3-(Trifluoromethyl)phenol → HCID 178418715, compound

HRID 10155

Reaction equation

HRID 10155 reaction equation
[CH:1]1([Zr:6](C)C)[CH:5]=[CH:4][CH:3]=[CH:2]1.[F:9][C:10]([F:19])([F:18])[C:11]1[CH:16]=[CH:15][CH:14]=[C:13]([OH:17])[CH:12]=1>C1(C)C=CC=CC=1>[CH:1]1([Zr:6]([O:17][C:13]2[CH:14]=[CH:15][CH:16]=[C:11]([C:10]([F:9])([F:18])[F:19])[CH:12]=2)[O:17][C:13]2[CH:14]=[CH:15][CH:16]=[C:11]([C:10]([F:18])([F:19])[F:9])[CH:12]=2)[CH:5]=[CH:4][CH:3]=[CH:2]1

Participants

4

Reactant 2

HCID 73763-(Trifluoromethyl)phenolHCID 178418892HCID 178418892, compound

Product 1

HCID 178418715HCID 178418715, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent3×

Procedure

To a 50 ml Schlenk flask containing 138.7 mg (0.5 mmole) of (1-methylboratabenzene) (cyclopentadienyl) dimethyl zirconium [intermediate product of 1st Step] in 15 ml toluene and at 0° C., 162.1 mg (1 mmole) of Trifluoro-m-Cresol in 10 ml toluene is added slowly under stirring. After warming up to room temperature and stirring one hour at room temperature, toluene of the reaction mixture is moved by vacuum. The desired product (1-methylboratabenzene) (cyclopentadienyl) bis(3-trifluoromethylphenoxy) zirconium can be obtained from the residue of vacuum distillation.

Workup

  1. stirringstirring one hour at room temperature

Sources & evidence

ORD record
ord-6cea0494348b410e84f555c127ac38a6
Source dataset
uspto-grants-2006_08
Patent number
US07094723B2

Linked notes

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