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Gallium bromide (GaBr3)

HCID 83477
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Basic information

CAS
13450-88-9
Standard SMILES
[Br][Ga]([Br])[Br]
InChIKey
SRVXDMYFQIODQI-UHFFFAOYSA-K
Molecular formula
Br3Ga
Average molar mass
309.44 g/mol
Monoisotopic mass
305.68059

Overview

Gallium(III) bromide is a chemical compound of gallium and bromine. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625)

Names & identifiers

Preferred name
Gallium bromide (GaBr3)
IUPAC
tribromogallane
English name
GALLIUM(III) BROMIDE
Molecular formula
Br3Ga
Molecular weight
309.43

Names & synonyms

Gallium(III) bromide13450-88-9Gallium bromide (GaBr3)tribromogallaneGaBr3Gallium bromideTribromogalliumGallium (III) Bromide, anhydrousEINECS 236-609-5NSC 94001Gallium bromide, GaBr3SCHEMBL150912
Show more names
ribromogallaneGALLIUM TRIBROMIDEGallium(lll) bromidegalliumbromide(gabr3)Gallium(III) Tribromide
DTXSID2065466Gallium(III) bromide, ultra dryNSC94001Gallium(III) bromide, 99.999%NSC-94001Q2175117Gallium(III) bromide, anhydrous, powder, 99.999% trace metals basisGallium(III) bromide, ultra dry, 99.99% (metals basis), crystalline, ampouled

Database identifiers

CAS
13450-88-9
PubChem CID
83477
DTXSID
DTXSID2065466
EC Number
236-609-5

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
0
Rotatable bonds
0
Heavy atoms
4
Formal charge
0
Complexity
8

Experimental & physicochemical properties

Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical DescriptionWhite, odorless crystalline solid; [MSDSonline]

Physicochemical properties

Melting point
121.5 °C · 121.5 °C(lit.)
Boiling point
279 °C · 279 °C(lit.)
Density
3.69 g/mL · 3.69 g/mL at 25 °C(lit.)
Flash point
278.8 °C · 278.8°C
storage temp.
2 · under inert gas (nitrogen or Argon) at 2-8°C
solubility
2 O: · H2O: slightly soluble(lit.)
form
powder
color
White
Specific Gravity
3.69 · 3.69
Water Solubility
Soluble in water.
Sensitive
Moisture Sensitive
Stability
Stable, but reacts violently with water. Avoid contact with water, moisture, strong oxidizing agents. May discolour in air.

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 43 reports by companies from 2 notifications to the ECHA C&L Inventory.

Hazard information

Regulatory InformationChemical: Gallium bromide (GaBr3)
Other Safety InformationEvaluation - Chemicals not considered for in depth evaluation - Not commercially active in Australia
Hazards SummaryReacts violently with water; A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline] See Bromine.
Hazard Classes and CategoriesSkin Corr. 1B (100%)

Toxicology

Treatment · 1 item

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Chemistry & industry

Pharmacology

Metabolism/Metabolites · 1 item

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

Uses & manufacturing

General Manufacturing InformationGallium bromide (GaBr3): INACTIVE

Applications

UsesGallium(III) bromide is used as organic intermediates. It is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes.

UsesGallium(III) bromide may be used to catalyze the coupling of indoles with phenylacetylene to form 1,1-bis(1H-3-indolyl)-1-phenylethanes.

Upstream & downstream products

Downstream products

Gallium(III) trifluoromethanesulfonate

Related reactions

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Compound notes

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Major Application
electroplatingmaterial synthesis precursor
InChI
1S/3BrH.Ga/h3*1H;/q;;;+3/p-3
InChIKey
SRVXDMYFQIODQI-UHFFFAOYSA-K
SMILES
Br[Ga](Br)Br
CAS DataBase Reference
13450 · 13450-88-9(CAS DataBase Reference)
EPA Substance Registry System
Gallium bromide (GaBr3) (13450-88-9)
UNSPSC Code
12352302 · 12352302
NACRES
23 · NA.23
Symbol(GHS)
5 · GHS05
Signal word
Danger
Hazard statements
314 · H314
Precautionary statements
280 · P280-P305+P351+P338-P310
PPE
3 · Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes
C
Risk Statements
14 · 14-34
Safety Statements
8 · 8-26-36/37/39-45
RIDADR
3260 · UN 3260 8/PG 2
WGK Germany
3 · 3
TSCA
TSCA listed
HazardClass
8 · 8
PackingGroup
II
HS Code
2827590000 · 2827590000
Storage Class
8 A · 8A - Combustible corrosive hazardous materials
Hazard Classifications
1 B · Skin Corr. 1B
Health Effects · 1 item

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Adverse EffectsDermatotoxin - Skin burns.
Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1 item

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1 item

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

Safety data

PPE
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
wgk
3
tsca
TSCA listed
ridadr
UN 3260 8/PG 2
hs_code
2827590000
risk_code
14-34
Signal word
Danger
Symbol(GHS)
GHS05
hazard_code
C
safety_code
8-26-36/37/39-45
hazard_class
8
Storage Class
8A - Combustible corrosive hazardous materials
packing_group
II
Hazard statements
H314
Hazard Classifications
Skin Corr. 1B
Precautionary statements
P280-P305+P351+P338-P310