Bis(1 5-cyclooctadiene)rhodium(I)

HCID 92002603

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Basic information

CAS: 207124-65-0
Standard SMILES: C1=CCCC=CCC1.C1=CCCC=CCC1.F[B-](F)(F)F.O.[Rh]
InChIKey: RVVSQTPAHKVLPL-UHFFFAOYSA-N
Molecular formula: C16H26BF4ORh-
Average molar mass: 424.1 g/mol
Monoisotopic mass: 424.10678

Names & identifiers

Preferred name: Bis(1 5-cyclooctadiene)rhodium(I)
IUPAC: bis(cycloocta-1,5-diene);rhodium;tetrafluoroborate;hydrate
English name: Bis(1 5-cyclooctadiene)rhodium(I)
Molecular formula: C16H24BF4Rh
Molecular weight: 406.07

Names & synonyms

207124-65-0BIS(1 5-CYCLOOCTADIENE)RHODIUM(I)SCHEMBL299426062C8H12.BF4.Rh.H2O6196AHBis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate hydrateuoroborate hydrateooctadiene)rhodium(I) tetrafL(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate,hydrateBis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate hydrate 97%

Database identifiers

CAS: 207124-65-0
PubChem CID: 92002603
EC Number: 633-785-9

Properties

Computed structural properties

Topological polar surface area: 1 Å²
Hydrogen bond donors: 1
Hydrogen bond acceptors: 6
Rotatable bonds: 0
Heavy atoms: 23
Formal charge: -1
Complexity: 91.7

Physicochemical properties

Melting point: 165 °C · 165 °C (dec.)(lit.)
form: powder
InChI: 1S/2C8H12.BF4.H2O.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;;/h2*1-2,7-8H,3-6H2;;1H2;/q;;-1;;+1/b2*2-1-,8-7-;;;
InChIKey: NYMNQNLSUITCLM-DIURZKMRSA-N
SMILES: O.[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2
UNSPSC Code: 12161600 · 12161600
NACRES: 22 · NA.22
Symbol(GHS): 2 · GHS02,GHS07
Signal word: Warning
Hazard statements: 228 · H228-H315-H317-H319-H335
Precautionary statements: 210 · P210-P240-P241-P280-P302+P352-P305+P351+P338
target organs: Respiratory system
PPE: 3 · Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes: F
Risk Statements: 11 · 11-34
Safety Statements

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Danger

H228 (100%): Flammable solid [Danger Flammable solids]

P210, P240, P241, P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesFlam. Sol. 2 (100%)

Safety data

PPE: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
wgk: 2
ridadr: UN 2921 8/PG 2
risk_code: 11-34
Signal word: Warning
Symbol(GHS): GHS02,GHS07
hazard_code: F
safety_code: 26-36/37/39-45
Storage Class: 4.1B - Flammable solid hazardous materials
target organs: Respiratory system
Hazard statements: H228-H315-H317-H319-H335
Hazard Classifications: Eye Irrit. 2Flam. Sol. 2Skin Irrit. 2Skin Sens. 1STOT SE 3
Precautionary statements: P210-P240-P241-P280-P302+P352-P305+P351+P338

Chemistry & industry

Applications

UsesBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate Hydrate is a coordination complex used as catalyst for research purposes.

UsesUmicore Precatalysts for Asymmetric and Cross-Coupling CatalysisHydrosilylation Catalysts

Suppliers38 total

T&W GROUP021-61551611 13296011611 · [email protected]

Aladdin Scientific[email protected]

上海卡伦姆生化科技有限公司15837198050 · [email protected]

郑州德元凯化工有限公司17837139533 · [email protected]

安耐吉化学&3A（安徽泽升科技有限公司）021-58432009 400-005-6266 · [email protected]

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