3-Bromo-5-(methylthio)pyridine → 3-Bromo-5-(methylsulfinyl)pyridine

Reaction equation

[Br:1][C:2]1[CH:3]=[N:4][CH:5]=[C:6]([S:8][CH3:9])[CH:7]=1.BrC1C=CC(S(C)=[O:18])=NC=1>>[Br:1][C:2]1[CH:3]=[N:4][CH:5]=[C:6]([S:8]([CH3:9])=[O:18])[CH:7]=1

Participants

Reactant 2

HCID 223903593-Bromo-5-(methylthio)pyridine

HCID 584853485-Bromo-2-(methylsulfinyl)pyridine

Product 1

HCID 584853343-Bromo-5-(methylsulfinyl)pyridine

Procedure

The title compound was prepared from 3-bromo-5-methylsulfanyl-pyridine following a procedure analogous to that described for 5-bromo-2-methanesulfinyl-pyridine in Example 182.

Sources & evidence

ORD record: ord-748968cae89f4b0e9763ef296e6f9d25
Source dataset: uspto-grants-2013_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08569292B2

Reaction notes

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