Magnesium, chloro(1-methylpropyl)-
Basic information
- CAS
15366-08-2- Standard SMILES
C[CH-]CC.[Cl-].[Mg+2]- InChIKey
MJHZUYZQMNONPK-UHFFFAOYSA-M- Molecular formula
- C4H9ClMg
- Average molar mass
- 116.87 g/mol
- Monoisotopic mass
- 116.0243197
Names & identifiers
- Preferred name
- Magnesium, chloro(1-methylpropyl)-
- IUPAC
- magnesium;butane;chloride
- English name
- sec-Butylmagnesium chloride
- Molecular formula
- C4H9ClMg
- Molecular weight
- 116.87
Names & synonyms
sec-Butylmagnesium chloride15366-08-2Magnesium, chloro(1-methylpropyl)-Chloro(1-methylpropyl)magnesiumEINECS 239-403-3DTXSID70884834EC 239-403-3RefChem:800664DTXCID801024255239-403-32-Butylmagnesium chlorides-bumgcl
Show more names
25wt%solutioninTHFsec-Butylchloromagnesiumsec-Butylmagnesiumchloridchloro(1-methylpropyl)-magnesiuCentral butyl magnesium chloridesec-butylmagnesium chloride solution
2-butyl magnesium chloridesec-butyl magnesium chloride(Butan-2-yl)chloridomagnesiumSCHEMBL114580(butan-2-yl)(chloro)magnesiumMJHZUYZQMNONPK-UHFFFAOYSA-MAKOS015915539
Database identifiers
- CAS
15366-08-2- PubChem CID
- 84884
- DTXSID
DTXSID70884834- EC Number
- 239-403-3
Properties
Computed structural properties
- Topological polar surface area
- 0 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 2
- Rotatable bonds
- 1
- Heavy atoms
- 6
- Formal charge
- 0
- Complexity
- 11.5
Physicochemical properties
- Boiling point
- 66 °C · 66 °C
- Density
- 0.83 g/mL · 0.83 g/mL at 20 °C
- Flash point
- -21 °C · -21 °C
- storage temp.
- Flammables + water-Freezer (-20°C)e area
- form
- liquid
- color
- dark brown
- Sensitive
- air sensitive, moisture sensitive
- BRN
- 3600265 · 3600265
- InChI
- 1S/C4H9.ClH.Mg/c1-3-4-2;;/h3H,4H2,1-2H3;1H;/q;;+1/p-1
- InChIKey
- MJHZUYZQMNONPK-UHFFFAOYSA-M
- SMILES
- CCC(C)[Mg]Cl
- EPA Substance Registry System
- Magnesium, chloro(1-methylpropyl)- (15366-08-2)
- UNSPSC Code
- 12352103 · 12352103
- NACRES
- 22 · NA.22
- Symbol(GHS)
- 2 · GHS02,GHS05,GHS07
- Signal word
- Danger
- Hazard statements
- 225 · H225-H250-H260-H302-H314-H336
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H225 (33.8%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P222, P223, P231, P231+P232, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 77 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Regulatory Information
REACH registered substance: sec-butylmagnesium chloride (EC: 239-403-3)
Magnesium, chloro(1-methylpropyl)-: Does not have an individual approval but may be used under an appropriate group standard
Hazard Classes and CategoriesFlam. Liq. 2 (33.8%)
Safety data
- F
- 1-3-10
- PPE
- Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
- wgk
- 1
- tsca
- TSCA listed
- ridadr
- UN 3399 4.3/PG 1
- hs_code
- 29319090
- risk_code
- 12-14/15-22-34-66-67-19-11
- Signal word
- Danger
- Symbol(GHS)
- GHS02,GHS05,GHS07
- hazard_code
- F+,C,F
- safety_code
Chemistry & industry
Uses & manufacturing
General Manufacturing InformationMagnesium, chloro(1-methylpropyl)-: ACTIVE
Applications
Usessec-Butylmagnesium chloride solution is a Grignard reagent, it can be used in: Metal catalyzed cross-coupling reactions with non-activated aryl chlorides.The synthesis of various alkoxytrichlorosilanes by reacting with tetrachlorosilane and alcohols.
Upstream & downstream products
Downstream products
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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