N,N,2-Trimethylaniline → p-Methoxybenzyltrichlorosilane

HRID 1068528Notes

Reaction equation

HRID 1068528 reaction equation
CN(C)C1C(C)=CC=CC=1.[CH3:11][O:12][C:13]1[CH:20]=[CH:19][C:16]([CH2:17]Cl)=[CH:15][CH:14]=1.[Cl:21][SiH:22]([Cl:24])[Cl:23]>>[CH3:11][O:12][C:13]1[CH:20]=[CH:19][C:16]([CH2:17][Si:22]([Cl:24])([Cl:23])[Cl:21])=[CH:15][CH:14]=1

Participants

4

Reactant 3

HCID 11869N,N,2-TrimethylanilineHCID 24811TrichlorosilaneHCID 699934-Methyloxybenzyl chloride

Product 1

HCID 11482253p-MethoxybenzyltrichlorosilaneYield 11.3%

Procedure

In the same apparatus and procedure as Example 1 above, 0.06 g (0.45 mmol) of N,N-dimethyltoluidine, 0.7 g (4.5 mmol) of 4-methoxybenzyl chloride, and 3.05 g (22.5 mmol) of trichlorosilane were reacted at 200+ C. for 15 hrs. The resulting mixture was distilled to give 0.13 g of (4-methoxybenzyl)trichlorosilane (yield; 11%).

Workup

  1. distillationThe resulting mixture was distilled

Sources & evidence

ORD record
ord-386dd98b71b5429bb4eb1c57d306cbbf
Source dataset
uspto-grants-2001_06
Patent number
US06251057B1

Reaction notes

Loading…