2-Bromo-4-(methylthio)pyridine → 2-Bromo-4-methanesulfinyl-pyridine

Reaction equation

[Br:1][C:2]1[CH:7]=[C:6]([S:8][CH3:9])[CH:5]=[CH:4][N:3]=1.BrC1C=CC(S(C)=[O:18])=NC=1>>[Br:1][C:2]1[CH:7]=[C:6]([S:8]([CH3:9])=[O:18])[CH:5]=[CH:4][N:3]=1

Participants

Reactant 2

HCID 234370172-Bromo-4-(methylthio)pyridine

HCID 584853485-Bromo-2-(methylsulfinyl)pyridine

Product 1

HCID 584853392-Bromo-4-methanesulfinyl-pyridine

Procedure

The title compound was prepared from 2-bromo-4-methylsulfanyl-pyridine following a procedure analogous to that described for 5-bromo-2-methanesulfinyl-pyridine in Example 182. Mass spectrum (ESI+): m/z=220/222 (Br) [M+H]+.

Sources & evidence

ORD record: ord-56695d0523cf457f8cf04de3085e1756
Source dataset: uspto-grants-2013_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08569292B2

Reaction notes

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