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CID 9837014

HCID 9837014
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Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
7632-51-1
Standard SMILES
[Cl-].[Cl-].[Cl-].[Cl-].[V+4]
InChIKey
JTJFQBNJBPPZRI-UHFFFAOYSA-J
Molecular formula
Cl4V
Average molar mass
192.7 g/mol
Monoisotopic mass
190.819368

Overview

See also: Vanadium tetrachloride (preferred).

Names & identifiers

Preferred name
CID 9837014
IUPAC
vanadium(4+) tetrachloride
English name
VANADIUM (IV) CHLORIDE
Molecular formula
Cl4V
Molecular weight
192.75

Names & synonyms

SCHEMBL320871AT45523Q421255VCl4VANADIUM CHLORIDEVanadium tetrachlorideTetrachlorovanadiumvanadiumchloride(vcl4)VANADIUM (IV) CHLORIDETetrachlorovanadium(IV)Vanadium(IV) tetrachlorideVANADIUM (IV) CHLORIDE 99+%
Show more names
(t-4)-vanadiumchloride(vcl4

Database identifiers

CAS
7632-51-1
PubChem CID
9837014
UNII
2I17MGM5YJ
Nikkaji
J36.577G

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
4
Rotatable bonds
0
Heavy atoms
5
Formal charge
0
Complexity
0

Physicochemical properties

Melting point
24.5 °C · −24.5 °C (−12.1 °F; 248.7 K)
Boiling point
148 °C · 148 °C (298 °F; 421 K)
Density
1.816 g/cm3, · 1.816 g/cm3, liquid
vapor pressure
10.173 hPa · 10.173hPa at 25℃
Flash point
Not applicable
storage temp.
water-free area
solubility
diethyl ether: slightly soluble(lit.)
form
liquid
color
bright red
Water Solubility
93 · soluble alcohol, ether [HAW93]
Specific Heat Capacity
0.5 J/ · Cp(gas): 0.5 J/(g·K), at 25℃
Sensitive
Moisture Sensitive
Dielectric constant
3.1 · 3.1(Ambient)
Major Application
battery manufacturing
InChI
InChI=1S/4ClH.V/h4*1H;/q;;;;+4/p-4
InChIKey
JTJFQBNJBPPZRI-UHFFFAOYSA-J

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

PPE
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
wgk
3
tsca
TSCA listed
rtecs
YW2625000
ridadr
UN 2444
hs_code
28273990
risk_code
14-23/24/25-34
Signal word
Danger
Symbol(GHS)
GHS05
hazard_code
T
safety_code
26-27-36/37/39-45
hazard_class
8
Storage Class
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
packing_group
I
Hazard statements
H314-H412
REACH Registrations
Active
Hazard Classifications
Acute Tox. 3 OralAquatic Chronic 3Eye Dam. 1Skin Corr. 1C
Precautionary statements
P260-P264-P280-P273-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P305+P351+P338-P405-P501
Hazardous Substances Data
7632-51-1(Hazardous Substances Data)

Chemistry & industry

Applications

UsesPreparation of vanadium trichloride, vanadium dichloride, and organovanadium compounds.

Preparation methods

PreparationDisproportionate of VCl3 to VCl2 and VCl4 by heating in a N2 stream at 900°C in a porcelain tube.

Upstream & downstream products

Upstream raw materials

Vanadium(V) trichloride oxide

Downstream products

ChlorotriethylsilaneVanadium(III) chlorideChlorine

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
SMILES
[V](Cl)(Cl)(Cl)Cl
LogP
0 at · 0 at 20℃
EWG's Food Scores
1 · 1
FDA UNII
2 I17MGM5YJ · 2I17MGM5YJ
EPA Substance Registry System
Vanadium chloride (VCl4), (T-4)- (7632-51-1)
UNSPSC Code
12352302 · 12352302
Symbol(GHS)
5 · GHS05
Signal word
Danger
Hazard statements
314 · H314-H412
Precautionary statements
260 · P260-P264-P280-P273-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P305+P351+P338-P405-P501
PPE
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes
T
Risk Statements
14 · 14-23/24/25-34
Safety Statements
26 · 26-27-36/37/39-45
RIDADR
2444 · UN 2444
WGK Germany
3 · 3
RTECS
2625000 · YW2625000
TSCA
TSCA listed
HazardClass
8 · 8
PackingGroup
I
HS Code
28273990 · 28273990
Storage Class
6.1 C · 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
Hazard Classifications
3 OralAquatic · Acute Tox. 3 OralAquatic Chronic 3Eye Dam. 1Skin Corr. 1C
Hazardous Substances Data
7632 · 7632-51-1(Hazardous Substances Data)
REACH Registrations
Active