CAS 24596-19-8 4-Bromo-2,6-xylidine (HCID 90549)

Names & identifiers

Preferred name: 4-Bromo-2,6-xylidine
IUPAC: 4-bromo-2,6-dimethylaniline
English name: 4-Bromo-2,6-dimethylaniline
Molecular formula: C8H10BrN
Molecular weight: 200.08

Names & synonyms

24596-19-84-Bromo-2,6-xylidine4-bromo-2,6-dimethylbenzenamineEINECS 246-337-9DTXSID40179345NSC 227944RefChem:519161DTXCID70101836246-337-9InChI=1/C8H10BrN/c1-5-3-7(9)4-6(2)8(5)10/h3-4H,10H2,1-2H4-Bromo-2,6-dimethylanilineBenzenamine, 4-bromo-2,6-dimethyl-

Show more names

6-diMethylanilineTIMTEC-BB SBB0024104-Bromo-2,6-dimethylLABOTEST-BB LT011432222,6-Xylidine, 4-bromo-4-broMo-2,6-deMethylaniline

2,6-Dimethyl-4-bromoaniline4-Bromo-2,6-dimethyl-phenylamine4-bromo-2,6-dimethylphenylamineMFCD000078264-bromo-2,6-dimethyl-aniline9W5K8J5F6BCS-W019870NSC-227944

Database identifiers

CAS: 24596-19-8
PubChem CID: 90549
DTXSID: DTXSID40179345
UNII: 9W5K8J5F6B
EC Number: 246-337-9
Nikkaji: J236.723H

Properties

Computed structural properties

XLogP: 2.7
Topological polar surface area: 26 Å²
Hydrogen bond donors: 1
Hydrogen bond acceptors: 1
Rotatable bonds: 0
Heavy atoms: 10
Formal charge: 0
Complexity: 104

Experimental & physicochemical properties

SpringerMaterials Properties15N nuclear magnetic resonance spectrum

Physicochemical properties

Melting point: 48 · 48-51 °C (lit.)
Boiling point: 120 °C · 120°C 0,2mm
Density: 1.4423 · 1.4423 (rough estimate)
refractive index: 1.5748 · 1.5748 (estimate)
Flash point: 230 °F · >230 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Chloroform, Methanol
pka: 3.6 · 3.60±0.10(Predicted)
form: Liquid
color: Clear yellow to orange to amber
BRN: 1936300 · 1936300
InChI: InChI=1S/C8H10BrN/c1-5-3-7(9)4-6(2)8(5)10/h3-4H,10H2,1-2H3
InChIKey: QGLAYJCJLHNIGJ-UHFFFAOYSA-N
SMILES: C1(N)=C(C)C=C(Br)C=C1C
CAS DataBase Reference: 24596 · 24596-19-8(CAS DataBase Reference)
FDA UNII: 9 W5K8J5F6B · 9W5K8J5F6B
NIST Chemistry Reference: 4 · Benzenamine, 4-bromo-2,6-dimethyl-(24596-19-8)
UNSPSC Code: 12352100 · 12352100
NACRES: 22 · NA.22
Symbol(GHS): 6 · GHS06,GHS08,GHS09
Signal word: Danger
Hazard statements: 302 · H302-H311+H331-H315-H335-H351-H410
Precautionary statements: 273 · P273-P280-P301+P312-P302+P352+P312-P304+P340+P311-P308+P313
target organs: Respiratory system
PPE: 95 · dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes: Xi,Xn
Risk Statements: 38 · 38-43-36/37/38-20/21/22
Safety Statements: 36 · 36/37-36/37/39-26
RIDADR: 2811 · UN2811/6.1/III
WGK Germany: 3 · 3
F: 8 · 8-10-23
Hazard Note: Harmful
HazardClass: 6.1 · 6.1
HS Code: 29214990 · 29214990
Storage Class: 6.1 C · 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
Hazard Classifications: 3 DermalAcute · Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Carc. 2Skin Irrit. 2STOT SE 3

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H302 (18.4%): Harmful if swallowed [Warning Acute toxicity, oral]

P233, P260, P261, P264, P264+P265, P270, P271, P280, P284, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P342+P316, P362+P364, P403, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 49 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesAcute Tox. 4 (18.4%)

Safety data

F: 8-10-23
PPE: dust mask type N95 (US), Eyeshields, Faceshields, Gloves
wgk: 3
ridadr: UN2811/6.1/III
hs_code: 29214990
risk_code: 38-43-36/37/38-20/21/22
Signal word: Danger
Symbol(GHS): GHS06,GHS08,GHS09
hazard_code: Xi,Xn
hazard_note: Harmful
safety_code: 36/37-36/37/39-26
hazard_class: 6.1
Storage Class: 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
target organs: Respiratory system
Hazard statements: H302-H311+H331-H315-H335-H351-H410
Hazard Classifications: Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Carc. 2Skin Irrit. 2STOT SE 3
Precautionary statements: P273-P280-P301+P312-P302+P352+P312-P304+P340+P311-P308+P313

Chemistry & industry

Applications · 1 item

Uses4-Bromo-2,6-dimethylaniline has been used in the preparation of:4-bromo-N-(1-(6-(1-isopropyl-1H-benzo[d]imidazol-2-yl)pyridin-2-yl)ethylidene)-2,6-dimethylbenzenamineN-(4-Bromo-2,6-dimethylphenyl)-5-trimethylammoniumsalicylaldimine chlorideethynyl-functionalized persistent perylene diimide-multichromophore