3,3'-Dimethoxy(1,1'-biphenyl)-4,4'-bis(diazonium) dichloride, compound with zinc chloride
Basic information
- CAS
14263-94-6- Standard SMILES
COc1cc(-c2ccc([N+]#N)c(OC)c2)ccc1[N+]#N.[Cl-].[Cl-].[Cl-].[Cl-].[Zn+2]- InChIKey
GPPKNJIWDULNQH-UHFFFAOYSA-J- Molecular formula
- C14H12Cl4N4O2Zn
- Average molar mass
- 475.5 g/mol
- Monoisotopic mass
- 471.900578
Overview
Fast blue salt B is an organic chloride salt composed of 3,3'-dimethoxy[1,1'-biphenyl]-4,4'-bis(diazonium), zinc and chloride ions in a ratio of 1:1:4. Used for detection of marijuana metabolites in urine. It has a role as a histological dye. It is a zinc molecular entity and an organic chloride salt. It contains a zinc dichloride and a fast blue B.
Names & identifiers
- Preferred name
- 3,3'-Dimethoxy(1,1'-biphenyl)-4,4'-bis(diazonium) dichloride, compound with zinc chloride
- IUPAC
- zinc;4-(4-diazonio-3-methoxyphenyl)-2-methoxybenzenediazonium;tetrachloride
- English name
- FAST BLUE B SALT FOR MICROSCOPY
- Molecular formula
- C14H12N4O2.Cl4Zn
- Molecular weight
- 475.48
Names & synonyms
RefChem:1065549DTXSID60233635283-430-33,3'-Dimethoxy(1,1'-biphenyl)-4,4'-bis(diazonium) dichloride, compound with zinc chlorideFast Blue B Salt14263-94-6Azoic diazo 48Fast Blue Salt BDiazo Blue Bzinc;4-(4-diazonio-3-methoxyphenyl)-2-methoxybenzenediazonium;tetrachloride(1,1'-Biphenyl)-4,4'-bis(diazonium), 3,3'-dimethoxy-, (T-4)-tetrachlorozincate(2-) (1:1)[1,1'-Biphenyl]-4,4'-bis(diazonium), 3,3'-dimethoxy-, (T-4)-tetrachlorozincate(2-) (1:1)
Show more names
Fast Blue Bate(2-)(1:1)Echtblausalz BFast Blue B zinc saltFast Blue B Salt (DBB)Azoic Diazo No.48 zinc saltTetrazotized di-2-anisidinefastbluebsalt(dyecontentca.90%)FAST BLUE B SALT FOR MICROSCOPYFastsaltblueBidentischmit#131497
MFCD00075203EINECS 238-153-23,3'-dimethoxy[1,1'-biphenyl]-4,4'-bis(diazonium) chloride--dichlorozinc (1/2/1)3,3'-dimethoxy[1,1'-biphenyl]-4,4'-bis(diazonium) zinc chloride (1/1/4)SCHEMBL5444051CHEBI:87627FF01477(3,3-Dimethoxy(1,1-biphenyl)-4,4'-diyl)bisbenzenediazonium, dichloride, zinc chloride
Properties
Computed structural properties
- Topological polar surface area
- 74.8 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 8
- Rotatable bonds
- 3
- Heavy atoms
- 25
- Formal charge
- 0
- Complexity
- 383
Physicochemical properties
- Melting point
- 300 °C · >300 °C(lit.)
- storage temp.
- 2 · Inert atmosphere,2-8°C
- solubility
- 2 O: · H2O: soluble1mg/mL
- form
- powder
- Colour Index
- 37235 · 37235
- color
- Light yellow to yellow
- ex/em
- 365 nm; · λex 365 nm; λem 420 nm
- BRN
- 1499067 · 1499067
- Stability
- Stable. Incompatible with strong oxidizing agents, alkaline hydroxides. May discolour on exposure to light.
- Major Application
- diagnostic assay manufacturinghematologyhistology
- InChI
- InChI=1S/C14H12N4O2.4ClH.Zn/c1-19-13-7-9(3-5-11(13)17-15)10-4-6-12(18-16)14(8-10)20-2;;;;;/h3-8H,1-2H3;4*1H;/q+2;;;;;+2/p-4
- InChIKey
- GPPKNJIWDULNQH-UHFFFAOYSA-J
- SMILES
- [Zn+2]([Cl-])([Cl-])([Cl-])[Cl-].O(C1=C(C=CC(C2C=CC([N+]#N)=C(OC)C=2)=C1)[N+]#N)C
- EPA Substance Registry System
- 1 · [1,1'-Biphenyl]-4,4'-bis(diazonium), 3,3'-dimethoxy-, (T-4)-tetrachlorozincate(2-) (1:1) (14263-94-6)
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
Safety data
- F
- 8
- PPE
- Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
- wgk
- 3
- tsca
- TSCA listed
- hs_code
- 2927000090
- risk_code
- 45-61-20/21/22
- Signal word
- Danger
- Symbol(GHS)
- GHS02,GHS08
- hazard_code
- T
- safety_code
- 53-45-36/37/39
- Storage Class
- 5.2 - Organic peroxides and self-reacting hazardous materials
- Hazard statements
- H242-H350
- Hazard Classifications
- Carc. 1BSelf-react. C
- Precautionary statements
- P202-P210-P235-P308+P313-P370+P378-P403
Chemistry & industry
Applications
UsesFast Blue B Salt is a stain that is used for the determination of various compounds. It has been used to demonstrate esterase activity. Histochemically it has stained enterochromaffin cells and cells that have gone under free radical oxidative damage. It can be used as reactant/reagent in one pot preparation of phenanthroline-based shape-persistent fluorescent macrocycle using Sonogashira coupling. Dyes and metabolites.
Additional notes
DefinitionChEBI: An organic chloride salt composed of 3,3'-dimethoxy[1,1'-biphenyl]-4,4'-bis(diazonium), zinc and chloride ions in a ratio of 1:1:4. Used for detection of marijuana metabolites in urine.
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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