Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II)
Basic information
- CAS
14564-35-3- Standard SMILES
[C-]#[O+].[C-]#[O+].[Cl-].[Cl-].[Ru+2].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1- InChIKey
PXURRFCLQDNZOY-UHFFFAOYSA-L- Molecular formula
- C38H30Cl2O2P2Ru
- Average molar mass
- 752.6 g/mol
- Monoisotopic mass
- 752.01415
Overview
See also: Dicarbonyldichlorobis(triphenylphosphine)ruthenium (preferred).
Names & identifiers
- Preferred name
- Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II)
- IUPAC
- carbon monoxide;ruthenium(2+);bis(triphenylphosphane);dichloride
- English name
- Dichlorodicarbonylbis(triphenylphosphine)ruthenium (II)
- Molecular formula
- C38H30Cl2O2P2Ru
- Molecular weight
- 752.57
Names & synonyms
Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II)Bis(triphenylphosphine)ruthenium(II) dicarbonyl chlorideDICARBONYLDICHLOROBIS(TRIPHENYLPHOSPHIN&Dichlorodicarbonylbis(triphenylphosphine)Dichlorodicarbonylbis(triphenylphosphine)ruthdicarbonyldichlorobis(triphenylphosphine)-ruthenidicarbonyldichlorobis(triphenylphosphine)rutheniumDichlorodicarbonylbis-(triphenylphosphino)-rutheniumRUTHENIUM(II)-BIS(TRIPHENYLPHOSPHINE)DICHLOROCARBONYLDichlorocarbonylbis(triphenylphosphine)ruthenium (II)Dichlorodicarbonylbis(triphenylphosphine)ruthenium(Ⅱ)
Database identifiers
- CAS
14564-35-3- PubChem CID
- 84526
Properties
Computed structural properties
- Topological polar surface area
- 2 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 4
- Rotatable bonds
- 6
- Heavy atoms
- 45
- Formal charge
- 0
- Complexity
- 233
Physicochemical properties
- Melting point
- 230 · 230-235°C
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Powder
- color
- white
- InChI
- InChI=1S/2C18H15P.2CO.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2;;;/h2*1-15H;;;2*1H;/q;;;;;;+2/p-2
- InChIKey
- PXURRFCLQDNZOY-UHFFFAOYSA-L
- SMILES
- P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.[Ru](Cl)Cl.[O+]#[C-].[O+]#[C-]
- CAS DataBase Reference
- 14564 · 14564-35-3
- EPA Substance Registry System
- Ruthenium, dicarbonyldichlorobis(triphenylphosphine)- (14564-35-3)
- UNSPSC Code
- 12161600 · 12161600
- NACRES
- 22 · NA.22
- PPE
- 95 · Eyeshields, Gloves, type N95 (US)
- Hazard Codes
- Xn
- Risk Statements
- 20 · 20/21/22-36/37/38
- Safety Statements
- 22 · 22-24/25
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
Safety data
- PPE
- Eyeshields, Gloves, type N95 (US)
- wgk
- 3
- tsca
- TSCA listed
- hs_code
- 28439090
- risk_code
- 20/21/22-36/37/38
- hazard_code
- Xn
- safety_code
- 22-24/25
- Storage Class
- 11 - Combustible Solids
Chemistry & industry
Applications
UsesDichlorodicarbonylbis(triphenylphosphine)ruthenium exhibits good catalytic performance in the addition reaction of aromatic ketone carbonyl groups with olefin molecules, and can be widely used as a noble metal catalyst in organic synthesis reactions.
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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