Basic information
- CAS
224311-55-1- Standard SMILES
c1ccc(-c2ccccc2P(C23CC4CC(CC(C4)C2)C3)C23CC4CC(CC(C4)C2)C3)cc1- InChIKey
MSKLBRMTWIUCEQ-UHFFFAOYSA-N- Molecular formula
- C32H39P
- Average molar mass
- 454.6 g/mol
Names & identifiers
- Preferred name
- 2-[Bis(1-adamantyl)phosphino]biphenyl
- IUPAC
- bis(1-adamantyl)-(2-phenylphenyl)phosphane
- English name
- [1,1′-Biphenyl]-2-yldi[(3S,5S,7S)-1-adamantanyl]phosphine
- Molecular formula
- C32H39P
- Molecular weight
- 454.63
Names & synonyms
224311-55-1(2-Biphenyl)di-1-adamantylphosphine[1,1'-Biphenyl]-2-yldi(adamantan-1-yl)phosphine2-[Bis(1-adamantyl)phosphino]biphenylBis(1-adamantyl)-(2-phenylphenyl)phosphaneMFCD28100470[1,1 inverted exclamation marka-Biphenyl]-2-yldi[(3S,5S,7S)-1-adamantanyl]phosphineSCHEMBL4433788C32H39PMSKLBRMTWIUCEQ-UHFFFAOYSA-N2-(di-1-adamantylphosphino)biphenyl2-Biphenylyldi(1-adamantyl)phosphine
Show more names
2-(Bis(adamant-1-yl)phosphino)biphenyl2-[Diphenylphosphine-1-undecyl]benzene(2-Biphenyl)di-1-adamantylphosphine 97%1,1'-Biphenyl]-2-yldi(adamantan-1-yl)phosphineBiphenyl]-2-yldi[(3S,5S,7S)-1-adamantanyl]phosphine[1,1′-Biphenyl]-2-yldi[(3S,5S,7S)-1-adamantanyl]phosphinePhosphine, [1,1'-biphenyl]-2-ylbis(tricyclo[3.3.1.13,7]dec-1-yl)-
2-(di- 1-adamantylphosphino)biphenylSY279477CS-0108697E81299[1,1'-biphenyl]-2-yldi(adamantan-1-yl)phosphaneF870266[1,1'-Biphenyl]-2-yldi[(3S,5S,7S)-1-adamantanyl]phosphine[1,1?-Biphenyl]-2-yldi[(3S,5S,7S)-1-adamantanyl]phosphine
Properties
Computed structural properties
- XLogP
- 8.5
- Topological polar surface area
- 0 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 0
- Rotatable bonds
- 4
- Heavy atoms
- 33
- Formal charge
- 0
- Complexity
- 619
Physicochemical properties
- Melting point
- 220 · 220-225°C
- storage temp.
- 2 · 2-8°C, protect from light, stored under nitrogen
- Appearance
- White to off-white Solid
- InChI
- InChI=1S/C32H39P/c1-2-6-28(7-3-1)29-8-4-5-9-30(29)33(31-16-22-10-23(17-31)12-24(11-22)18-31)32-19-25-13-26(20-32)15-27(14-25)21-32/h1-9,22-27H,10-21H2
- InChIKey
- MSKLBRMTWIUCEQ-UHFFFAOYSA-N
- SMILES
- P(C1=CC=CC=C1C1=CC=CC=C1)(C12CC3CC(CC(C3)C1)C2)C12CC3CC(CC(C3)C1)C2
- Symbol(GHS)
- 6 · GHS06
- Signal word
- Danger
- Hazard statements
- 301 · H301-H315-H319
- Precautionary statements
- 301 · P301+P310-P305+P351+P338
- Hazard Codes
- T
- Risk Statements
- 23 · 23/24/25-36/37/38
- Safety Statements
- 36 · 36/37/39-45
- RIDADR
- 2811 · UN 2811 6.1 / PGIII
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]
P264, P264+P265, P270, P280, P301+P316, P302+P352, P305+P351+P338, P321, P330, P332+P317, P337+P317, P362+P364, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Hazard Classes and CategoriesAcute Tox. 3 (100%)
Safety data
- wgk
- 3
- ridadr
- UN 2811 6.1 / PGIII
- risk_code
- 23/24/25-36/37/38
- Signal word
- Danger
- Symbol(GHS)
- GHS06
- hazard_code
- T
- safety_code
- 36/37/39-45
- Hazard statements
- H301-H315-H319
- Precautionary statements
- P301+P310-P305+P351+P338
Chemistry & industry
Applications
UsesPhosphine ligand for cross coupling.
Suppliers34 total
杭州摩库生物医药科技有限公司+86-057181025280; +8617767106207 · [email protected]
湖南嘉航医药科技有限公司85521272 15200744171 · [email protected]
陕西缔都化学有限公司029-029-81123119 17391733320 · [email protected]
毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]
安耐吉化学&3A（安徽泽升科技有限公司）021-58432009 400-005-6266 · [email protected]
Protheragen-ING+86-15618352007 · [email protected]
成都麦卡希化工有限公司028-85632863 18108198598 · [email protected]
台州南峰药物研究所[email protected] 18616377689 · [email protected]
上海亚毓生物医药有限公司021-54370211 18051886391 · [email protected]
上海笛柏生物科技有限公司400-008-9730,021-54359730 400-008-9730 · [email protected]
新乡市润宇新材料科技有限公司166-166-37336996 15690792173 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
Related reactions
7 records
Compound notes
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