Basic information
- CAS
352-87-4- Standard SMILES
C=C(C)C(=O)OCC(F)(F)F- InChIKey
QTKPMCIBUROOGY-UHFFFAOYSA-N- Molecular formula
- C6H7F3O2
- Average molar mass
- 168.11 g/mol
- Monoisotopic mass
- 168.03981412
Names & identifiers
- Preferred name
- 2,2,2-Trifluoroethyl methacrylate
- IUPAC
- 2,2,2-trifluoroethyl 2-methylprop-2-enoate
- English name
- 2,2,2-Trifluoroethyl methacrylate
- Molecular formula
- C6H7F3O2
- Molecular weight
- 168.11
Names & synonyms
2,2,2-TRIFLUOROETHYL METHACRYLATE352-87-42-Propenoic acid, 2-methyl-, 2,2,2-trifluoroethyl esterDTXSID7059856TFEMARefChem:80807DTXCID0038962206-525-32,2,2-trifluoroethyl 2-methylprop-2-enoateTrifluoroethyl methacrylate2-Propenoic acid, 2-methyl-, trifluoroethyl esterMFCD00013576
Show more names
3-FMTFOL-MFluoresterViscoat 3FM2-PropenoicAcryester 3FELight Ester M 3F2,2,2-trifluoroethyles
Methacrylic acid 2,2,2-trifluoroethyl ester2,2,2-Trifluoroethyl Methacrylate (stabilized with MEHQ)2,2,2-TRIFLUOROETHYLMETHACRYLATEEINECS 206-525-3NSC 32617Methacrylic acid, 2,2,2-trifluoroethyl esterSCHEMBL365952,2-Trifluoroethyl methacrylate
Database identifiers
- CAS
352-87-4- PubChem CID
- 9608
- DTXSID
DTXSID7059856- EC Number
- 206-525-3
- Nikkaji
- J107.718J
Properties
Computed structural properties
- XLogP
- 2.7
- Topological polar surface area
- 26.3 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 5
- Rotatable bonds
- 3
- Heavy atoms
- 11
- Formal charge
- 0
- Complexity
- 171
Experimental & physicochemical properties
PFASPFAS -> PFAS identified in REACH Regulation EC No. 1272/2008
LogP1.56
Physical DescriptionLiquid
Physicochemical properties
- Boiling point
- 59 °C100 · 59 °C100 mm Hg(lit.)
- Density
- 1.181 g/mL · 1.181 g/mL at 25 °C(lit.)
- vapor pressure
- 22 hPa · 22hPa at 20℃
- refractive index
- 20 · n20/D 1.361(lit.)
- Flash point
- 62 °F · 62 °F
- storage temp.
- 2 · 2-8°C
- form
- Crystals or Crystalline Powder
- Specific Gravity
- 1.181 · 1.181
- color
- White
- Water Solubility
- 906 mg/L · 906mg/L at 20℃
- BRN
- 4175872 · 4175872
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H225 (94.9%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P280, P301+P316, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 98 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Regulatory Information
Chemical: 2-Propenoic acid, 2-methyl-, 2,2,2-trifluoroethyl ester
2-Propenoic acid, 2-methyl-, 2,2,2-trifluoroethyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, 2-methyl-, 2,2,2-trifluoroethyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 28-02-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/18658
2-Propenoic acid, 2-methyl-, 2,2,2-trifluoroethyl ester: Does not have an individual approval but may be used under an appropriate group standard
Hazard Classes and CategoriesFlam. Liq. 2 (94.9%)
Safety data
- PPE
- Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
- wgk
- 2
- tsca
- TSCA listed
- ridadr
- UN 3272 3/PG 2
- hs_code
- 29161400
Chemistry & industry
Uses & manufacturing
U.S. Production2023: 250,000 - <550,000 lb
Industry UsesIntermediate
General Manufacturing Information
Paint and Coating Manufacturing
2-Propenoic acid, 2-methyl-, 2,2,2-trifluoroethyl ester: ACTIVE
Applications
Uses2,2,2-TRIFLUOROETHYL METHACRYLATE is a useful research chemical.
Uses2,2,2-Trifluoroethyl methacrylate is mainly used for coating to improve its weather resistance, water resistance and pollution resistance. It can also be used as a charge regulator for cladding and core materials of optical fibers, contact lenses, toner and carrier particles of computers.
UsesTFEMA can be used in the preparation of poly(TFEMA), which can be used in the development of acrylic protective coatings.
General Description2,2,2-Trifluoroethyl methacrylate (TFEMA) is a semifluorinated monomer that can be synthesized from methacryloyl chloride and 2,2,2-trifluoroethanol in presence of triethylamine. Its properties include chemical inertness, good wear resistance and low dielectric constant.
Suppliers100 total
国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
中节能万润股份有限公司
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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