Pyridine → Benzene, [(trichlorosilyl)methyl]-

HRID 1068522

Reaction equation

HRID 1068522 reaction equation
N1C=CC=CC=1.[CH2:7](Cl)[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1.[Cl:15][SiH:16]([Cl:18])[Cl:17]>>[CH2:7]([Si:16]([Cl:18])([Cl:17])[Cl:15])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1

Participants

4

Reactant 3

HCID 1049PyridineHCID 7503Benzyl ChlorideHCID 24811Trichlorosilane

Product 1

HCID 69863Benzene, [(trichlorosilyl)methyl]-Yield 11%

Procedure

In the same apparatus and procedure as Example 1 above, 0.08 g (1.0 mmol) of pyridine, 0.63 g (5.0 mmol) of benzyl chloride, and 3.41 g (25.2 mmol) of trichlorosilane were reacted at 200° C. for 6 hrs. The resulting mixture was distilled to give 0.12 g of benzyltrichlorosilane (yield; 11%).

Workup

  1. distillationThe resulting mixture was distilled

Sources & evidence

ORD record
ord-742d3d2df58f4c96b4dbd7fc7f874d68
Source dataset
uspto-grants-2001_06
Patent number
US06251057B1

Linked notes

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