Basic information
- CAS
17250-25-8- Standard SMILES
[C-]#[O+].[H-].[Ir].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1- InChIKey
OWVGPTPQWABNND-UHFFFAOYSA-N- Molecular formula
- C55H46IrOP3-
- Average molar mass
- 1,008.1 g/mol
- Monoisotopic mass
- 1,008.23908
Names & identifiers
- Preferred name
- Carbonylhydrotris(triphenylphosphine)iridium
- IUPAC
- carbon monoxide;hydride;iridium;tris(triphenylphosphane)
- English name
- HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
- Molecular formula
- C55H45IrOP3
- Molecular weight
- 1007.08
Names & synonyms
Carbonylhydrotris(triphenylphosphine)iridiumEINECS 241-282-7Iridium, carbonylhydrotris(triphenylphosphine)-Carbonyltris(triphenylphosphine)hydridoiridium(I)RefChem:574583DTXSID10889388DTXCID701782074241-282-717250-25-8CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)Ir18.6%minDichlorodicarbonyl ruthenium
Show more names
carbonylhydrotris(triphenylphosphine)-iridiuHydrocarbonyltris(triphenylphosphine)iridiumHydridocarbonyltris-(triphenylphosphino)-iridiumhydridocarbonyltris (triphenylphosphine) iridiuM
Database identifiers
- CAS
17250-25-8- PubChem CID
- 87018
- EC Number
- 241-282-7
Properties
Computed structural properties
- Topological polar surface area
- 1 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 2
- Rotatable bonds
- 9
- Heavy atoms
- 60
- Formal charge
- -1
- Complexity
- 214
Physicochemical properties
- Melting point
- 170 °C · 170°C (dec.)
- storage temp.
- 2 · under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Soluble in chloroform and toluene
- form
- Powder
- color
- light yellow
- Sensitive
- Moisture Sensitive
- CAS DataBase Reference
- 17250 · 17250-25-8
- EPA Substance Registry System
- Iridium, carbonylhydrotris(triphenylphosphine)- (17250-25-8)
- Symbol(GHS)
- 7 · GHS07
- Signal word
- Danger
- Hazard statements
- 302 · H302-H315-H319-H335
- Precautionary statements
- 261 · P261-P280a-P304+P340-P305+P351+P338-P405-P501a
- Hazard Codes
- Xn
- Risk Statements
- 36 · 36/37/38
- Safety Statements
- 26 · 26-36/37/39
- RIDADR
- 2813 · UN2813
- TSCA
- TSCA listed
- HS Code
- 2843.9 · 2843.90.0000
- HazardClass
- 4.3 · 4.3
- PackingGroup
- III
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H301+H311+H331 (20%): Toxic if swallowed, in contact with skin or if inhaled [Danger Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation]
P261, P262, P264, P264+P265, P270, P271, P280, P301+P316, P301+P317, P302+P352, P304+P340, P305+P351+P338, P316, P319, P321, P330, P332+P317, P337+P317, P361+P364, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 5 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Hazard Classes and CategoriesAcute Tox. 3 (20%)
Safety data
- tsca
- TSCA listed
- ridadr
- UN2813
- hs_code
- 2843.90.0000
- risk_code
- 36/37/38
- Signal word
- Danger
- Symbol(GHS)
- GHS07
- hazard_code
- Xn
- safety_code
- 26-36/37/39
- hazard_class
- 4.3
- packing_group
- III
- Hazard statements
- H302-H315-H319-H335
- Precautionary statements
- P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Chemistry & industry
Uses & manufacturing
General Manufacturing InformationIridium, carbonylhydrotris(triphenylphosphine)-: INACTIVE
Applications
UsesHydridocarbonyltris(triphenylphosphine)iridium (I) (CAS# 17250-25-8) is a useful reagent used for Si-C bond cleavage, and as a catalyst in the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers.
Suppliers54 total
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
清宁生物（江苏博泉生物科技有限公司）王 19352250998 13160238781 · [email protected]
陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
北京索莱宝科技有限公司010-50973130 17801761073 · [email protected]
阿法埃莎（中国）化学有限公司400-6106006 · [email protected]
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
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上海钰康生物科技有限公司+86-18930848214 +86-021-56762820 · [email protected]
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Alfa Chemistry1-516-6625404 · [email protected]
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山东小野化学股份有限公司0539-6362799 20）
上海贤鼎生物科技有限公司021-021-52271985 17721149837 · [email protected]
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career henan chemical co+86-0371-86658258 · [email protected]
上海吉至生化科技有限公司021-4009004166/18616739031 18616739031 · [email protected]
TCI Chemicals (India) Pvt. Ltd.[email protected]
江苏艾康生物医药研发有限公司025-58859352 17714375163 · [email protected]
河南威梯希化工科技有限公司0371-63284658 18135795563 · [email protected]
海蔚化学86-21-51086038 · [email protected]
Aladdin Scientific[email protected]
武汉福鑫化工有限公司027-59207852 13308628970 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
上海凯为化学科技有限公司021-58461859 15821823057 · [email protected]
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Related reactions
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Compound notes
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