TIBA isododecane → 2,3,5-Triiodobenzoic acid

HRID 1011848Notes

Reaction equation

HRID 1011848 reaction equation
[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12].CCCCCCCCCC(C)C>C1(C)C=CC=CC=1>[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12]

Participants

3

Reactant 1

HCID 131728349TIBA isododecane

Product 1

HCID 69482,3,5-Triiodobenzoic acid

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

9.8 cc of TIBA/isododecane solution (101 g/L) were mixed with 1.91 cc of MAO/toluene solution (Albemarle -30% wt) to obtain a MAO/TIBA molar ratio of 2:1. The solution was stirred for 1 hour at room temperature. Then, 26 mg of A-1 were dissolved in the solution.

Sources & evidence

ORD record
ord-b1c79844f75f48d4949d31fdccf96742
Source dataset
uspto-grants-2011_07
Patent number
US07977444B2

Reaction notes

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