Reaction equation
C[N:2](C)[CH:3]=[CH:4][C:5]1[CH:10]=[CH:9][C:8]([N+:11]([O-:13])=[O:12])=[C:7]([O:14][CH3:15])[CH:6]=1.[N+](C1C=CC(CC#N)=C2C=1NN=C2)([O-])=O>>[CH3:15][O:14][C:7]1[CH:6]=[C:5]([CH2:4][C:3]#[N:2])[CH:10]=[CH:9][C:8]=1[N+:11]([O-:13])=[O:12]Participants
3
Procedure
19.8 g of N,N-dimethyl-N-[2-(3-methoxy-4nitrophenyl)ethenyl]amine and 30.0 g of hydroxylamineorthosulfonic acid are reacted as described in connection with preparing 2-(7-nitro-1H-indazol-4-yl)acetonitrile, thus obtaining 17.0 g of (3-methoxy-4-nitrophenyl)acetonitrile, mp 85°-86.5° C.
Sources & evidence
- ORD record
- ord-5e0df74fa9d84916b8697d0da74d71e9
- Source dataset
- uspto-grants-1990_09
- Patent number
- US04958026
Linked notes
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