Praseodymium(III) trifluoromethanesulfonate

HCID 9894708

Notes Reactions

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Basic information

CAS: 52093-27-3
Standard SMILES: O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.[Pr+3]
InChIKey: ROUBZIWQWFQCHU-UHFFFAOYSA-K
Molecular formula: C3F9O9PrS3
Average molar mass: 588.1 g/mol
Monoisotopic mass: 587.76372636

Names & identifiers

Preferred name: Praseodymium(III) trifluoromethanesulfonate
IUPAC: praseodymium(3+);tris(trifluoromethanesulfonate)
English name: Praseodymium (III) trifluoromethanesulfonate
Molecular formula: C3F9O9PrS3
Molecular weight: 588.11

Names & synonyms

Praseodymium(III) trifluoromethanesulfonateDTXSID70432455RefChem:373781DTXCID40383283627-591-352093-27-3Praseodymium(III) triflatepraseodymium(3+);trifluoromethanesulfonateMFCD00192417Praseodymium (III) trifluoromethanesulfonatePraseodymium(III)trifluoromethanesulfonateC3F9O9PrS3

Show more names

Praseodymium(III) trifLPRASEODYMIUM TRIFLUOROMETHANESULFONATEPraseodyMiuM(III) trifluoroMethanesulfonPRASEODYMIUM(III) TRIFLUOROMETHANESULPHONATEPraseodymium(III) trifluoromethanesulfonate 98%Praseodymium (III) Trifluoromethanesulfonate extrapure, 98%Praseodymium(III) trifluoromethanesulfonate (Praseodymium triflate)

SCHEMBL384988AKOS025243476GS-6837SY061446Praseodymium tris(trifluoromethanesulfonate)H10848praseodymium(3+) ion tritrifluoromethanesulfonatePraseodymium(III) trifluoromethanesulfonate, 98%

Database identifiers

CAS: 52093-27-3
PubChem CID: 9894708
DTXSID: DTXSID70432455
EC Number: 627-591-3
Nikkaji: J1.021.249I

Properties

Computed structural properties

Topological polar surface area: 197 Å²
Hydrogen bond donors: 0
Hydrogen bond acceptors: 18
Rotatable bonds: 0
Heavy atoms: 25
Formal charge: 0
Complexity: 145

Physicochemical properties

storage temp.: 2 · under inert gas (nitrogen or Argon) at 2-8°C
solubility: Methanol (Slightly), Water (Slightly)
form: Powder
color: green
Water Solubility: Insoluble in water.
Sensitive: heat sensitive, hygroscopic
Stability: Hygroscopic
InChI: 1S/3CHF3O3S.Pr/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
InChIKey: ROUBZIWQWFQCHU-UHFFFAOYSA-K
SMILES: [Pr+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
UNSPSC Code: 12352300 · 12352300
NACRES: 22 · NA.22
Symbol(GHS): 7 · GHS07
Signal word: Warning
Hazard statements: 315 · H315-H319-H335
Precautionary statements: 280 a-P304+P340-P405-P501a-P261-P305+P351+P338 · P280a-P304+P340-P405-P501a-P261-P305+P351+P338
target organs: Respiratory system
PPE: 95 · dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes: Xi
Risk Statements: 36 · 36/37/38
Safety Statements: 26 · 26-36
WGK Germany: 3 · 3
HS Code: 2846901020 · 2846901020
Storage Class: 11 · 11 - Combustible Solids
Hazard Classifications: 2 Skin · Eye Irrit. 2Skin Irrit. 2STOT SE 3

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 43 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesSkin Irrit. 2 (100%)

Safety data

PPE: dust mask type N95 (US), Eyeshields, Gloves
wgk: 3
hs_code: 2846901020
risk_code: 36/37/38
Signal word: Warning
Symbol(GHS): GHS07
hazard_code: Xi
safety_code: 26-36
Storage Class: 11 - Combustible Solids
target organs: Respiratory system
Hazard statements: H315-H319-H335
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
Precautionary statements: P280a-P304+P340-P405-P501a-P261-P305+P351+P338

Chemistry & industry

Applications · 2 items

UsesPraseodymium(III) Triflate can be used to prepare halogen-free flame retardant composition.

General DescriptionPraseodymium (III) trifluoromethanesulfonate (Praseodymium(III) triflate) is a water-tolerant Lewis acid. It is an efficient catalyst employed for the synthesis of α-aminonitrile, via condensation of aldehydes, amines and trimethylsilyl cyanide.

Suppliers64 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]

阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]

上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]

Related reactions

30 records

New reaction record

HRID 279694As reactantuspto-grants-2002_03

HRID 279697As reactantuspto-grants-2002_03

HRID 2000192As reagent39k HTE dataset from Pfizer

HRID 2000206As reagent39k HTE dataset from Pfizer

HRID 2000308As reagent39k HTE dataset from Pfizer

HRID 2000318As reagent39k HTE dataset from Pfizer

HRID 2031151As reagent39k HTE dataset from Pfizer

HRID 2031165As reagent39k HTE dataset from Pfizer

Compound notes

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