Allyltributylstannane

HCID 90628
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Basic information

CAS
24850-33-7
Standard SMILES
C=C[CH2][Sn]([CH2]CCC)([CH2]CCC)[CH2]CCC
InChIKey
YLGRTLMDMVAFNI-UHFFFAOYSA-N
Molecular formula
C15H32Sn
Average molar mass
331.12 g/mol
Monoisotopic mass
332.15259572

Names & identifiers

Preferred name
Allyltributylstannane
IUPAC
tributyl(prop-2-enyl)stannane
English name
Allyltributyltin
Molecular formula
C15H32Sn
Molecular weight
331.12

Names & synonyms

AllyltributyltinAllyltributylstannane24850-33-7UNII-AOR8OD4103AOR8OD4103Tributyl-2-propen-1-ylstannaneEINECS 246-494-3ALLYLTRIBUTYLSTANNANE [MI]DTXSID50179553RefChem:110920DTXCID10102044246-494-3
Show more names
Tributylallylstannaneallyltri-n-butylstannane2-PropenyltributylstannaneTRIBUTYL-2-PROPENYLSTANNANESKL1093Allytri-N-Butyltin
YLGRTLMDMVAFNI-UHFFFAOYSA-NAllyltri-n-ButyltinStannane, tributyl-2-propenyl-Allyl(tributyl)stannanetributyl(prop-2-en-1-yl)stannanetributyl(prop-2-enyl)stannaneStannane, tributyl-2-propen-1-yl-allyl tributylstannane

Database identifiers

CAS
24850-33-7
PubChem CID
90628
DTXSID
DTXSID50179553
UNII
AOR8OD4103
EC Number
246-494-3
Nikkaji
J236.685A

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
0
Rotatable bonds
11
Heavy atoms
16

Experimental & physicochemical properties

Endocrine DisruptorsPotential endocrine disrupting compound

Physicochemical properties

Melting point
134 · 134-135 °C
Boiling point
88 · 88-92 °C0.2 mm Hg(lit.)
Density
1.068 g/mL · 1.068 g/mL at 25 °C(lit.)
refractive index
20 · n20/D 1.486(lit.)
Flash point
230 °F · >230 °F
storage temp.
2 · 2-8°C

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P260, P264, P264+P265, P270, P273, P280, P301+P316, P302+P352, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory InformationStannane, tributyl-2-propenyl-: Does not have an individual approval but may be used under an appropriate group standard
Hazard Classes and CategoriesAcute Tox. 3 (100%)

Safety data

F
13
PPE
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk
3
tsca
No
ridadr
UN 2788 6.1/PG 2
hs_code
29319019

Chemistry & industry

Applications · 2 items

UsesAllylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7

UsesAllylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595). Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones and allyl acetates.Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.

Upstream & downstream products

Suppliers100 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]

Related reactions

221 records
New reaction record

Compound notes

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