Camphor-10-sulfonyl chloride

HCID 88856

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Basic information

CAS: 21286-54-4
Standard SMILES: CC1(C)[C@@H]2CC[C@@]1(CS(=O)(=O)Cl)C(=O)C2
InChIKey: BGABKEVTHIJBIW-GMSGAONNSA-N
Molecular formula: C10H15ClO3S
Average molar mass: 250.74 g/mol
Monoisotopic mass: 250.04304302

Overview

RN refers to (1S)-isomer

Names & identifiers

Preferred name: Camphor-10-sulfonyl chloride
IUPAC: [(1S,4R)-7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl]methanesulfonyl chloride
English name: D(+)-10-Camphorsulfonyl chloride
Molecular formula: C10H15ClO3S
Molecular weight: 250.74

Names & synonyms

21286-54-4Camphor-10-sulfonyl chlorideDTXSID90891707RefChem:123143DTXCID001030836244-314-8D(+)-10-Camphorsulfonyl chloride((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride(1S)-(+)-Camphor-10-sulfonyl chlorideMFCD00064156(1S)-(+)-10-Camphorsulfonyl chlorideD-(+)-10-Camphorsulfonyl chloride

Show more names

(+)-10-Camphorsulfonyl ChlorideCamphor-10-suLD(+)CAMPHOR SULFONYL CHLORIDED-CAMPHOR-10-SULFONYL CHLORIDES-(+)-caMphorsulfonyl chlorideD(+)-1-CaMphorsulfonyl chlorideD-CAMPHOR-10-SULFONYL CHLORIDE 96%

[(1S,4R)-7,7-Dimethyl-2-Oxobicyclo[2.2.1]Heptan-1-Yl]Methanesulfonyl ChlorideD-10-Camphorsulfonyl chlorideC10H15ClO3S(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonyl chlorideAKOS016842458(+)-Camphor-10-sulfonyl chloride[(1S,4R)-7,7-dimethyl-2-oxo-norbornan-1-yl]methanesulfonyl chloride(1S)-(+)-10-Camphorsulfonyl chloride, 97%

Database identifiers

CAS: 21286-54-4
PubChem CID: 88856
DTXSID: DTXSID90891707
EC Number: 244-314-8
Nikkaji: J208.235G

Properties

Computed structural properties

XLogP: 1.8
Topological polar surface area: 59.6 Å²
Hydrogen bond donors: 0
Hydrogen bond acceptors: 3
Rotatable bonds: 2
Heavy atoms: 15
Formal charge: 0
Complexity: 407

Physicochemical properties

Melting point: 67 · 67-68 °C
alpha: 33 · 33 º (c=1, CHCl3 22 ºC)
Boiling point: 349.4 · 349.4±15.0 °C(Predicted)
Density: 1.2078 · 1.2078 (estimate)
refractive index: 32 ° · 32 ° (C=1, CHCl3)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
form: Crystalline Powder
color: Off-white to beige
optical activity: 22 · [α]22/D +33°, c = 1 in chloroform
Sensitive: Moisture Sensitive
BRN: 3205974 · 3205974
InChI: 1S/C10H15ClO3S/c1-9(2)7-3-4-10(9,8(12)5-7)6-15(11,13)14/h7H,3-6H2,1-2H3/t7-,10-/m1/s1
InChIKey: BGABKEVTHIJBIW-UHFFFAOYSA-N
SMILES: [H][C@@]12CC[C@@](CS(Cl)(=O)=O)(C(=O)C1)C2(C)C
CAS DataBase Reference: 21286 · 21286-54-4(CAS DataBase Reference)
NIST Chemistry Reference: -10 · (+)-Camphor-10-sulfonyl chloride(21286-54-4)
UNSPSC Code: 12352115 · 12352115
NACRES: 22 · NA.22
Symbol(GHS): 5 · GHS05
Signal word: Danger
Hazard statements: 314 · H314
Precautionary statements: 260 · P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
PPE: 3 · Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes: C
Risk Statements: 34 · 34
Safety Statements: 26 · 26-36/37/39-45
RIDADR: 3261 · UN 3261 8/PG 2
WGK Germany: 3 · 3
F: 10 · 10-21
HazardClass: 8 · 8
PackingGroup: II
HS Code: 29147000 · 29147000
Storage Class: 8 A · 8A - Combustible corrosive hazardous materials
Hazard Classifications: 1 B · Skin Corr. 1B
Limited Quantities: 1 Kg · 1 Kg (2.2 lbs) (solid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 50 reports by companies from 5 notifications to the ECHA C&L Inventory.

Hazard information

Hazard Classes and CategoriesSkin Corr. 1B (100%)

Safety data

F: 10-21
PPE: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
wgk: 3
ridadr: UN 3261 8/PG 2
hs_code: 29147000
risk_code: 34
Signal word: Danger
Symbol(GHS): GHS05
hazard_code: C
safety_code: 26-36/37/39-45
hazard_class: 8
Storage Class: 8A - Combustible corrosive hazardous materials
packing_group: II
Hazard statements: H314
Limited Quantities: 1 Kg (2.2 lbs) (solid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
Hazard Classifications: Skin Corr. 1B
Precautionary statements: P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363