight yellow to dark brown hygroscopic solid; Soluble in water; [Merck Index] Yellow odorless granules; Hygroscopic and soluble in water; [Alfa Aesar MSDS]

Physicochemical properties

Melting point
684 °C · 684 °C(lit.)
Boiling point
934 °C · 934 °C(lit.)
Density
4.63 g/mL · 4.63 g/mL at 25 °C(lit.)
storage temp.
2 · Storage temp. 2-8°C
solubility
ethanol: very soluble(lit.)
form
beads
color
Yellow
Specific Gravity
4.636 · 4.636
Water Solubility
Soluble in water, THF, methanol, ethanol.
Sensitive

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Danger

H302 (11.1%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 45 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazards SummaryCauses burns; Harmful by ingestion; [Alfa Aesar MSDS] See Iron salts, soluble.
Hazard Classes and CategoriesSkin Corr. 1B (15.6%)

Safety & protection

Threshold Limit Values (TLV)1.0 [mg/m3], as Fe

Toxicology

Treatment · 1 item

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Chemistry & industry

Pharmacology

Metabolism/Metabolites · 1 item

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

Uses & manufacturing

Uses · 2 items

Used as a polymerization catalyst; [Merck Index]

Iron(II) bromide is useful synthetic intermediate. (L653)

Applications

UsesIron(II) bromide is used as a polymerization catalyst. It is used in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications.

General DescriptionThis product has been enhanced for catalytic efficiency.

Preparation methods

PreparationIron(II) bromide can be prepared by the direct reaction of bromine or hydrogen bromide with iron at red heat.

Upstream & downstream products

Downstream products

Calcium bromide

Suppliers86 total

北京华美互利生物化工010-56205725 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Hygroscopic
Merck
14 · 14,4042
Exposure limits
1 mg/m3NIOSH: · ACGIH: TWA 1 mg/m3NIOSH: TWA 1 mg/m3
Stability
hygroscopic
Major Application
electroplatingmaterial synthesis precursor
InChI
InChI=1S/2BrH.Fe/h2*1H;/q;;+2/p-2
InChIKey
GYCHYNMREWYSKH-UHFFFAOYSA-L
SMILES
[Fe+2].[Br-].[Br-]
CAS DataBase Reference
7789 · 7789-46-0(CAS DataBase Reference)
FDA UNII
3 X054RBZ · EA3X054RBZ
EPA Substance Registry System
Iron bromide (FeBr2) (7789-46-0)
UNSPSC Code
12352302 · 12352302
NACRES
23 · NA.23
Symbol(GHS)
7 · GHS07,GHS05
Signal word
Warning
Hazard statements
315 · H315-H319-H332-H335-H302-H314-H318
Precautionary statements
261 · P261-P305+P351+P338-P280-P309-P310-P310a
PPE
95 · dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes
Xn
Risk Statements
20 · 20-36/37/38
Safety Statements
26 · 26-36
RIDADR
3260 · UN3260
WGK Germany
3 · 3
TSCA
TSCA listed
HazardClass
8 · 8
PackingGroup
III
HS Code
28275900 · 28275900
Storage Class
11 · 11 - Combustible Solids
Health Effects · 1 item

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Adverse EffectsDermatotoxin - Skin burns.
Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1 item

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1 item

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

Safety data

PPE
dust mask type N95 (US), Eyeshields, Gloves
wgk
3
tsca
TSCA listed
ridadr
UN3260
hs_code
28275900
risk_code
20-36/37/38
Signal word
Warning
Symbol(GHS)
GHS07,GHS05
hazard_code
Xn
safety_code
26-36
hazard_class
8
Storage Class
11 - Combustible Solids
packing_group
III
Hazard statements
H315-H319-H332-H335-H302-H314-H318
Precautionary statements
P261-P305+P351+P338-P280-P309-P310-P310a
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]
武汉英诺医药科技有限公司+86-027-59232304 15387063101 · [email protected]
毕佳索(上海毕得医药科技股份有限公司)400-6005915 · [email protected]
咸宁深蓝生物医药研发有限公司18171815831 · [email protected]
杭州品高化工有限公司0571-87658025 · [email protected]
南京修合医药科技有限公司19848384152 · [email protected]
上海毕得医药科技股份有限公司400-1647117 13681763483 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]
湖北云镁科技有限公司027-59206672 18327059871 · [email protected]
Aladdin Scientific[email protected]
阿法埃莎(中国)化学有限公司400-6106006 · [email protected]
安耐吉化学&3A(安徽泽升科技股份有限公司)400-0056266 · [email protected]
欧利希(湖北)医药科技有限公司17316404525 17316404525 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
山东西亚化学有限公司13355009207 13355009207 · [email protected]
上海健超生物科技有限公司15021035486 18081542813 · [email protected]
玛雅试剂+86 (573) 82222445 (0)18006601000 452520369 · [email protected]
天津希恩思生化科技有限公司400 638 7771 · [email protected]
ZHEJIANG JIUZHOU CHEM CO., LTD+86-0576225566889 +86-13454675544 · [email protected];[email protected];[email protected]
上海和宁美生物医药科技有限公司021-18019086215 18019086215 · [email protected]
赛默飞世尔科技(中国)有限公司800-810-5118 · [email protected]
北京伊诺凯科技有限公司400-810-7969 010-59572699 · [email protected]
江阴市贝壳化学有限公司15312220685 · [email protected]
武汉锦烁达新材料有限公司19292735370 19292735370 · [email protected]
苏州亚科科技股份有限公司0512-87182055 13451648594 · [email protected]
成都零六生物科技有限公司400-1166-196 13458535857 · [email protected]
雷丁试剂0510-85629785 18013409632 · [email protected]
天津普西唐生物医药科技有限公司010-60605840 · [email protected]
上海麦克林生化科技股份有限公司15221275939 15221275939 · [email protected]
青岛海智微元生物科技有限公司18317699790 18317699790 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
武汉多普乐生物医药有限公司+86-02787215551 19945035818 · [email protected]
上海源叶生物科技有限公司18916372613 · [email protected]
武汉市承天精细化工有限公司18164098996 · [email protected]
上海颖心实验室设备有限公司021-021-59178156 15300768757 · [email protected]
山东西亚化学有限公司4009903999 13395398332 · [email protected]
河北贞佳新材料有限公司0319-5925599 13315915972 · [email protected]
上海巍涛化工有限公司02150630626 17717886015 · [email protected]
广州市金华大化学试剂有限公司020-84383047 · [email protected]
Shaanxi Dideu New Materials Co. Ltd18192503167 · [email protected]
陕西缔都医药化工有限公司029-81154043 17391733319 · [email protected]
Shanghai Acmec Biochemical Technology Co., Ltd.+86-18621343501 · [email protected]
Shaanxi Didu New Materials Co. Ltd+86-86-17392712779 +86-13289823923 · [email protected]
无锡鸣鹭医药科技有限公司0510-88726693 · [email protected]
湖北鑫鸣泰化学有限公司177-7179-1433 17771741533 · [email protected]
江苏艾康生物医药研发有限公司025-66113011 19370895928 · [email protected]
上海易恩化学技术有限公司400-400-1332688 18019345275 · [email protected]