Isobutyraldehyde trimethylsilyl enol ether

HCID 99685
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Basic information

CAS
6651-34-9
Standard SMILES
CC(C)=CO[Si](C)(C)C
InChIKey
KZVPFSJPLBOVLO-UHFFFAOYSA-N
Molecular formula
C7H16OSi
Average molar mass
144.29 g/mol
Monoisotopic mass
144.09704166

Overview

structure given in first source

Names & identifiers

Preferred name
Isobutyraldehyde trimethylsilyl enol ether
IUPAC
trimethyl(2-methylprop-1-enoxy)silane
English name
2-Methyl-1-(trimethylsiloxy)-1-propene
Molecular formula
C7H16OSi
Molecular weight
144.29

Names & synonyms

6651-34-9ITSEIsobutyraldehyde trimethylsilyl enol etherDTXSID30216713RefChem:149118DTXCID601392042-Methyl-1-(trimethylsilyloxy)-1-propenetrimethyl((2-methylprop-1-en-1-yl)oxy)silane2-METHYL-1-(TRIMETHYLSILOXY)-1-PROPENEtrimethyl[(2-methylprop-1-en-1-yl)oxy]silanetrimethyl(2-methylprop-1-enoxy)silaneMFCD00192331
Show more names
rimethyl(2-methylprop-1-enoxy)silane1-(Trimethylsilyloxy)-2-methylpropeneTrimethyl[(2-methyl-1-propen-1-yl)oxy]silane2-Methyl-1-(trimethylsilyloxy)-1-propene 99%
Silane, trimethyl((2-methyl-1-propenyl)oxy)-Silane, trimethyl[(2-methyl-1-propenyl)oxy]-F87375FT-0693925SCHEMBL160478CHEMBL142371hydro isobutenyloxy(trimethyl)silaneNSC266194

Database identifiers

CAS
6651-34-9
PubChem CID
99685
DTXSID
DTXSID30216713
ChEMBL
CHEMBL142371
EC Number
627-551-5
Nikkaji
J258.812I

Properties

Computed structural properties

Topological polar surface area
9.2 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
1
Rotatable bonds
2
Heavy atoms
9

Experimental & physicochemical properties

SpringerMaterials PropertiesChemical shift

Physicochemical properties

Boiling point
114 · 114-116 °C/650 mmHg (lit.)
Density
0.785 g/mL · 0.785 g/mL at 25 °C (lit.)
refractive index
20 · n20/D 1.409(lit.)
Flash point
57 °F · 57 °F
form
liquid
Specific Gravity
0.785 · 0.785

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

Safety data

PPE
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk
3
tsca
No
ridadr
UN 1993 3/PG 2
risk_code
11-36/37/38
Signal word
Danger

Chemistry & industry

Applications · 3 items

Uses1-(Trimethylsilyloxy)-2-methylpropene is used as a nucleophiles in Lewis Acid-Catalyzed reactions.

Uses2-Methyl-1-(trimethylsilyloxy)-1-propene may be used as reagent in the direct conversion of α-amino acids into β-amino aldehydes.

General Description2-Methyl-1-(trimethylsilyloxy)-1-propene is an enol ether.

Upstream & downstream products

Suppliers49 total

上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]
温州共赢化学有限公司+86-0086-577-64498589 +86-15355981851 · [email protected]
上海毕得医药科技股份有限公司400-1647117 13681763483 · [email protected]
Suzhou ARTK Medchem Co., Ltd.+86-18168183658 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]

Related reactions

5 records
New reaction record

Compound notes

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