Zinc mercaptobenzothiazole
Basic information
- CAS
155-04-4- Standard SMILES
[S-]c1nc2ccccc2s1.[S-]c1nc2ccccc2s1.[Zn+2]- InChIKey
PGNWIWKMXVDXHP-UHFFFAOYSA-L- Molecular formula
- C14H8N2S4Zn
- Average molar mass
- 397.9 g/mol
- Monoisotopic mass
- 395.886175
Names & identifiers
- Preferred name
- Zinc mercaptobenzothiazole
- IUPAC
- zinc bis(1,3-benzothiazole-2-thiolate)
- English name
- Zinc 2-mercaptobenzothiazole
- Molecular formula
- C14H8N2S4Zn
- Molecular weight
- 397.88
Names & synonyms
Zinc 2-mercaptobenzothiazole155-04-4Bantex2-Mercaptobenzothiazole zinc saltZeniteZetaxZenite specialVulkacit ZMHermat Zn-mbtPennac ZTTisperse MB-58Zinc 2-benzothiazolethiolate
Show more names
ZMBTvulkacitzmznmboxafpennacztusafgy-7Zinc MBT
Caswell No. 917ZINC MERCAPTOBENZOTHIAZOLEZinc benzothiazolethiolateHMM5IX9Q3BUSAF GY-7Zinc mercaptobenzothiazolateZinc benzothiazolylmercaptideBis(2-benzothiazolylthio)zinc
Database identifiers
- CAS
155-04-4- PubChem CID
- 9071
- DTXSID
DTXSID6020808- UNII
- HMM5IX9Q3B
- EC Number
- 205-840-3
- Nikkaji
- J6.128J
Properties
Computed structural properties
- Topological polar surface area
- 84.3 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 6
- Rotatable bonds
- 0
- Heavy atoms
- 21
- Formal charge
- 0
- Complexity
- 129
Experimental & physicochemical properties
PolymersPlastics & Rubber -> Rubber Additives
Density1.7 AT 25 °C/4 °C
Color/FormLIGHT YELLOW POWDER
Decompositionwhen heated to decomp ... emits toxic fumes of /sulfur oxides, nitrogen oxides and zinc/.
Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical Description
Dry Powder
Light yellow solid; [HSDB] Cream to pale yellow powder; [MSDSonline]
Physicochemical properties
- Melting point
- 330 °C · 330 °C
- Density
- 1.7 g/cm3 · 1.7 g/cm3(Temp: 25 °C)
- storage temp.
- Refrigerator
- solubility
- Acidic Methanol (Slightly, Heated)
- form
- Solid
- pka
- 7.03 · 7.03[at 20 ℃]
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
This chemical does not meet GHS hazard criteria for 4.5% (24 of 539) of reports.
Warning
H317 (93.7%): May cause an allergic skin reaction [Warning Sensitization, Skin]
P261, P272, P273, P280, P302+P352, P321, P333+P317, P362+P364, P391, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 539 reports by companies from 20 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Warning
Hazard information
Regulatory Information
Chemical: 2(3H)-Benzothiazolethione, zinc salt (2:1)
2(3H)-Benzothiazolethione, zinc salt (2:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2(3H)-Benzothiazolethione, zinc salt (2:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: Zinc di(benzothiazol-2-yl) disulphide (EC: 205-840-3)
Zinc 2-mercaptobenzothiazole: Does not have an individual approval but may be used under an appropriate group standard
Other Safety InformationIMAP assessments - Mercaptobenzothiazole and its salts: Human health tier II assessment
Hazards SummaryMay cause irritation; [MSDSonline] See Mercaptobenzothiazole. See Mercapto mix.
FIFRA Requirements
As the federal pesticide law FIFRA directs, EPA is conducting a comprehensive review of older pesticides to consider their health and environmental effects and make decisions about their future use. Under this pesticide reregistration program, EPA examines health and safety data for pesticide active ingredients initially registered before November 1, 1984, and determines whether they are eligible for reregistration. In addition, all pesticides must meet the new safety standard of the Food Quality Protection Act of 1996. Pesticides for which EPA had not issued Registration Standards prior to the effective date of FIFRA, as amended in 1988, were divided into three lists based upon their potential for human exposure and other factors, with List B containing pesticides of greater concern and List D pesticides of less concern. Zinc 2-mercaptobenzothiazolate is found on List B. Case No: 2380; Pesticide type: fungicide, antimicrobial; Case Status: RED Approved 09/94; OPP has made a decision that some/all uses of the pesticide are eligible for reregistration, as reflected in a Reregistration Eligibility Decision (RED) document.; Active ingredient (AI): Zinc 2-mercaptobenzothiazolate; Data Call-in (DCI) Date(s): 04/12/91; AI Status: OPP has completed a Reregistration Eligibility Decision (RED) document for the case/AI.
Chemistry & industry
Uses & manufacturing
Uses
Used as rubber accelerator and fungicide; [HSDB]
Farming (Pesticides) [Category: Industry]
RUBBER ACCELERATOR, FUNGICIDE
U.S. Production
2023: 100,000 - <250,000 lb
927,000 kg in 1979.
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesProcessing aids not otherwise specified
General Manufacturing Information
Rubber Product Manufacturing
2(3H)-Benzothiazolethione, zinc salt (2:1): ACTIVE
Applications
UsesZinc 2-Mercaptobenzothiazole is an additive which is used in flooring material to allow excellent hardening at low temperatures.
UsesAccelerator for latex, powder coating, fungicide.
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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