Dihexylamine

HCID 8920CAS 143-16-8

Basic information

Standard SMILES
CCCCCCNCCCCCC
InChIKey
PXSXRABJBXYMFT-UHFFFAOYSA-N
Molecular formula
C12H27N
Average molar mass
185.35 g/mol
Monoisotopic mass
185.21434986

Overview

Dihexylamine is a clear colorless liquid. (NTP, 1992)

Names & identifiers

Preferred name
Dihexylamine
IUPAC
N-hexylhexan-1-amine
English name
Di-n-hexylamine
Molecular formula
C12H27N
Molecular weight
185.35

Names & synonyms

DIHEXYLAMINEDi-N-hexylamine1-Hexanamine, N-hexyl-N,N-DihexylamineN-HexylhexanamineCCRIS 4622DTXSID1022009UNII-K37ADA14ZVNSC 7498EINECS 205-588-4K37ADA14ZVBis(1-hexyl)amine
Show more names
DihexylaminDi-n-hexylaminDihexylaMine 1Dihexylamine >Bis(1-hexyl)amine
di-Normal-hexylamineBRN 1738519AI3-15144NSC-7498DTXCID8020094-04-00-00711 (Beilstein Handbook Reference)DiNhexylamineNHexylhexanamine

Database identifiers

CAS
143-16-8
PubChem CID
8920
DTXSID
DTXSID1022009
ChEMBL
CHEMBL3188279
UNII
K37ADA14ZV
EC Number
205-588-4
Nikkaji
J27.960I

Properties

Computed structural properties

XLogP
4.5
Topological polar surface area
12 Ų
Hydrogen bond donors
1
Hydrogen bond acceptors
1
Rotatable bonds
10
Heavy atoms
13

Experimental & physicochemical properties

Chemical Classes · 2 items

Nitrogen Compounds -> Amines, Aliphatic

Flammable agents - 3rd degree

SpringerMaterials PropertiesBoiling point
Density0.79 at 68 °F (NTP, 1992) - Less dense than water; will float
Solubilityless than 1 mg/mL at 79 °F (NTP, 1992)
Flash Point203 °F (NTP, 1992)
Boiling Point451 to 469 °F at 760 mmHg (NTP, 1992)

Physicochemical properties

Melting point
3 °C · 3 °C
Boiling point
192 · 192-195 °C(lit.)
Density
0.795 g/mL · 0.795 g/mL at 25 °C(lit.)
vapor density
6.4 · 6.4 (vs air)
vapor pressure
0.05 hPa · 0.05 hPa (20 °C)
refractive index
20 · n20/D 1.432(lit.)

Safety & regulation

GHS classification

GHS Classification · 5 items

This chemical does not meet GHS hazard criteria for 0.7% (1 of 151) of reports.

Danger

H300 (72.2%): Fatal if swallowed [Danger Acute toxicity, oral]

P260, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P316, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P320, P321, P330, P361+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 151 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 3 items

Chemical: 1-Hexanamine, N-hexyl-

Dihexylamine: HSNO Approval: HSR004442 Approved with controls

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelPoison
Fire HazardsThis compound is combustible. (NTP, 1992)
Health HazardsACUTE/CHRONIC HAZARDS: This compound is readily absorbed through the skin. (NTP, 1992)
Hazards Summary · 1 item

A severe eye and mild skin irritant; [RTECS] Readily absorbed through skin; [NTP] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Toxic by ingestion; Highly toxic by skin absorption; [Sigma-Aldrich MSDS] See 2-Ethylhexylamine.

Reactive GroupAmines, Phosphines, and Pyridines

Safety & protection

Fire FightingFires involving this compound can be controlled with carbon dioxide, dry chemical or Halon extinguishers. (NTP, 1992)
First Aid · 1 item

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 item

SMALL SPILLS AND LEAKAGE: If you spill this chemical, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Personal Protective Equipment (PPE)MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.

Toxicology

Adverse EffectsDermatotoxin - Skin burns.

Safety data

PPE
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
wgk
2
tsca
TSCA listed
rtecs
IH6600000
ridadr
UN 2922 8/PG 2
hs_code
29211990

Chemistry & industry

Uses & manufacturing

UsesUsed in organic synthesis; [NTP]
General Manufacturing Information1-Hexanamine, N-hexyl-: ACTIVE
Applications · 3 items

UsesDihexylamine is used in organic syntheses.

UsesDi-n-hexylamine is used in organic synthesis and involved in the preparation of succinic acid.

General DescriptionClear colorless liquid.

Suppliers50 total

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]

Related reactions

54 records

Linked notes

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