Methyl atropate → Methyl phenylglyoxalate

HRID 1065740

Reaction equation

HRID 1065740 reaction equation
[C:1]([O:11][CH3:12])(=[O:10])[C:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)=C.C(O)(=[O:31])CCCCCCC/C=C\CCCCCCCC>C(O)(=O)C>[C:2]([C:1]([O:11][CH3:12])=[O:10])(=[O:31])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1

Participants

4

Reactant 2

HCID 193334Methyl atropateHCID 445639Oleic Acid

Product 1

HCID 84835Methyl phenylglyoxalateYield 88%

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

The co-oxidation reaction was carried out in manner as described in Example 16, except that methyl atropate was used in lieu of oleic acid. As a result, acetic acid was obtained at a yield of 95% and methyl benzoylformate was obtained at a yield of 88%.

Workup

  1. customThe co-oxidation reaction

Sources & evidence

ORD record
ord-cba2002bf722486e97dfbc4f4ed88723
Source dataset
uspto-grants-1982_05
Patent number
US04331608

Linked notes

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