Benzene, 1,1',1''-[(chlorosilylidyne)tris(methylene)]tris-

HCID 87774
NotesReactions
Substructure searchFind similar structures

Basic information

CAS
18740-59-5
Standard SMILES
Cl[Si](Cc1ccccc1)(Cc1ccccc1)Cc1ccccc1
InChIKey
UTXPCJHKADAFBB-UHFFFAOYSA-N
Molecular formula
C21H21ClSi
Average molar mass
336.9 g/mol
Monoisotopic mass
336.11010488

Names & identifiers

Preferred name
Benzene, 1,1',1''-[(chlorosilylidyne)tris(methylene)]tris-
IUPAC
tribenzyl(chloro)silane
English name
CHLOROTRIBENZYLSILANE
Molecular formula
C21H21ClSi
Molecular weight
336.93

Names & synonyms

TribenzylchlorosilaneSilane, tribenzylchloro-EINECS 242-549-0NSC 1398501,1',1''-[(Chlorosilylidyne)tris(methylene)]tris[benzene]Benzene, 1,1',1''-((chlorosilylidyne)tris(methylene))tris-1,1',1''-((Chlorosilylidyne)tris(methylene))tris(benzene)Benzene, 1,1',1''-[(chlorosilylidyne)tris(methylene)]tris-RefChem:562157242-549-0Chlorotribenzylsilane18740-59-5
Show more names
TRIBENZYL CHLOROSILANEtribenzylchlorosilicaneTribenzylchlorosilane 97%chlorotris(phenylmethyl)-silanChlorotris(phenylmethyl)silaneTribenzylchlorosilane, Tribenzylsilyl chloride
tribenzyl(chloro)silaneSilane, chlorotris(phenylmethyl)-Tribenzylsilyl chlorideVQR444HU54NSC-139850NSC139850UNII-VQR444HU54SCHEMBL820045

Database identifiers

CAS
18740-59-5
PubChem CID
87774
DTXSID
DTXSID0066404
UNII
VQR444HU54
EC Number
242-549-0
Nikkaji
J222.293K

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
0
Rotatable bonds
6
Heavy atoms
23

Physicochemical properties

Melting point
139 · 139-142 °C(lit.)
Boiling point
437.9 · 437.9±14.0 °C(Predicted)
Density
1.096 · 1.096±0.06 g/cm3(Predicted)
solubility
sparingly sol cold petroleum ether; moderately sol hot petroleum ether; sol ether.
FDA UNII
444 HU54 · VQR444HU54
EPA Substance Registry System
Silane, chlorotris(phenylmethyl)- (18740-59-5)

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesSkin Corr. 1B (100%)

Safety data

F
10-21
wgk
3
tsca
TSCA listed
ridadr
UN 3261 8/PG 2
risk_code
34
Signal word
Danger

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationBenzene, 1,1',1''-[(chlorosilylidyne)tris(methylene)]tris-: INACTIVE

Applications

UsesTribenzylchlorosilane is widely used as reagent for alcohol protection.

Preparation methods · 1 item

PreparationIt is prepared by reaction of benzylmagnesium chloride with SiCl4 in ether; separation from mono- and dibenzylated chlorosilane byproducts is then accomplished by fractional distillation (boiling range 300–360 °C/100 mmHg). Other preparations involve the chlorination of tribenzylsilane using Cl2 or an acyl chloride. No yields are reported for any of the above preparative procedures.

Upstream & downstream products

Suppliers18 total

杭州品高化工有限公司0571-87658025 · [email protected]
陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
北京华威锐科化工有限公司0757-86329057 18934348241 · [email protected]
NANJING YINGWEN BIOTECHNOLOGY CO LTD+86-13382787392 · [email protected]
上海祈铭新材料有限公司021-36010885 13661599081;13701898138 · [email protected]

Related reactions

2 records
New reaction record

Compound notes

Loading…