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Yttrium fluoride

HCID 83679
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Basic information

CAS
13709-49-4
Standard SMILES
[F][Y]([F])[F]
InChIKey
RBORBHYCVONNJH-UHFFFAOYSA-K
Molecular formula
F3Y
Average molar mass
145.9011 g/mol
Monoisotopic mass
145.901048

Names & identifiers

Preferred name
Yttrium fluoride
IUPAC
trifluoroyttrium
English name
YTTRIUM FLUORIDE
Molecular formula
F3Y
Molecular weight
145.9

Names & synonyms

Yttrium FluoratumEINECS 237-257-5UNII-V8QS7WES60V8QS7WES60RefChem:58197237-257-513709-49-4Yttrium fluorideYttrium trifluoridetrifluoroyttriumYttrium fluoride (YF3)Yttrium Fluoride, anhydrous
Show more names
Yttrium fLYttriuM fluoridyttriumtrifluorideYttrium fluoride 99yttriumfluoride(yf3)YTTRIUM(III) FLUORIDENano Yttrium Fluoride
Yttrium trifluoride (YF3)Yttrium fluoride, granular,Yttrium fluoride, 99.99%SCHEMBL632630DTXSID2065595YTTRIUM FLUORIDE, 99.9%FCD-546-3Yttrium fluoride, granular, <=1 mm

Database identifiers

CAS
13709-49-4
PubChem CID
83679
DTXSID
DTXSID2065595
EC Number
237-257-5

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
3
Rotatable bonds
0
Heavy atoms
4
Formal charge
0
Complexity
8

Experimental & physicochemical properties

Chemical ClassesMetals -> Rare Earth Metals
SpringerMaterials Propertiespseudobinary system
Physical DescriptionWhite odorless chunks; [MSDSonline]

Physicochemical properties

Melting point
1387 °C · 1387 °C
Density
4.01 g/mL · 4.01 g/mL at 25 °C(lit.)
refractive index
1.54 · 1.54
solubility
2 O · insoluble in H2O
form
powder
color
White
Specific Gravity
4.01 · 4.01
Water Solubility
Soluble in acids. Insoluble in water.
Specific Heat Capacity
0.48 J/ · Cp(gas): 0.48 J/(g·K), at 25℃
Sensitive
Hygroscopic
Crystal Structure
3 type · YF3 type

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 5 items

This chemical does not meet GHS hazard criteria for 4.8% (11 of 228) of reports.

Warning

H302 (19.3%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 228 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 3 items

Chemical: Yttrium fluoride (YF3)

REACH registered substance: Yttrium trifluoride (EC: 237-257-5)

Yttrium fluoride (YF3): Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryAn irritant; Can be absorbed through skin; [MSDSonline] See RARE EARTH METALS and the linked occupational diseases.
Hazard Classes and CategoriesAcute Tox. 4 (19.3%)

Safety & protection

Exposure Control and Personal Protection · 2 items

Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

Threshold Limit Values (TLV)2.5 [mg/m3], as F (1 mg/m3, as Y)

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationYttrium fluoride (YF3): ACTIVE
Applications · 5 items

DescriptionYttrium (III) fluoride (chemical formula: YF3) is an inorganic chemical compound being contained in fluoride mineral. It can be manufactured through the reaction between fluorine with yttria or yttrium hydroxide together with hydrofluoric acid. It is a water insoluble yttrium source which can be used in oxygen-sensitive applications such as metal production. It is useful in ceramics for crucibles for molten reactive metals, in computer displays, automotive fuel sensors, and florescent phosphors. It can also be used for the production of metallic yttrium, thin films, glasses, and ceramics.

UsesYttrium Fluoride is widely applied in metallurgy, ceramics, glass, and electronics. High purity grades are the most important materials for tri-bands Rare Earth phosphors and , which are very effective microwave filters. Yttrium Fluoride also can be used for the production of metallic Yttrium, thin films, glasses and ceramics. Yttrium is used in the production of a large variety of synthetic garnets, and Yttria is used to make Yttrium Iron Garnets, which are very effective microwave filters.

UsesRecent studies include InF3-based glasses, and optical characterization of YF3 thin films.

UsesYttrium(III) fluoride is used for the production of metallic yttrium, thin films, laboratory reagents, catalysts, electrical compounds, glasses and ceramics.

UsesFluorides of rare earths find applications in anti-reflective coatings. They are also used in synthesis of luminescent bio-imaging probes.

Upstream & downstream products

Upstream raw materials

Yttrium oxideHydrogen fluorideCHLORINE TRIFLUORIDE

Related reactions

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Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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crystal system
Nogata
Space group
Pnma
Solubility Product Constant (Ksp)
20.06 · pKsp: 20.06
Lattice constant
a/nm
Symbol(GHS)
7 · GHS07,GHS06
Signal word
Warning
Hazard statements
302 · H302-H312-H331-H302+H312+H332-H315-H319-H335
Precautionary statements
304 · P304+P340-P405-P501a-P261-P280-P305+P351+P338
Hazard Codes
Xn,Xi
Risk Statements
20 · 20/21/22-36/37/38
Safety Statements
26 · 26-37/39
RIDADR
3288 · UN3288
WGK Germany
3 · 3
RTECS
3417500 · ZG3417500
Hazard Note
Irritant
TSCA
TSCA listed
HazardClass
6.1 · 6.1
PackingGroup
III
HS Code
28469036 · 28469036
Storage Class
11 · 11 - Combustible Solids
REACH Registrations
Inactive
Permissible Exposure Limit (PEL)2.5 [mg/m3], as F (1 mg/m3, as Y)

Toxicology

Adverse EffectsFibrogenic - Inducing tissue injury and fibrosis (scarring).

Safety data

wgk
3
tsca
TSCA listed
rtecs
ZG3417500
ridadr
UN3288
hs_code
28469036
risk_code
20/21/22-36/37/38
Signal word
Warning
Symbol(GHS)
GHS07,GHS06
hazard_code
Xn,Xi
hazard_note
Irritant
safety_code
26-37/39
hazard_class
6.1
Storage Class
11 - Combustible Solids
packing_group
III
Hazard statements
H302-H312-H331-H302+H312+H332-H315-H319-H335
REACH Registrations
Inactive
Precautionary statements
P304+P340-P405-P501a-P261-P280-P305+P351+P338
YTTRIUM NITRATE HEXAHYDRATE
carbon monoxide
Carbon dioxide
Trifluoroacetic anhydride