1-(Trimethylsilyl)methylamine (HCID 87488)

Names & identifiers

Preferred name: 1-(Trimethylsilyl)methylamine
IUPAC: trimethylsilylmethanamine
English name: (Trimethylsilyl)methylamine
Molecular formula: C4H13NSi
Molecular weight: 103.24

Names & synonyms

1-(Trimethylsilyl)methylamineEINECS 242-049-2DTXSID30171176NSC 96778RefChem:428852DTXCID2093667242-049-218166-02-4(Aminomethyl)trimethylsilane(Trimethylsilyl)methylaminetrimethylsilylmethanamine(trimethylsilyl)methanamine

Show more names

AMTMSrimethylsilylmethanamineTrimethylsilylmethaneamine2-AMINOMETHYLTRIMETHYLSILANEMethylamine, 1-(trimethylsilyl)-,

aminomethyltrimethylsilaneTrimethylsilylmethylamineMethanamine, 1-(trimethylsilyl)-1-(trimethylsilyl)methanamineMFCD00042931Y4CS778E5BNSC-96778NSC96778

Database identifiers

CAS: 18166-02-4
PubChem CID: 87488
DTXSID: DTXSID30171176
ChEMBL: CHEMBL76074
UNII: Y4CS778E5B
EC Number: 242-049-2
Nikkaji: J260.904E

Properties

Computed structural properties

Topological polar surface area: 26 Å²
Hydrogen bond donors: 1
Hydrogen bond acceptors: 1
Rotatable bonds: 1
Heavy atoms: 6
Formal charge: 0
Complexity: 37.3

Experimental & physicochemical properties

SpringerMaterials Properties29Si nuclear magnetic resonance spectrum

Physicochemical properties

Melting point: 0 °C · <0°C
Boiling point: 92 · 92-94 °C(lit.)
Density: 0.771 g/mL · 0.771 g/mL at 20 °C(lit.)
refractive index: 20 · n20/D 1.416
Flash point: 9 °C · 9°C
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: liquid
pka: 10.89 · 10.89±0.10(Predicted)
Specific Gravity: 0.7697 · 0.7697
Hydrolytic Sensitivity: 4 · 4: no reaction with water under neutral conditions
BRN: 1731488 · 1731488
InChI: InChI=1S/C4H13NSi/c1-6(2,3)4-5/h4-5H2,1-3H3
InChIKey: YVWPNDBYAAEZBF-UHFFFAOYSA-N
SMILES: C([Si](C)(C)C)N
CAS DataBase Reference: 18166 · 18166-02-4(CAS DataBase Reference)
FDA UNII: 4 CS778E5B · Y4CS778E5B
NIST Chemistry Reference: Trimethylsilylmethylamine(18166-02-4)
UNSPSC Code: 12352100 · 12352100
NACRES: 22 · NA.22
Symbol(GHS): 2 · GHS02,GHS05
Signal word: Danger
Hazard statements: 225 · H225-H314
Precautionary statements: 210 · P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
PPE: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes: F,C
Risk Statements: 11 · 11-34-37
Safety Statements: 16 · 16-26-36/37/39-45
RIDADR: 2733 · UN 2733 3/PG 2
WGK Germany: 3 · 3
F: 3 · 3-10
TSCA: No
HazardClass: 3.1 · 3.1
PackingGroup: II
Storage Class: 3 · 3 - Flammable liquids
Hazard Classifications: 2 Skin · Flam. Liq. 2Skin Corr. 1B

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

Safety data

F: 3-10
PPE: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
wgk: 3
tsca: No
ridadr: UN 2733 3/PG 2
risk_code: 11-34-37
Signal word: Danger
Symbol(GHS): GHS02,GHS05
hazard_code: F,C
safety_code: 16-26-36/37/39-45
hazard_class: 3.1
Storage Class: 3 - Flammable liquids
packing_group: II
Hazard statements: H225-H314
Hazard Classifications: Flam. Liq. 2Skin Corr. 1B
Precautionary statements: P210-P233-P240-P280-P303+P361+P353-P305+P351+P338

Chemistry & industry

Applications

Uses(Trimethylsilyl)methylamine is used for the synthesis of trimethylsilyldiazomethane; 1,3-cycloaddition of its imino group; from ketone imine ylide.