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Strontium zirconium oxide (SrZrO3)

HCID 82852
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Basic information

CAS
12036-39-4
Standard SMILES
[O]=[Zr]([O-])[O-].[Sr+2]
InChIKey
FCCTVDGKMTZSPU-UHFFFAOYSA-N
Molecular formula
O3SrZr
Average molar mass
226.84 g/mol
Monoisotopic mass
225.795055

Names & identifiers

Preferred name
Strontium zirconium oxide (SrZrO3)
IUPAC
strontium dioxido(oxo)zirconium
English name
STRONTIUM ZIRCONATE
Molecular formula
O3SrZr
Molecular weight
226.84

Names & synonyms

12036-39-4EINECS 234-847-4RefChem:186108DTXCID001436842DTXSID701014251Strontium zirconium oxide (SrZrO3)Strontium zirconateStrontium zirconium trioxidestrontium;dioxido(oxo)zirconiumSTRONTIUM ZIRCONIUM OXIDESCHEMBL56892O3SrZr
Show more names
Strontiumzirconate,95%STRONTIUM (II) ZIRCONATEStrontium zirconate powderzirconate(zro32-),strontium(1:1)

Database identifiers

CAS
12036-39-4
PubChem CID
82852
EC Number
234-847-4

Properties

Computed structural properties

Topological polar surface area
63.2 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
3
Rotatable bonds
0
Heavy atoms
5
Formal charge
0
Complexity
18.8

Experimental & physicochemical properties

Chemical ClassesMetals -> Metals, Inorganic Compounds
SpringerMaterials Propertiesdielectric constant
Physical DescriptionWhite odorless powder; Insoluble in water; [Alfa Aesar MSDS]

Physicochemical properties

Melting point
2700 ℃ · 2700℃
Boiling point
9000 ℃ · 9000℃
Density
5.46 g/cm3 · 5.46 g/cm3
refractive index
2.08 · 2.08
form
powder
color
White to off-white
Water Solubility
Solubility in water is negligible.
Exposure limits
5 mg/m3; · ACGIH: TWA 5 mg/m3; STEL 10 mg/m3NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference
12036 · 12036-39-4(CAS DataBase Reference)

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Warning

H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]

P264+P265, P280, P305+P351+P338, and P337+P317 (click each P-code to see the statement)

Aggregated GHS information provided per 2 reports by companies from 1 notifications to the ECHA C&L Inventory.

Hazard information

Regulatory InformationREACH registered substance: Strontium zirconium trioxide (EC: 234-847-4)
Hazards SummaryMay cause irritation; [Alfa Aesar MSDS] See Strontium and Magnesium zirconate.
Hazard Classes and CategoriesEye Irrit. 2 (100%)

Safety & protection

Exposure Control and Personal Protection1.0 [mg/m3], inhalable fraction (metal and insol. cmpds.)[German Research Foundation (DFG)]
Threshold Limit Values (TLV) · 2 items

5.0 [mg/m3], as Zr

10.0 [mg/m3], as Zr

Permissible Exposure Limit (PEL)5.0 [mg/m3], as Zr (compounds)
Immediately Dangerous to Life or Health (IDLH)25.0 [mg/m3], as Zr

Safety data

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationStrontium zirconium oxide (SrZrO3): ACTIVE
Applications · 4 items

DescriptionStrontium zirconate, as mixed metal oxides with different structural characteristics can be widely applied in the field of electronic ceramics and refractory materials of high melting temperatures, and also can be applied in fuel cells and hydrogen sensors due to their proton conductivity at high temperatures. The performance of strontium zirconate would be related to powder purity, crystal structure and size, which mainly depends on synthesis procedure. The synthesis routes for obtaining strontium with similar purity, homogeneity and chemical composition can fall into solid and wet methods, including conventional solid state reaction, combustion process, co-precipitation, hydrothermal methods, the Pechini process and citrate complexation.

UsesStrontium zirconate was most actively investigated concerning the possibility of its use in magnetohydrodynamic plants. The components of these plants experience the effect of high-temperature (up to 2700°C) high-speed (above 1000 msec) gas flow and electromagnetic fields and are in contact with alkaline additive, oxidizing reactants, and zirconium dioxide electrodes. Strontium zirconate proved to be suitable for such service conditions. Strontium zirconate has been the subject of several investigations because of its technological applications. For instance, Strontium zirconate can be used in the electronic industry as insulators, and its refractory properties are of interest in high-temperature applications. In nuclear safety studies, Strontium zirconate plays an important role as it is formed in the UOz fuel by reaction between the fission products in the fuel matrix, and during core-concrete interactions between the fission products and the oxidized zircaloy cladding. The thermodynamic properties, the structural variants and phase transitions are thus of special interest as they influence the behaviour of hazardous fission products. SrZrO3 (SZO) has been the subject of investigations because of its technological applications. For instance, the wide band gap and high dielectric constant of SZO can be used in the electronic industry, and its refractory properties are of interest in high-temperature applications. Moreover, SZO thin films may be regarded as one of the most promising candidate materials used in optoelectronic devices because of the wide band gap and transparent to visible light.

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Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
EPA Substance Registry System
Strontium zirconium oxide (SrZrO3) (12036-39-4)
Symbol(GHS)
7 · GHS07
Signal word
Warning
Hazard statements
319 · H319
Precautionary statements
264 · P264-P280-P305+P351+P338-P337+P313P
WGK Germany
3 · 3
TSCA
TSCA listed
REACH Registrations
Active
wgk
3
tsca
TSCA listed
Signal word
Warning
Symbol(GHS)
GHS07
Hazard statements
H319
REACH Registrations
Active
Precautionary statements
P264-P280-P305+P351+P338-P337+P313P

UsesMostly as intermediates( primary and secondary ). For chemical research.

UsesElectronics.