Cyclopentene

HCID 8882

Basic information

CAS
142-29-0
Standard SMILES
C1=CCCC1
InChIKey
LPIQUOYDBNQMRZ-UHFFFAOYSA-N
Molecular formula
C5H8
Average molar mass
68.12 g/mol
Monoisotopic mass
68.06260026

Overview

Cyclopentene appears as a colorless liquid. Less dense than water and insoluble in water. Flash point below 0 °F. Vapors heavier than air. Inhalation of high concentrations may be narcotic. Used to make rubber and plastics.

Names & identifiers

Preferred name
Cyclopentene
IUPAC
cyclopentene
English name
Cyclopentene
Molecular formula
C5H8
Molecular weight
68.12

Names & synonyms

CYCLOPENTENE142-29-01-CyclopenteneDTXSID6029171UNII-ONM2CKV81ZONM2CKV81ZNSC 5160EINECS 205-532-9UN2246NSC-5160DTXCID609171CHEBI:49155
Show more names
CyclopentenopenteneCyclopcntenCyclopentene >Cyclopentene, 98+%CYCLOPENTENE, STAB.Cyclopentene, tech.Cyclopentene, tech., ≥95%
EC 205-532-9RefChem:129879205-532-9InChI=1/C5H8/c1-2-4-5-3-1/h1-2H,3-5HLPIQUOYDBNQMRZ-UHFFFAOYSA-NC5H8MFCD0000139429300-20-7

Database identifiers

CAS
142-29-0
PubChem CID
8882
DTXSID
DTXSID6029171
ChEMBL
CHEMBL1797299
ChEBI
CHEBI:49155
UNII
ONM2CKV81Z
EC Number
205-532-9
Nikkaji
J34.912G

Properties

Computed structural properties

XLogP
1.9
Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
0
Rotatable bonds
0
Heavy atoms
5

Experimental & physicochemical properties

Chemical Classes · 2 items

Other Classes -> Aliphatics, Unsaturated

Flammable agents - 3rd degree

SpringerMaterials PropertiesSchoenflies notation
Density0.774 (USCG, 1999) - Less dense than water; will float
Flash Point-30 °F (USCG, 1999)
Boiling Point112 °F at 760 mmHg (USCG, 1999)
Melting Point-211 °F (USCG, 1999)

Physicochemical properties

Melting point
135 °C · −135 °C(lit.)
Boiling point
44 · 44-46 °C(lit.)
Density
0.771 g/mL · 0.771 g/mL at 25 °C(lit.)
vapor pressure
20.89 psi · 20.89 psi ( 55 °C)
refractive index
20 · n20/D 1.421(lit.)
Flash point
30 °F · <−30 °F

Safety & regulation

GHS classification

GHS Classification · 6 items

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P273, P280, P301+P316, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P317, P319, P321, P330, P331, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 190 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H225: Highly Flammable liquid and vapor [Danger Flammable liquids]

Hazard information

Regulatory Information · 5 items

Chemical: Cyclopentene

Cyclopentene is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cyclopentene are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 25-02-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/27532

Cyclopentene: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelFlammable Liquid
Fire Hazards · 2 items

Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flashback. Explosion may occur under fire condition. (USCG, 1999)

· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Health Hazards · 2 items

May be harmful by inhalation, ingestion, or skin absorption. May cause eye and skin irritation. (USCG, 1999)

CAUTION: Petroleum crude oil (UN1267) may contain TOXIC hydrogen sulphide gas.

Hazards Summary · 1 item

May polymerize; High vapor concentrations may have narcotic effects; [CAMEO] May cause smarting and reddening of skin if spilled and allowed to remain on clothes; High vapor concentrations may cause mild smarting of eyes and respiratory system, dizziness, and loss of consciousness; [CHRIS] An irritant that can cause skin burns on prolonged contact; [FAHG] May form explosive peroxides; An irritant; Harmful by ingestion (may cause lung damage by aspiration); Inhalation may cause dizziness or drowsiness; Harmful by ingestion and skin absorption; [Alfa Aesar MSDS] See 1-Pentene.

DOT ID and Guide2246 128

Safety & protection

Fire FightingExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Accidental Release Measures · 2 items

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 items

INHALATION: Call a physician. If inhaled, remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Isolation and Evacuation · 2 items

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:

Immediate precautionary measure

Toxicology

Adverse EffectsNeurotoxin - Acute solvent syndrome
Toxicity DataLCLo (rat) = 16,000 ppm/4hr

Safety data

F
10-23
PPE
Eyeshields, Faceshields, Gloves
wgk
3
tsca
TSCA listed
rtecs
GY5950000
ridadr
UN 2246

Chemistry & industry

Uses & manufacturing

UsesUsed to make rubber and plastics; [CAMEO]
U.S. Production2023: 50,000,000 - <100,000,000 lb
Consumer UsesOther
Industry UsesOther
General Manufacturing Information · 2 items

Petrochemical Manufacturing

Cyclopentene: ACTIVE

Applications · 3 items

UsesCyclopentene is a cycloalkene that is cyclopentane having one endocyclic double bond. Vapors heavier than air. Inhalation of high concentrations may be narcotic. Used to make rubber and plastics. Neopentyl phosphine ligand catalyzed Heck coupling of cyclopentene has been reported. Mechanism of reaction of ground state oxygen atom with cyclopentene has been investigated. Homopolymerization of cyclopentene has been reported. Photocatalytic oxidation of cyclopentene over various titanium(IV) oxide catalyst has been reported. Cyclopentene was used to investigate the [2+2] cycloaddition of diamond (001) surfaces with alkene.

UsesCyclopentene is used in organic synthesis for cross-linking resin. It is used as an intermediate in Industries such as Agrochemical, Dyestuff, Pharmaceutical, syntheses material, Chemical. It is used as a monomer for synthesis of plastics and rubber. It is also used for the synthesis of various chemicals, such as 1,1,2-Trimethylcyclohexane.

General DescriptionCyclopentene appears as a colorless liquid. Less dense than water and insoluble in water. Flash point below 0°F. Vapors heavier than air. Inhalation of high concentrations may be narcotic. Used to make rubber and plastics.

Preparation methods · 1 item

PreparationCyclopentene is synthesized by selective hydrogenation of cyclopentadiene or by dehydration of cyclopentanol. It is produced industrially in large amounts by steam cracking of naphtha. Cyclopentene is present in coal tar, cigarette smoke, and automobile emissions.

Suppliers100 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
山东春雨精细化工有限责任公司13561220159 · [email protected]
上海比阳实业有限公司+86-21-52699951; +8613917686115 · [email protected]

Additional notes

DefinitionChEBI: Cyclopentene is a cycloalkene that is cyclopentane having one endocyclic double bond.

Related reactions

77 records

Compound notes

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