Styrene → GDMA Styrene

HRID 1004857

Reaction equation

HRID 1004857 reaction equation
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:9]([O:16][C:17]([CH2:19][SH:20])=[O:18])[CH2:10][O:11][C:12]([CH2:14][SH:15])=[O:13]>>[CH2:10]([O:11][C:12]([CH2:14][SH:15])=[O:13])[CH2:9][O:16][C:17]([CH2:19][SH:20])=[O:18].[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Participants

3

Reactant 2

HCID 7501Styrene2×HCID 61059Ethylene di(S-thioacetate)

Product 1

HCID 131721770GDMA Styrene

Procedure

Styrene (481.4 g, 4.62 eq.) was weighed into a 2000 ml, three neck, round bottom flask along with TPO (1.52 g). The flask was sealed with rubber stoppers and placed in a 60° C. oven for approximately 20 minutes. The contents were swirled occasionally until the TPO dissolved into the styrene. The flask was removed from the oven and allowed to cool to less than 40° C. at which point GDMA (518.6 g, 4.467 eq.) was weiched into the flask.

Workup

  1. customThe flask was sealed with rubber stoppers
  2. customplaced in a 60° C.
  3. customfor approximately 20 minutes
  4. customThe flask was removed from the oven

Sources & evidence

ORD record
ord-fe929a317ad642db80bb0c66e2bfd293
Source dataset
uspto-grants-2000_04
Patent number
US06051733

Linked notes

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