CAS 17832-28-9 1,4-Butanediol monovinyl ether (HCID 87329)

Names & identifiers

Preferred name: 1,4-Butanediol monovinyl ether
IUPAC: 4-ethenoxybutan-1-ol
English name: 1,4-Butanediol vinyl ether
Molecular formula: C6H12O2
Molecular weight: 116.16

Names & synonyms

17832-28-91-Butanol, 4-(ethenyloxy)-4-(Vinyloxy)butan-1-ol4-Hydroxybutyl vinyl ether4-(Ethenyloxy)butan-1-ol4-(Vinyloxy)-1-butanolTetramethylene Glycol Monovinyl Ether1,4-Butanediol monovinyl etherDTXSID60448548LGM5RZX0NRAPI-CURE HBVEEINECS 241-793-5

Show more names

HBVEHYDROXYBUTYL VINYL ETHERBUTANEDIOL MONOVINYL ETHER4-VINYLOXYBUTANOL4-Vinyloxy-1-butanol5-Oxa-6-heptene-1-ol4-vinyloxy-butan-1-ol

4-(VINYLOXY)BUTANOL4-ETHENYLOXY-1-BUTANOLDTXCID4024854EC 241-793-51-BUTANOL, 4-(VINYLOXY)-RefChem:4164971,4-Butanediol vinyl ether4-ethenoxybutan-1-ol

Database identifiers

CAS: 17832-28-9
PubChem CID: 87329
DTXSID: DTXSID6044854
ChEMBL: CHEMBL3182123
UNII: 8LGM5RZX0N
EC Number: 241-793-5
Nikkaji: J51.553A

Properties

Computed structural properties

XLogP: 0.9
Topological polar surface area: 29.5 Å²
Hydrogen bond donors: 1
Hydrogen bond acceptors: 2
Rotatable bonds: 5
Heavy atoms: 8
Formal charge: 0
Complexity: 52.5

Experimental & physicochemical properties

SpringerMaterials PropertiesViscosity

Physical DescriptionLiquid

Physicochemical properties

Melting point: -33 °C · -33 °C
Boiling point: 95 °C/20 · 95 °C/20 mmHg (lit.)
Density: 0.939 g/mL · 0.939 g/mL at 25 °C (lit.)
vapor pressure: 0.3 hPa · 0.3 hPa (20 °C)
refractive index: 20 · n20/D 1.444(lit.)
Flash point: 185 °F · 185 °F
storage temp.: 20 °C · Store at <= 20°C.
solubility: 75 g/l · 75g/l
pka: 15.04 · 15.04±0.10(Predicted)
form: clear liquid
color: Colorless to Light yellow
Specific Gravity: 0.93 · 0.93
explosive limit: 1.4 · 1.4-9.9%(V)
Water Solubility: 75 g/L · 75 g/L (20 ºC)
InChI: 1S/C6H12O2/c1-2-8-6-4-3-5-7/h2,7H,1,3-6H2
InChIKey: HMBNQNDUEFFFNZ-UHFFFAOYSA-N
SMILES: OCCCCOC=C
LogP: 0.43 at · 0.43 at 25℃
CAS DataBase Reference: 17832 · 17832-28-9(CAS DataBase Reference)
FDA UNII: 8 LGM5RZX0N · 8LGM5RZX0N
EPA Substance Registry System: 1 · 1-Butanol, 4-(ethenyloxy)- (17832-28-9)
UNSPSC Code: 12162002 · 12162002
NACRES: 23 · NA.23
Symbol(GHS): 7 · GHS07
Signal word: Warning
Hazard statements: 302 · H302-H319-H412
Precautionary statements: 264 · P264-P270-P273-P280-P301+P312-P305+P351+P338
PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes: Xn
Risk Statements: 20 · 20/21/22-36/37/38-22-52/53
Safety Statements: 26 · 26-36-24/25-61
RIDADR: 1993 · NA 1993 / PGIII
WGK Germany: 1 · 1
Autoignition Temperature: 225 °C · 225 °C DIN 51794
TSCA: TSCA listed
HS Code: 2909 · 2909 49 80
Storage Class: 10 · 10 - Combustible liquids
Hazard Classifications: 4 OralAquatic · Acute Tox. 4 OralAquatic Chronic 3Eye Irrit. 2
Toxicity: 50 orally · LD50 orally in Rabbit: 1738 mg/kg LD50 dermal Rat > 2000 mg/kg
REACH Registrations: Active

Safety & regulation

GHS classification

GHS Classification · 5 items

This chemical does not meet GHS hazard criteria for 3.5% (6 of 171) of reports.

Warning

H302 (90.6%): Harmful if swallowed [Warning Acute toxicity, oral]

P264, P264+P265, P270, P273, P280, P301+P317, P305+P351+P338, P330, P337+P317, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 171 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 3 items

1-Butanol, 4-(ethenyloxy)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Butanol, 4-(ethenyloxy)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 30-10-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/11952

1,4-Butanediolmonovinylether: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesAcute Tox. 4 (90.6%)

Safety data

PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk: 1
tsca: TSCA listed
ridadr: NA 1993 / PGIII
hs_code: 2909 49 80
Toxicity: LD50 orally in Rabbit: 1738 mg/kg LD50 dermal Rat > 2000 mg/kg
risk_code: 20/21/22-36/37/38-22-52/53
Signal word: Warning
Symbol(GHS): GHS07
hazard_code: Xn
safety_code: 26-36-24/25-61
Storage Class: 10 - Combustible liquids
Hazard statements: H302-H319-H412
REACH Registrations: Active
Hazard Classifications: Acute Tox. 4 OralAquatic Chronic 3Eye Irrit. 2
Autoignition Temperature: 225 °C DIN 51794
Precautionary statements: P264-P270-P273-P280-P301+P312-P305+P351+P338

Chemistry & industry

Uses & manufacturing

U.S. Production2023: 1,000,000 - <8,500,000 lb

Industry UsesMonomers

General Manufacturing Information · 2 items

All Other Basic Organic Chemical Manufacturing

1-Butanol, 4-(ethenyloxy)-: ACTIVE

Applications · 1 item

Uses4-Hydroxybutylvinyl ether is a commercially available polymer chemical, polymer material, and organic synthesis intermediate. It can undergo self-polymerization under the action of sulfonic acid. In synthetic transformation, its hydroxyl groups can be converted into aldehyde groups under Swern oxidation conditions.