1,3-Dithiolane-4-methanol → HCID 22670109, compound

Reaction equation

[C:1]1([CH:7]2[S:11][CH:10]([CH2:12]O)[CH2:9][S:8]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.OCC1CSC[S:17]1>>[C:1]1([CH:7]2[S:11][CH:10]([CH2:12][SH:17])[CH2:9][S:8]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

Reactant 2

HCID 221471,3-Dithiolane-4-methanol

HCID 474291HCID 474291, compound

Product 1

HCID 22670109HCID 22670109, compound

Procedure

The same method was followed as in Example 1 except that 2-phenyl-4-hydroxymethyl-1,3-dithiolane produced in Example 2 was used in stead of 4-hydroxymethyl-1,3-dithiolane synthesized in Manufacturing Example 1 to obtain 2-phenyl-4-mercaptomethyl-1,3-dithiolane represented by the following formula (2-6).

Workup

customsynthesized in Manufacturing Example 1

Sources & evidence

ORD record: ord-e3029790a5cd4d17aee2689900445cd4
Source dataset: uspto-grants-2004_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06794471B2

Reaction notes

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