Dibutylstannane → Bis[2-(2-ethylhexanoyloxy)ethyl]dibutyltin

HRID 1073485

Reaction equation

HRID 1073485 reaction equation
[CH2:1]([SnH2:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].[CH2:10]([CH:12]([CH2:18][CH2:19][CH2:20][CH3:21])[C:13]([O:15][CH:16]=[CH2:17])=[O:14])[CH3:11]>C1CCCCC1>[CH2:10]([CH:12]([CH2:18][CH2:19][CH2:20][CH3:21])[C:13]([O:15][CH2:16][CH2:17][Sn:5]([CH2:17][CH2:16][O:15][C:13](=[O:14])[CH:12]([CH2:10][CH3:11])[CH2:18][CH2:19][CH2:20][CH3:21])([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:1][CH2:2][CH2:3][CH3:4])=[O:14])[CH3:11]

Participants

4

Reactant 2

HCID 6513DibutylstannaneHCID 62343Vinyl 2-ethylhexanoate

Product 1

HCID 14512235Bis[2-(2-ethylhexanoyloxy)ethyl]dibutyltin

Reagents, catalysts & solvents 1

HCID 8078CyclohexaneSolvent

Procedure

2.349 g (0.01 mol) of dibutyltin dihydride, 3.405 g (0.02 mol) of distilled vinyl 2-ethylhexanoate and 2.5 g of anhydrous cyclohexane were introduced into a Pyrex® tube. The exposure to ultraviolet rays was for 8 hours 30 min at 30°-35° C. The solvent was removed under vacuum at ambient temperature.

Workup

  1. customThe solvent was removed under vacuum at ambient temperature

Sources & evidence

ORD record
ord-afdeea21f83649c98c3d79d9bf899067
Source dataset
uspto-grants-1990_11
Patent number
US04970115

Linked notes

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